Polyethylene for pipe and joint, and molded body thereof
A polyethylene for a pipe and a joint of the present invention satisfies the following characteristics (1) to (5): Characteristic (1): a melt flow rate at a temperature of 190° C. and a load of 21.6 kg (HLMFR) is 5 to 20 g/10 minutes, Characteristic (2): a density (D) is 0.954 to 0.960 g/cm 3 , Characteristic (3): a ratio of weight-average molecular weight (Mw) and number-average molecular weight (Mn) (Mw/Mn) measured by gel permeation chromatography (GPC) is 15 to 27, Characteristic (4): a rupture time at 80° C. and 5 MPa by a full notch creep test (FNCT) is 150 hours or more, and Characteristic (5): a Charpy impact strength (CIS) measured at −20° C. is 8.5 kJ/m 2 or more.
1. A polyethylene, which satisfies the following characteristics (1) to (5):
Characteristic (1): a melt flow rate at a temperature of 190° C. and a load of 21.6 kg (HLMFR) is 5 to 20 g/10 minutes,
Characteristic (2): a density (D) is 0.954 to 0.960 g/cm 3 ,
Characteristic (3): a ratio of weight-average molecular weight (Mw) and number-average molecular weight (Mn) (Mw/Mn) measured by gel permeation chromatography (GPC) is 15 to 27,
Characteristic (4): a rupture time at 80° C. and 5 MPa by a full notch creep test (FNCT) is 150 hours or more, and
Characteristic (5): a Charpy impact strength (CIS) measured at −20° C. is 8.5 kJ/m 2 or more,
wherein the polyethylene contains at least 25 to 35% by weight of the following polyethylene component (a) and 75 to 65% by weight of the polyethylene component (b):
the polyethylene component (a) being a polyethylene which is polymerized using a metallocene catalyst, has an HLMFR of 0.01 to 0.5 g/10 minutes, and has a density of 0.915 to 0.930 g/cm 3 and
the polyethylene component (b) being a polyethylene which is at least one of an ethylene homopolymer and a copolymer of ethylene and an α-olefin, has a melt flow rate (MFR) at a temperature of 190° C. and a load of 2.16 kg of 1 to 10 g/10 minutes, a density of 0.960 to 0.975 g/cm 3 , and an Mw/Mn of 12 to 25, and
wherein the polyethylene component (b) is composed of 18 to 30% by weight of a polyethylene component (b-1) and 70 to 82% by weight of a polyethylene component (b-2), the polyethylene component (b-1) has an HLMFR of 0.45 to 4.0 g/10 minutes and a density of 0.935 to 0.955 g/cm 3 , and the polyethylene component (b-2) has an MFR of 50 to 200 g/10 minutes and a density of 0.960 to 0.975 g/cm 3 .
2. The polyethylene according to claim 1 , which further satisfies the following characteristic (6):
Characteristic (6): a relationship between the CIS and the HLMFR satisfies the following formula (1):
CIS>−0.1255×HLMFR+11.216 Formula (1).
3. The polyethylene according to claim 1 , which further satisfies the following characteristic (7):
Characteristic (7): a relationship between the CIS and the density (D) satisfies the following formula (2):
CIS>−1375×D+1323 Formula (2).
4. The polyethylene according to claim 1 , wherein the polyethylene component (b) is an ethylene-based polymer polymerized using a Ziegler catalyst.
5. The polyethylene according to claim 1 , wherein the polyethylene component (a) is polymerized using a metallocene catalyst having a cyclopentadienyl ring and a heterocyclic aromatic group.
6. The polyethylene according to claim 1 , wherein the polyethylene component (b) is polymerized using a metallocene catalyst having a cyclopentadienyl ring and a fluorenyl ring.
7. A molded body formed from the polyethylene according to claim 1 .
8. The molded body according to claim 7 , wherein the molded body is a pipe or a joint.
9. The molded body according to claim 8 , wherein a breaking time at 20° C. and at a circumferential stress of 13.0 MPa by an internal pressure creep test is 500 hours or more.
10. The molded body according to claim 9 , wherein an internal pressure at a test temperature of 23° C. and for a use lifetime of 50 years determined by long-term hydrostatic strength (LTHS) measured in accordance with ISO 9080:2012 is 12.5 MPa or more.