IP Library › Granted Patent US 10,381,119
Granted Patent B2
US 10,381,119 · App. 15/021,618 · Granted Aug 13, 2019

Nuclear fuel pellet having enhanced thermal conductivity, and preparation method thereof

Inventors: Irina Semyonovna Kurina (Obninsk, RU); Vjacheslav Vasilyevich Popov (Obninsk, RU); Vladimir Nikolaevich Rumyantsev (Obninsk, RU); Aleksander Evgenievich Rusanov (Obninsk, RU); Stepan Sergeevich Rogov (Obninsk, RU); Said Mirfaisovich Sharikpulov (Barvikha, RU)
Assignee: Joint Stock Company “AKME-Engineering”
G21C3/623G21C3/044G21C3/58G21C21/02G21C3/045Y02E30/38
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Quick Facts
Patent No.
US 10,381,119
App. No.
15/021,618
Granted
Aug 13, 2019
Kind
B2
Abstract

The invention relates to nuclear physics, and specifically to reactor fuel elements and units thereof, and particularly to the composition of solid ceramic fuel elements based on uranium dioxide, intended for and exhibiting characteristics for being used in variously-purposed nuclear reactors. The result consists in a more reliable, special structure and a simple composition of uranium dioxide without heterogeneous fuel pellet additives, approaching the characteristics of a monocrystal having enhanced, and specifically exceeding reference data, thermal conductivity as temperature increases, and a simple production method thereof. The result is achieved in that pores of between 1 and 5 microns in size are distributed along the perimeters of grains in the micro-structure of each metal cluster in a nuclear fuel pellet, and in that located within the grains are pores which are predominantly nano-sized. In addition, the metal clusters comprise between 0.01 and 1.0 percent by mass. The invention provides for a method of preparing a nuclear fuel pellet, including precipitating metal hydroxides, in two stages, having different pH levels. Uranium metal is melted at a temperature exceeding 1150 DEG C., sintering is carried out in an insignificant amount of liquid phase at a temperature ranging between 1600 and 2200 DEG C. in a hydrogen medium until forming uranium dioxide, the structure of which includes metal clusters dispersed therein. An X-ray photon spectroscope is used for identifying the new structure of the UO2 pellet and the additional U—U chemical bond.

Claims (8)

1. A nuclear fuel pellet, comprising:

a pellet structure of a pressed and sintered uranium dioxide powder;

wherein the pellet structure is made up of evenly distributed pores among grains of the uranium dioxide powder;

wherein nanopores and metal clusters of chemically bonded uranium cations are located inside the grains;

wherein the nanopores are between 1 and 200 nm in size and comprise at least 50% of a total porosity of the pellet structure;

wherein the metal clusters are surrounded by the uranium dioxide powder;

wherein a total content of the metal clusters is between 0.01 and 2 wt %;

wherein the nuclear fuel pellet has a thermal conductivity in a range of 7.6 to 8.7 W/m·degrees over a temperature range of 600° to 900° C.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 29, 2016
From: KURINA, IRINA SEMYONOVNA; VJACHESLAV VASILYEVICH POPOV, DECEASED, BY ILYA VLADIMIROVICH CHERNYKH, ADMINISTRATOR/EXECUTOR; RUMYANTSEV, VLADIMIR NIKOLAEVICH; RUSANOV, ALEKSANDER EVGENIEVICH; ROGOV, STEPAN SERGEEVICH; SHARIKPULOV, SAID MIRFAISOVICH
To: JOINT STOCK COMPANY "AKME-ENGINEERING"
Reel/Frame 039044/0249 →
Priority Claims (1)
RU 2013152247 · Nov 26, 2013 · national
Continuity (1)
Related Publication 20160232993A1 · Aug 11, 2016