Secondary battery system using temperature threshold in response to lithium ion concentrations
A secondary battery system includes a battery having an electrode body impregnated with an electrolyte containing lithium ions; and an ECU configured to permit charge and discharge of the battery when battery temperature is equal to or more than a threshold temperature and to restrict the charge and discharge of the battery when the battery temperature is less than the threshold temperature. The ECU is configured to obtain a value related to minimum concentration of the lithium ions (minimum salt concentration) caused by a deviation of concentration distribution of the lithium ions in the electrode body, and to set the threshold temperature to be higher as the related value representing the minimum salt concentration becomes lower.
1. A secondary battery system, comprising:
a secondary battery having an electrode body impregnated with an electrolyte containing lithium ions; and
a control unit configured to permit charge and discharge of the secondary battery when temperature of the secondary battery is equal to or more than a threshold temperature and to restrict the charge and discharge of the secondary battery when the temperature of the secondary battery is less than the threshold temperature, wherein
the control unit is configured to obtain a value related to a minimum concentration of the lithium ions in a region of the secondary battery, the region having the smallest concentration of the lithium ions out of all regions in the secondary battery due to a deviation in concentration distribution of the lithium ions in the electrode body, and to set the threshold temperature to be higher as an amount of decrease in the minimum concentration becomes larger, the amount of decrease being represented by the related value.
2. The secondary battery system according to claim 1 , wherein
the control unit is configured to calculate, based on a charge and discharge history of the secondary battery, an evaluation value representing a deteriorating degree of the secondary battery attributed to the deviation of the concentration distribution caused by the charge and discharge of the secondary battery and to set the threshold temperature to be higher as the evaluation value is larger.
3. The secondary battery system according to claim 1 , wherein
the secondary battery further includes: a battery casing that houses the electrode body; and a surface pressure sensor that measures surface pressure on a surface of the battery casing, and
the control unit is configured to set the threshold temperature to be higher as the surface pressure is higher.
4. The secondary battery system according to claim 1 , wherein
the control unit is configured to calculate a flow velocity of the electrolyte using a liquid flow equation that defines a flow of the electrolyte, to calculate the concentration distribution from the flow velocity, and to calculate the minimum concentration from the calculated concentration distribution.