Low-dust, high insulation aerogel blanket and method for producing the same
The present invention relates to a low-dust, high insulation aerogel blanket and a method for producing the same. More specifically, the present invention provides a method for producing a low-dust, high insulation aerogel blanket, wherein a plate type Mg(OH) 2 .MgO.SiO 2 powder is added to a silica sol, thereby being capable of reducing the generation of dust with excellent flame retardancy and thermal conductivity, and an aerogel blanket produced thereby.
1. A method for producing an aerogel blanket, the method comprising the steps of:
1) mixing a silica precursor, water, and alcohol to prepare a silica sol;
2) adding an additive represented by Formula 1 below to the silica sol;
3) mixing a basic catalyst with the silica sol mixed with the additive and then impregnating a blanket substrate;
4) performing a gelation reaction of the silica sol in a state in which the silica sol is impregnated into the blanket substrate; and
5) thereafter, performing surface modifying and drying,
M(OH) x .M y O z .SiO 2 [Formula 1]
wherein:
M is at least one metal element selected from the group consisting of Mg, Ca and Al; and
x, y and z are positive integers of 3 or less.
2. The method of claim 1 , wherein the additive is Mg(OH) 2 .MgO.SiO 2 .
3. The method of claim 1 , wherein the additive is a plate powder.
4. The method of claim 1 , wherein the additive is used in an amount of 2.5 to 20 parts by weight, based on 100 parts by weight of the silica precursor.
5. The method of claim 1 , wherein the basic catalyst is at least one selected from the group consisting of ammonium hydroxide (NH 4 OH), tetramethylammonium hydroxide (TMAH), tetraethylammonium hydroxide (TEAH), tetrapropylammonium hydroxide (TPAH), tetrabutylammonium hydroxide (TBAH), methylamine, ethylamine, isopropylamine, monoisopropylamine, diethylamine, diisopropylamine, dibutylamine, trimethylamine, triethylamine, triisopropylamine, tributylamine, colin, monoethanolamine, diethanolamine, 2-aminoethanol, 2-(ethylamino)ethanol, 2-(methylamino)ethanol, N-methyldiethanolamine, dimethylaminoethanol, diethylaminoethanol, nitrilotriethanol, 2-(2-aminoethoxy)ethanol, 1-amino-2-propanol, triethanolamine, monopropanolamine, and dibutanolamine.
6. The method of claim 1 , wherein the blanket substrate is at least one selected from the group consisting of films, sheets, nets, fibers, porous bodies, foams, and nonwoven fabrics.
7. The method of claim 1 , further comprising, after step 4), a step of performing an aging.
8. The method of claim 1 , wherein the surface modification is performed by adding at least one surface modifier selected from the group consisting of trimethylchlorosilane (TMCS), hexamethyldisilazane (HMDS), methyltrimethoxysilane, trimethylethoxysilane, ethyltriethoxysilane, phenyltriethoxysilane, and polydimethylsiloxane.
9. The method of claim 1 , wherein the drying is performed by a supercritical drying or ambient drying process.
10. An aerogel blanket produced by the method of claim 1 .
11. The aerogel blanket of claim 10 , wherein the thermal conductivity of the aerogel blanket is 14 mW/mK or less.