Settable, form-filling loss circulation control compositions comprising in situ foamed calcium aluminate cement systems and methods of using them
This document relates to settable, hydraulic, non-Portland foamed cement compositions comprising nitrogen gas-generating compositions used for loss circulation control.
1. A cementitious composition comprising:
calcium aluminate comprising greater than or about 68.5% alumina and less than or about 31% calcium oxide;
a nitrogen gas-generating compound in an amount of about 1% to about 10% by weight of the calcium aluminate, the nitrogen gas-generating compound comprising an azo compound;
an amine activator to accelerate generation of gas from the nitrogen gas-generating compound, the amine activator comprising an ethyleneamine, wherein a weight ratio of the azo compound to the amine activator is about 5:1 to about 1:5; and
a foam surfactant.
2. The composition of claim 1 , comprising a viscosifier comprising xanthan or diutan, or a combination thereof.
3. The composition of claim 1 , wherein the foam surfactant comprises an alkyl salt or cocoamidopropyl hydroxysultaine, or a combination thereof.
4. The composition of claim 1 , wherein the ethyleneamine comprises ethylenediamine (EDA), diethylenetriamine (DETA), triethylenetetramine (TETA), or tetraethylenepentamine (TEPA), or any combinations thereof.
5. The composition of claim 4 , wherein the foam surfactant comprises a surfactant solution added as 1% to 10% by volume of mix water to the cementitious composition.