IP Library › Granted Patent US 10,407,555
Granted Patent B2
US 10,407,555 · App. 15/756,909 · Granted Sep 10, 2019

Polyester film containing furandicarboxylate unit

Inventors: Jun Inagaki (Otsu, JP); Katsuya Ito (Otsu, JP); Toshiyuki Shimizu (Inuyama, JP); Shoichi Gyobu (Osaka, JP); Chikao Morishige (Osaka, JP); Jesper Gabriel Van Berkel (Amsterdam, NL)
Assignees: TOYOBO CO., LTD.; SYNVINA C.V.
C08J5/18C08G63/16C08J2367/02
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Quick Facts
Patent No.
US 10,407,555
App. No.
15/756,909
Granted
Sep 10, 2019
Kind
B2
Abstract

To provide a furandicarboxylate unit-containing polyester film usable for industrial and packaging purposes. The film of the present invention is a polyester film, which is a biaxially oriented film of a polyester resin including a dicarboxylic acid component containing mainly a furandicarboxylic acid and a glycol component containing mainly ethylene glycol, wherein the film has a plane orientation coefficient ΔP of not less than 0.005 and not more than 0.200 and a film thickness of not thinner than 1 micro meter and not thicker than 300 micro meters.

Claims (18)

1. A polyester film, which is a biaxially oriented film of a polyester resin comprising a dicarboxylic acid component containing mainly a furandicarboxylic acid and a glycol component containing mainly ethylene glycol,

wherein the film has

a plane orientation coefficient ΔP of 0.100 or more and 0.160 or less,

a thickness of 5 μm or more and 200 μm or less, and

a heat shrinkage rate of not less than 0.01% and not more than 30% when heated at 150° C. for 30 minutes in a machine direction of film plane and in a transverse direction perpendicular to the machine direction.

2. The polyester film according to claim 1 , wherein the polyester film has a heat shrinkage rate of not less than 0.01% and not more than 20% when heated at 150° C. for 30 minutes.

3. The polyester film according to claim 2 , wherein the polyester film has an oxygen permeability of not less than 1 mL/m 2 /day/MPa and not more than 200 mL/m 2 /day/MPa per 50 micro meters of film thickness under a temperature of 23° C. and a humidity of 65%.

4. The polyester film according to claim 3 , wherein the polyester film has a refractive index of not less than 1.5700 and not more than 1.7000 in a machine direction of film plane (nx) and in a transverse direction perpendicular to the machine direction (ny).

5. The polyester film according to claim 4 , wherein the polyester film has a heat shrinkage rate of not less than 0.01% and not more than 10% when heated at 150° C. for 30 minutes.

6. The polyester film according to claim 5 , wherein the polyester film has a heat shrinkage rate of not less than 0.01% and not more than 8% when heated at 150° C. for 30 minutes.

7. The polyester film according to claim 6 , wherein the polyester film has a heat shrinkage rate of not less than 0.01% and not more than 4.5% when heated at 150° C. for 30 minutes.

8. The polyester film according to claim 7 , wherein the polyester film has a plane orientation coefficient ΔP of not less than 0.100 and not more than 0.200.

9. A method for producing the polyester film according to claim 8 , comprising a stretching process for stretching an unstretched film in the machine direction and in the direction perpendicular to the machine direction to obtain a stretched film, and a relaxation process for relaxing the stretched film.

10. The polyester film according to claim 1 , wherein the polyester film has an oxygen permeability of not less than 1 mL/m 2 /day/MPa and not more than 200 mL/m 2 /day/MPa per 50 micro meters of film thickness under a temperature of 23° C. and a humidity of 65%.

11. The polyester film according to claim 1 , wherein the polyester film has a refractive index of not less than 1.5700 and not more than 1.7000 in a machine direction of film plane (nx) and in a transverse direction perpendicular to the machine direction (ny).

12. The polyester film according to claim 1 , wherein the polyester film has a heat shrinkage rate of not less than 0.01% and not more than 10% when heated at 150° C. for 30 minutes.

13. The polyester film according to claim 1 , wherein the polyester film has a plane orientation coefficient ΔP of not less than 0.100 and not more than 0.200.

14. A method for producing the polyester film according to claim 1 , comprising a stretching process for stretching an unstretched film in the machine direction and in the direction perpendicular to the machine direction to obtain a stretched film, and a relaxation process for relaxing the stretched film.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 23, 2020
From: SYNVINA C.V.
To: FURANIX TECHNOLOGIES B.V.
Reel/Frame 053864/0859 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 4, 2018
From: INAGAKI, JUN; ITO, KATSUYA; SHIMIZU, TOSHIYUKI; GYOBU, SHOICHI; MORISHIGE, CHIKAO; VAN BERKEL, JESPER GABRIEL
To: TOYOBO CO., LTD.; SYNVINA C.V.
Reel/Frame 045721/0166 →
Priority Claims (3)
WO PCT/JP2015/004466 · Sep 2, 2015 · international
WO PCT/JP2015/004625 · Sep 10, 2015 · international
WO PCT/JP2015/005370 · Oct 26, 2015 · international
Continuity (1)
Related Publication 20180244878A1 · Aug 30, 2018