Aluminum alloy wire, aluminum alloy stranded wire, covered electric wire, and wire harness
View Patent ↗The present disclosure provides an aluminum alloy wire or the like which can secure a high conductivity and a moderately low yield strength, and realize both a high elongation and a moderate tensile strength. An aluminum alloy wire of the present disclosure contains 0.10 to 1.00% by mass of Mg, 0.10 to 1.20% by mass of Si, 0.10 to 1.40% by mass of Fe, 0 to 0.10% by mass of Ti, 0 to 0.030% by mass of B, 0 to 1.00% by mass of Cu, 0 to 1.00% by mass of Mn, 0 to 1.00% by mass of Cr, 0 to 0.50% by mass of Zr, and 0 to 0.50% by mass of Ni, the balance being Al and 0.30% by mass or less of impurities. Coarse crystal grains are present in a vertical cross-sectional structure of the wire taken in a lengthwise direction of the wire. The greatest grain size of the coarse crystal grains as measured in the lengthwise direction of the wire is equal to or greater than a diameter of the wire. A proportion of an area of the coarse crystal grains to the total of the areas of all the crystal grains within a range of the vertical cross-sectional structure in which the vertical cross-sectional structure is measured, is 50% or more. Elongation of the wire is 10% or more.
1. An aluminum alloy wire having a chemical composition comprising 0.10 to 1.00% by mass of Mg, 0.10 to 1.20% by mass of Si, 0.10 to 1.40% by mass of Fe, 0 to 0.10% by mass of Ti, 0 to 0.030% by mass of B, 0 to 1.00% by mass of Cu, 0 to 1.00% by mass of Mn, 0 to 1.00% by mass of Cr, 0 to 0.50% by mass of Zr, and 0 to 0.50% by mass of Ni, the balance being Al and 0.30% by mass or less of impurities,
wherein:
coarse crystal grains are present in a vertical cross-sectional structure of the wire taken in a lengthwise direction of the wire;
the greatest grain size of the coarse crystal grains as measured in the lengthwise direction of the wire is equal to or greater than a diameter of the wire;
a proportion of an area of the coarse crystal grains to the total of the areas of all the crystal grains within a range of the vertical cross-sectional structure in which the vertical cross-sectional structure is measured, is 50% or more; and
elongation of the wire is 10% or more.
2. The aluminum alloy wire according to claim 1 , wherein a dispersion density of a Mg—Si-based compound having the maximum dimension of 1 μm or less in the vertical cross-sectional structure is 0.1 grain/μm 2 or more on average.
3. The aluminum alloy wire according to claim 2 ,
wherein:
a film thickness of an oxide layer formed on a surface of the wire is 500 nm or less;
a concentration of each of Mg and Si other than a compound in the vertical cross-sectional structure is 2.0% by mass or less; and
the elongation is 15% or more, 0.2% yield strength is 200 MPa or less, and tension strength is 120 MPa or more.
4. The aluminum alloy wire according to claim 2 ,
wherein:
the proportion of the area of the coarse crystal grains is 70% or more; and
the elongation is 20% or more, 0.2% yield strength is 150 MPa or less, and tension strength is 120 MPa or more.
5. The aluminum alloy wire according to claim 2 , wherein the chemical composition contains one or two selected from the group consisting of 0.001 to 0.100% by mass of Ti and 0.001 to 0.030% by mass of B.
6. The aluminum alloy wire according to claim 2 , wherein the chemical composition contains one or two selected from the group consisting of 0.01 to 1.00% by mass of Cu, 0.01 to 1.00% by mass of Mn, 0.01 to 1.00% by mass of Cr, 0.01 to 0.50% by mass of Zr, and 0.01 to 0.50% by mass of Ni.
7. The aluminum alloy wire according to claim 1 ,
wherein:
a film thickness of an oxide layer formed on a surface of the wire is 500 nm or less;
a concentration of each of Mg and Si other than a compound in the vertical cross-sectional structure is 2.0% by mass or less; and
the elongation is 15% or more, 0.2% yield strength is 200 MPa or less, and tension strength is 120 MPa or more.
8. The aluminum alloy wire according to claim 7 ,
wherein:
the proportion of the area of the coarse crystal grains is 70% or more; and
the elongation is 20% or more, 0.2% yield strength is 150 MPa or less, and tension strength is 120 MPa or more.
9. The aluminum alloy wire according to claim 7 , wherein the chemical composition contains one or two selected from the group consisting of 0.001 to 0.100% by mass of Ti and 0.001 to 0.030% by mass of B.
10. The aluminum alloy wire according to claim 7 , wherein the chemical composition contains one or two selected from the group consisting of 0.01 to 1.00% by mass of Cu, 0.01 to 1.00% by mass of Mn, 0.01 to 1.00% by mass of Cr, 0.01 to 0.50% by mass of Zr, and 0.01 to 0.50% by mass of Ni.
11. The aluminum alloy wire according to claim 1 ,
wherein:
the proportion of the area of the coarse crystal grains is 70% or more; and
the elongation is 20% or more, 0.2% yield strength is 150 MPa or less, and tension strength is 120 MPa or more.
12. The aluminum alloy wire according to claim 11 , wherein the chemical composition contains one or two selected from the group consisting of 0.001 to 0.100% by mass of Ti and 0.001 to 0.030% by mass of B.
13. The aluminum alloy wire according to claim 11 , wherein the chemical composition contains one or two selected from the group consisting of 0.01 to 1.00% by mass of Cu, 0.01 to 1.00% by mass of Mn, 0.01 to 1.00% by mass of Cr, 0.01 to 0.50% by mass of Zr, and 0.01 to 0.50% by mass of Ni.
14. The aluminum alloy wire according to claim 1 , wherein the chemical composition contains one or two selected from the group consisting of 0.001 to 0.100% by mass of Ti and 0.001 to 0.030% by mass of B.
15. The aluminum alloy wire according to claim 1 , wherein the chemical composition contains one or two selected from the group consisting of 0.01 to 1.00% by mass of Cu, 0.01 to 1.00% by mass of Mn, 0.01 to 1.00% by mass of Cr, 0.01 to 0.50% by mass of Zr, and 0.01 to 0.50% by mass of Ni.
16. The aluminum alloy wire according to claim 1 , wherein a total of contents of Fe, Ti, B, Cu, Mn, Cr, Zr, and Ni is 0.10 to 2.00% by mass.
17. The aluminum alloy wire according to claim 1 , wherein a diameter of a strand is 0.1 to 0.5 mm.
18. An aluminum alloy stranded wire obtained by stranding a plurality of the aluminum alloy wires according to claim 1 .
19. A covered electric wire comprising a covering layer at an outer periphery of the aluminum alloy wire according to claim 1 .
20. A wire harness comprising:
the covered electric wire according to claim 19 ; and
a terminal fitted at an end portion of the covered electric wire, the covering layer being removed from the end portion.