Optimization of the cerium-hydrogen redox flow cell
View Patent ↗The Ce—H 2 redox flow cell is optimized using commercially-available cell materials. Cell performance is found to be sensitive to the upper charge cutoff voltage, membrane boiling pretreatment, methanesulfonic-acid concentration, (+) electrode surface area and flow pattern, and operating temperature. Performance is relatively insensitive to membrane thickness, Cerium concentration, and all features of the (−) electrode including hydrogen flow. Cell performance appears to be limited by mass transport and kinetics in the cerium (+) electrode. Maximum discharge power of 895 mW cm −2 was observed at 60° C.; an energy efficiency of 90% was achieved at 50° C. The Ce—H 2 cell is promising for energy storage assuming one can optimize Ce reaction kinetics and electrolyte.
1. A redox flow cell comprising:
a separator;
a negative electrode in contact with hydrogen gas;
a liquid comprising approximately 0.6 M cerium and 3 M to 6 M methanesulfonic acid (MSA); and
a positive electrode comprising at least one metal mesh layer in contact with the liquid, the negative electrode being isolated from the positive electrode by the separator.
2. The redox flow cell of claim 1 , wherein the separator comprises a nanoporous separator.
3. The redox flow cell of claim 1 , wherein the positive electrode comprises a three dimensional porous flow-through structure.
4. The redox flow cell of claim 1 , wherein the positive electrode comprises a stack of metal mesh layers.
5. The redox flow cell of claim 1 , wherein the positive electrode comprises between 1 to 12 metal mesh layers comprising woven platinum meshes.
6. The redox flow cell of claim 1 , wherein the positive electrode comprises a nanostructured thin-film (NSTF) platinum catalyst layer.
7. The redox flow cell of claim 1 , wherein the negative electrode comprises a catalyst layer and a gas diffusion layer, and wherein the catalyst layer is in contact with the separator.
8. The redox flow cell of claim 7 , wherein the negative electrode further comprises a microporous layer, and wherein the microporous layer is disposed between the catalyst layer and the gas diffusion layer.
9. The redox flow cell of claim 7 , wherein the gas diffusion layer comprises carbon paper.
10. The redox flow cell of claim 1 , wherein the separator comprises a proton exchange membrane (PEM).
11. The redox flow cell of claim 1 , wherein the separator is 0.025 millimeters to 0.05 millimeters thick, and wherein the separator comprises a membrane treated by boiling in water.
12. The redox flow cell of claim 1 , wherein the liquid comprises approximately 0.6 M cerium and 5 M methanesulfonic acid (MSA).
13. The redox flow cell of claim 7 , wherein the catalyst layer comprises a 0.4 mg cm −1 platinum-on-carbon catalyst layer.
14. A method comprising:
providing redox flow cell comprising:
a separator,
a negative electrode, and
a positive electrode comprising at least one metal mesh layer, the negative electrode being isolated from the positive electrode by the separator;
contacting the negative electrode with hydrogen gas; and
contacting the positive electrode with a liquid comprising approximately 0.6 M cerium and 3 M to 6 M methanesulfonic acid (MSA), with electricity being generating when the hydrogen gas is oxidized and the cerium is reduced.
15. The method of claim 14 , wherein the liquid comprises approximately 0.6 M cerium and 5 M methanesulfonic acid (MSA).
16. The method of claim 14 , wherein the approximately 0.6 M cerium is produced by dissolving cerium (IV) methanesulfonate in water.
17. The method of claim 14 , wherein the redox flow operates at a temperature range between 21° C. to 60° C.
18. The method of claim 14 , wherein the redox flow cell operates at a temperature range between 50° C. to 60° C.
19. The method of claim 14 , wherein there is no measurable crossover liquid permeating through the separator from a positive electrode side to a negative electrode side when the redox flow cell is in operation.
20. The method of claim 14 , wherein the hydrogen gas is at a specific pressure above ambient pressure.
21. The method of claim 14 , wherein the specific pressure of the hydrogen gas is obtained by electrochemical compression.
22. The method of claim 14 , wherein the hydrogen gas is bubbled through water before contacting the negative electrode with the hydrogen gas.
23. The method of claim 14 , wherein the negative electrode comprises a catalyst layer and a gas diffusion layer, and wherein the catalyst layer is in contact with the separator.