IP Library Granted Patent US 10,428,213
Granted Patent B2
US 10,428,213 · App. 15/520,304 · Granted Oct 1, 2019

(Meth)acrylic resin composition and resin molded article

Inventors: Yutaka Ishihara (Tokyo, JP); Masahiro Nakano (Tokyo, JP); Masanori Suzuki (Tokyo, JP); Hiroshi Okafuji (Tokyo, JP)
Assignee: Mitsubishi Chemical Corporation
C08L33/10B32B27/08C08F220/14C08F220/18C08F265/06C08K5/521C08L33/12C08F2220/1816C08F2220/1825C08F2220/1833C08F2222/1013C08F2800/20C08L2201/02C08L2201/10
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Quick Facts
Patent No.
US 10,428,213
App. No.
15/520,304
Granted
Oct 1, 2019
Kind
B2
Abstract

A (meth)acrylic resin composition containing a (meth)acrylic polymer (P) and a phosphorus atom-containing compound (C), where the (meth)acrylic polymer (P) contains: (1) a repeating unit derived from methyl methacrylate at 19.95 to 84.95% by mass; (2) a repeating unit derived from a (meth)acrylic acid ester (M) having an aromatic hydrocarbon group or an alicyclic hydrocarbon group having from 3 to 20 carbon atoms in a side chain at 15.0 to 80.0% by mass; and (3) a repeating unit derived from a monomer (B) having two or more vinyl groups at 0.05 to 0.40% by mass, and an amount of the phosphorus atom-containing compound (C) with respect to 100 parts by mass of the (meth)acrylic polymer (P) being 5.0 to 35 parts by mass or less.

Claims (37)

1. A (meth)acrylic resin composition comprising a (meth)acrylic polymer (P) and a phosphorus atom-containing compound (C), wherein

the (meth)acrylic polymer (P) comprises

(1) a repeating unit derived from methyl methacrylate at 19.95% by mass or more and 84.95% by mass or less,

(2) repeating units derived from a (meth)acrylic acid ester (M), including

(2-1) a repeating unit derived from a methacrylic acid ester (M1) having an aromatic hydrocarbon group or an alicyclic hydrocarbon group having from 3 to 20 carbon atoms in a side chain at 10% by mass or more and 79.5% by mass or less and

(2-2) a repeating unit derived from an acrylic acid ester (M2) having an aromatic hydrocarbon group or an alicyclic hydrocarbon group having from 3 to 20 carbon atoms in a side chain at 0.50% by mass or more and 20% by mass or less, and

(3) a repeating unit derived from a monomer (B) having two or more vinyl groups at 0.05% by mass or more and 0.40% by mass or less;

a sum of the repeating unit derived from a methacrylic acid ester (M1) and the repeating unit derived from an acrylic acid ester (M2) is 15.0% by mass or more and 80.0% by mass or less; and

an amount of the phosphorus atom-containing compound (C) with respect to 100 parts by mass of the (meth)acrylic polymer (P) is 5.0 parts by mass or more and 35 parts by mass or less.

2. The (meth)acrylic resin composition according to claim 1 , wherein an amount of the repeating unit derived from methyl methacrylate in the (meth)acrylic polymer (P) is 19.95% by mass or more and 79.1% by mass or less and an amount of the repeating units derived from a (meth)acrylic acid ester (M) is 20.5% by mass or more and 80.0% by mass or less.

3. The (meth)acrylic resin composition according to claim 1 , wherein the (meth)acrylic polymer (P) is a polymer which comprises

(1) the repeating unit derived from a methacrylic acid ester (M1) at 10% by mass or more and 79.5% by mass or less and

(2) the repeating unit derived from acrylic acid ester (M2) at 0.50% by mass or more and 20.0% by mass or less as the repeating units derived from a (meth)acrylic acid ester (M) and has

a sum of the repeating unit derived from a methacrylic acid ester (M1) and the repeating unit derived from an acrylic acid ester (M2) of 20.5% by mass or more and 80.0% by mass or less.

4. The (meth)acrylic resin composition according to claim 1 , wherein the methacrylic acid ester (M1) is at least one kind selected from the group consisting of isobornyl methacrylate and cyclohexyl methacrylate.

5. The (meth)acrylic resin composition according to claim 1 , wherein the acrylic acid ester (M2) is at least one kind selected from the group consisting of isobornyl acrylate and cyclohexyl acrylate.

6. The (meth)acrylic resin composition according to claim 1 , comprising a phosphorus atom-containing compound (C) at Y parts by mass with respect to 100 parts by mass of the (meth)acrylic polymer (P), wherein

Y is represented by the following formulas:

5.00≤ Y≤ 13.6 in a case of 15.0≤ X≤ 41.4, and

5.00≤ Y≤ 0.0700 X+ 10.7 in a case of 41.4< X≤ 80.0,

wherein, X (unit: parts by mass) is a content of a repeating unit which is derived from a (meth)acrylic acid ester having an aromatic hydrocarbon group or an alicyclic hydrocarbon group having from 3 to 20 carbon atoms in a side chain and contained in the (meth)acrylic polymer (P) with respect to 100 parts by mass of the (meth)acrylic polymer (P).

7. The (meth)acrylic resin composition according to claim 1 , comprising a phosphorus atom-containing compound (C) at Y parts by mass with respect to 100 parts by mass of the (meth)acrylic polymer (P), wherein

Y is represented by the following formulas:

7.6< Y≤ 35.0 in a case of 15.0≤ X≤ 41.4, and

−0.07 X+ 16.5< Y≤ 35.0 in a case of 41.4< X≤ 80.0,

wherein, X (unit: parts by mass) is a content of a repeating unit which is derived from a (meth)acrylic acid ester having an aromatic hydrocarbon group or an alicyclic hydrocarbon group having from 3 to 20 carbon atoms in a side chain and contained in the (meth)acrylic polymer (P) with respect to 100 parts by mass of the (meth)acrylic polymer (P).

8. The (meth)acrylic resin composition according to claim 1 , comprising a phosphorus atom-containing compound (C) at Y parts by mass with respect to 100 parts by mass of the (meth)acrylic polymer (P), wherein

the (meth)acrylic polymer (P) is a polymer comprising

(1) the repeating unit derived from methyl methacrylate at 19.95% by mass or more and 58.6% by mass or less,

(2) the repeating unit derived from a (meth)acrylic acid ester (M) having an aromatic hydrocarbon group or an alicyclic hydrocarbon group having from 3 to 20 carbon atoms in a side chain at 41% by mass or more and 80% by mass or less, and

(3) the repeating unit derived from a monomer (B) having two or more vinyl groups at 0.05% by mass or more and 0.40% by mass or less, and

Y is represented by the following formula:

−0.07 X+ 16.5≤ Y≤− 0.07 X+ 10.7,

wherein, X (unit: parts by mass) is a content of a repeating unit which is derived from a (meth)acrylic acid ester having an aromatic hydrocarbon group or an alicyclic hydrocarbon group having from 3 to 20 carbon atoms in a side chain and contained in the (meth)acrylic polymer (P) with respect to 100 parts by mass of the (meth)acrylic polymer (P).

9. The (meth)acrylic resin composition according to claim 1 , wherein the monomer (B) is a compound having from 10 to 13 carbon atoms.

10. The (meth)acrylic resin composition according to claim 1 , wherein the monomer (B) is at least one kind selected from the group consisting of ethylene glycol di(meth)acrylate and neopentyl glycol di(meth)acrylate.

11. The (meth)acrylic resin composition according to claim 1 , wherein the phosphorus atom-containing compound (C) contains at least one kind selected from the group consisting of a phosphoric acid ester and a phosphonic acid ester.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 15, 2017
From: ISHIHARA, YUTAKA; NAKANO, MASAHIRO; SUZUKI, MASANORI; OKAFUJI, HIROSHI
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 042379/0356 →
Priority Claims (6)
JP 2014-214176 · Oct 21, 2014 · national
JP 2015-015740 · Jan 29, 2015 · national
JP 2015-035185 · Feb 25, 2015 · national
JP 2015-163651 · Aug 21, 2015 · national
JP 2015-163653 · Aug 21, 2015 · national
JP 2015-163654 · Aug 21, 2015 · national
Continuity (1)
Related Publication 20180223091A1 · Aug 9, 2018