Group III base stocks and lubricant compositions
Disclosed are Group III base stocks comprising greater than or equal to about 90 wt. % saturated hydrocarbons (saturates); a viscosity index from 120 to 145; a unique ratio of molecules with multi-ring naphthenes to single ring naphthenes (2R+N/1RN); a unique ratio of branched carbons to straight chain carbons (BC/SC); a unique ratio of branched carbons to terminal carbons (BC/TC); and unique MRV behavior as a function of base stock naphthene ratio (2R+N/1RN). A method for preparing the base stocks is also disclosed. Also disclosed is a lubricating oil having the base stock as a major component, and an additive as a minor component.
1. A method for producing a diesel fuel and a base stock, comprising:
providing a feed stock comprising a vacuum gas oil feed;
hydrotreating the feed stock under first effective hydrotreating conditions to produce a first hydrotreated effluent;
hydrotreating the first hydrotreated effluent under second effective hydrotreating conditions to produce a second hydrotreated effluent;
fractionating the second hydrotreated effluent to produce at least a first diesel product fraction and a bottoms fraction;
hydrocracking the bottoms fraction under effective hydrocracking conditions to produce a hydrocracked effluent;
dewaxing the hydrocracked effluent under effective catalytic dewaxing conditions to produce a dewaxed effluent, the dewaxing catalyst including at least one non-dealuminated, unidimensional, 10-member ring pore zeolite, and at least one Group VI metal, Group VIII metal or combination thereof;
hydrotreating the dewaxed effluent under third effective hydrotreating conditions to produce a third hydrotreated effluent; and
fractionating the third hydrotreated effluent to form at least a second diesel product fraction and a base stock product fraction, wherein the Group III lubricant base stock product fraction includes greater than or equal to 95 wt. % saturated hydrocarbons, a kinematic viscosity at 100° C. between 5 cSt and 12 cSt and has a ratio of multi-ring naphthenes to single ring naphthenes (2R+N/1RN) of less than about 0.59, and a ratio of branched carbons to straight chain (BC/SC) carbons less than or equal to 0.26.
2. The method of claim 1 , wherein the feedstock has a solvent dewaxed oil feed viscosity index of from about 60 to about 150.
3. The method of claim 1 , wherein the base stock has a ratio of branched chain carbons to terminal carbons (BC/TC) less than or equal to 2.3.
4. The method of claim 1 , wherein the effective hydrotreating conditions include a temperature of from 300° C. to 450° C., hydrogen partial pressure of from 1500 psi to 5000 psi (10.3 MPa to 34.6 MPa), a liquid hourly space velocity of from 0.2 hr−1 to 10 hr−1 , and a hydrogen circulation rate of from 35.6 to 1781 m 3 /m 3 (200 scf/B to 10,000 scf/B).
5. The method of claim 1 , wherein the effective hydrocracking conditions include a temperature of 280° C. to 450° C., a hydrogen partial pressure of 1000 psig to 5000 psig (6.9 MPa to 34.6 MPa), a liquid hourly space velocity of 0.5 h −1 to 10 h −1 , and a hydrogen treat gas rate of from 35.6 m 3 /m 3 to 1781 m 3 /m 3 (200 scf/B to 10,000 scf/B).
6. The method of claim 1 , wherein the dewaxing catalyst comprises a molecular sieve having a SiO 2 :Al 2 O 3 ratio of 200:1 to 30:1 and comprises from 0.1 wt % to 3.33 wt % framework Al 2 O 3 content, the dewaxing catalyst including from 0.1 wt % to 5 wt % platinum.
7. The method of claim 1 , wherein the total conversion of the hydrocracked, dewaxed bottoms relative to the feedstock is 30% to 90%.