Aromatic amine derivative and electroluminescence device using the same
Provided are a novel aromatic amine derivative having a specific structure and an organic electroluminescence device in which an organic thin layer comprising a single layer or plural layers including a light emitting layer is interposed between a cathode and an anode, wherein at least one layer of the above organic thin layer contains the aromatic amine derivative described above in the form of a single component or a mixed component. Thus, the organic electroluminescence device is less liable to be crystallized in molecules, improved in a yield in producing the organic electroluminescence device and extended in a lifetime.
1. An organic electroluminescence device in which an organic thin layer comprising plural layers including at least a light emitting layer and a hole transporting layer is interposed between a cathode and an anode, wherein at least the hole transporting layer contains an aromatic amine derivative represented by the following Formula (5) in the form of a single component or a mixed component:
wherein at least one of Ar 7 to Ar 9 is represented by the following Formula (3):
wherein R 4 to R 6 each are independently a hydrogen atom, or a non-substituted aryl group having 5 to 50 ring carbon atoms;
X is an oxygen atom;
f and h each are an integer of 0 to 4; g is an integer of 0 to 3; and i is an integer of 1 to 3;
in Formula (5), among Ar 7 to Ar 9 , the groups which are not represented by Formula (3) each are independently a substituted or non-substituted aryl group having 5 to 50 ring carbon atoms.
2. The organic electroluminescence device as described in claim 1 , wherein styrylamine and/or arylamine is contained in the light emitting layer described above.
3. The organic electroluminescence device as described in claim 1 emitting blue light.
4. The organic electroluminescence device as described in claim 1 , wherein R 4 to R 6 are independently selected from the group consisting of a phenyl group, a naphthyl group, a biphenyl group, an anthranyl group, a phenanthryl group, a pyrenyl group, a chrysenyl group, a fluoranthenyl group and a fluorenyl group.
5. The organic electroluminescence device as described in claim 1 , wherein R 4 to R 6 are independently selected from the group consisting of a phenyl group, a naphthyl group, or a biphenyl group.
6. The organic electroluminescence device as described in claim 1 , wherein among Ar 7 to Ar 9 , the groups which are not represented by Formula (3) each are independently selected from the group consisting of a phenyl group, a naphthyl group, a biphenyl group, an anthranyl group, a phenanthryl group, a pyrenyl group, a chrysenyl group, a fluoranthenyl group and a fluorenyl group, each being optionally substituted.
7. The organic electroluminescence device as described in claim 1 , wherein among Ar 7 to Ar 9 , the groups which are not represented by Formula (3) each are independently selected from the group consisting of a phenyl group, a biphenylyl group, a terphenylyl group and, 9,9-dimethyl fluorenyl group, each being optionally substituted.
8. The organic electroluminescence device as described in claim 1 , wherein among Ar 7 to Ar 9 , the groups which are not represented by Formula (3) each are independently selected from the group consisting of a phenyl group, a naphtyl group, and a biphenylyl group, each being optionally substituted.
9. The organic electroluminescence device as described in claim 1 , wherein Ar 7 is represented by Formula (3), Ar 8 is selected from the group consisting of a phenyl group, a biphenylyl group, a terphenylyl group and, 9,9-dimethyl fluorenyl group, each being optionally substituted, and Ar 9 is selected from the group consisting of a phenyl group, a biphenylyl group, a terphenylyl group and, 9,9-dimethyl fluorenyl group, each being optionally substituted.
10. The organic electroluminescence device as described in claim 1 , wherein among Ar 7 to Ar 9 , the groups which are not represented by Formula (3) each are independently an non-substituted aryl group having 5 to 50 ring carbon atoms.
11. The organic electroluminescence device as described in claim 1 , wherein among Ar 7 to Ar 9 , the groups which are not represented by Formula (3) each are independently selected from the group consisting of a non-substituted phenyl group, a non-substituted biphenylyl group, a non-substituted terphenylyl group, and a non-substituted 9,9-dimethyl fluorenyl group.
12. The organic electroluminescence device as described in claim 1 , wherein Ar 7 is represented by Formula (3), Ar 8 is selected from the group consisting of non-substituted phenyl group, a non-substituted biphenylyl group, a non-substituted terphenylyl group, and a non-substituted 9,9-dimethyl fluorenyl group, and
Ar 9 is selected from the group consisting of a non-substituted phenyl group, a non-substituted biphenylyl group, a non-substituted terphenylyl group, and a non-substituted 9,9-dimethyl fluorenyl group.
13. The organic electroluminescence device as described in claim 1 , wherein i is 1.
14. The organic electroluminescence device as described in claim 1 , wherein f is 0.
15. The organic electroluminescence device as described in claim 1 , wherein g is 0.
16. The organic electroluminescence device as described in claim 1 , wherein h is 0.
17. The organic electroluminescence device as described in claim 1 , wherein f and g are 0.
18. The organic electroluminescence device as described in claim 1 , wherein f, g, and h are 0.
19. The organic electroluminescence device as described in claim 1 , wherein Ar 7 to Ar 9 are represented by the following Formula (3).