Tire with tread with oxidized carbon black
This invention relates to a tire with a tread of rubber composition with reinforcing filler containing oxidized rubber reinforcing carbon black together with tris (2-ethyl hexyl) phosphate. In one embodiment, the invention relates to a truck tire intended for heavy duty performance with a tread rubber composition comprised of natural cis 1,4-polyisoprene rubber containing reinforcing filler comprised of oxidized rubber reinforcing carbon black together with tris (2-ethyl hexyl) phosphate.
1. A pneumatic tire having a circumferential rubber tread of a rubber composition comprised of, based on parts by weight per 100 parts by weight elastomer (phr):
(A) 100 phr of cis 1,4-polyisoprene natural rubber,
(B) about 25 to about 125 phr of reinforcing filler comprised of about 55 to about 100 weight percent rubber reinforcing black comprised of from about 20 to about 100 weight percent surface oxidized carbon black and about 10 to about 50 phr of precipitated silica together with silica coupler having a moiety reactive with hydroxyl groups on said precipitated silica and another different moiety interactive with said diene-based elastomers, and
(C) 1 to 5 phr of tris (2-ethyl hexyl) phosphate.
2. The tire of claim 1 wherein said oxidized carbon black is at least one of hydrogen peroxide or ozone treated rubber reinforcing carbon black.
3. The tire of claim 1 wherein said oxidized carbon black is a rubber reinforcing carbon black containing at least one of carboxyl and hydroxyl groups on its surface.
4. The tire of claim 1 wherein said precipitated silica is a product of reaction of said precipitated silica and said silica coupler within said rubber composition.
5. The tire of claim 1 wherein said silica coupler is comprised of:
(A) bis(3-trialkoxysilylalkyl) polysulfide having an average of from 2 to about 4 connecting sulfur atoms in its polysulfidic bridge, or
(B) alkoxyorganomercaptosilane.
6. The tire of claim 5 wherein said silica coupler is comprised of bis(3-triethoxysilylpropyl) polysulfide.
7. The tire of claim 5 wherein said coupler is comprised of alkoxyorganomercaptosilane.
8. The tire of claim 1 wherein said precipitated silica is a composite of said precipitated silica pre-reacted with said silica coupler.
9. The tire of claim 8 wherein said silica coupler is an alkoxyorganomercaptosilane.
10. The tire of claim 8 wherein said rubber composition contains additional precipitated silica and/or additional silica coupler.