Lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire, and preparation process thereof
A lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire, and a preparation process thereof. The aluminum wire is mainly composed of aluminum, boron, zirconium, iron, lanthanum, and inevitable impurity elements, and the preparation process for the wire is as follows: melting industrial pure aluminum; then adding intermediate alloys of boron, zirconium, iron, and lanthanum to the melt; performing stirring, refining, furnace front component rapid analysis, component adjustment, standing, deslagging, and rapid cooling casting to obtain an aluminum alloy blank; and performing annealing, extrusion, and drawing on the cast blank to obtain an aluminum alloy monofilament. The wire obtained has density less than or equal to 2.714 g/cm3, electrical conductivity greater than or equal to 62% IACS, a short-term heat-resistance temperature as high as 230° C., a long-term heat-resistance temperature as high as 210° C., and tensile strength greater than or equal to 170 MPa.
1. A lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire comprising the following components in percentage by weight:
B 0.04-0.10 wt. %;
Zr 0.10-0.15 wt. %;
Fe 0.10-0.20 wt. %;
La 0.05-0.30 wt. %; and
inevitable titanium, vanadium, chromium, and manganese with a total content less than 0.01 wt. %, and aluminum as the remaining.
2. The lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 1 , comprising the following components in percentage by weight:
B 0.045-0.095 wt. %;
Zr 0.10-0.15 wt. %;
Fe 0.10-0.20 wt. %;
La 0.05-0.30 wt. %; and
inevitable titanium, vanadium, chromium, and manganese with a total content less than 0.01 wt. %, and aluminum as the remaining.
3. The lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 1 wherein during casting, cooling is performed to a room temperature at a rate of 20-300° C./s and then high temperature annealing is performed at 480° C.-500° C. for 1-10 h.
4. The lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 1 wherein the wire has nanoscale spherical Al 3 (Er, Zr) composite particles.
5. The lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 4 , wherein the nanoscale spherical Al 3 (Er, Zr) composite particles are of an L12 structure coherent with a matrix.
6. The lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 1 wherein the wire has density less than or equal to 2.714 g/cm 3 , electrical conductivity greater than 62% IACS at 20° C., a short-term heat-resistance temperature as high as 230° C., a long-term heat-resistance temperature as high as 210° C., and tensile strength greater than or equal to 170 MPa.
7. A method for preparing a lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire, comprising: separately selecting industrial pure aluminum and aluminum-boron, aluminum-zirconium, aluminum-iron and aluminum-lanthanum intermediate alloys according to a designed material component ratio; melting the industrial pure aluminum at 740-780° C.; then adding the intermediate alloys; performing refining and rapid cooling casting to obtain a cast blank; and perform annealing, extrusion, and drawing on the blank to obtain an aluminum alloy monofilament.
8. The method for preparing a lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 7 , wherein during the casting, an ingot blank is obtained by common casting or semicontinuous casting; or a rod blank is obtained by continuous casting.
9. The method for preparing a lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 7 , wherein during the casting, the cast ingot is cooled to a room temperature at a rate of 20-300° C./s.
10. The method for preparing a lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 9 , wherein water-cooling casting is employed during the casting.
11. The method for preparing a lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 8 , wherein the ingot blank or the rod blank is subject to the annealing at a temperature of 480° C.-500° C., and is subject to furnace cooling after thermal insulation for 2-10 h.
12. The method for preparing a lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 8 , wherein the ingot blank is subject to hot extrusion at a hot extrusion temperature of 300-450° C.; and the rod blank is subject to continuous extrusion at a room temperature.
13. The method for preparing a lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 12 , wherein an extrusion ratio for the hot extrusion or the continuous extrusion at the room temperature is greater than or equal to 80, and a total extrusion deformation amount is greater than or equal to 80%.
14. The method for preparing a lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 7 , wherein multiple passes of drawing are performed after the extrusion, a coefficient of elongation for the passes being 1.2-1.5 and an accumulative total coefficient of elongation being 5.5-10.5; during the drawing, lubrication and cooling are performed with a common lubricating oil or an emulsion; and a temperature of the aluminum wire is controlled to be less than or equal to 180° C.
15. The method for preparing a lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 14 , wherein the prepared wire has density less than or equal to 2.714 g/cm 3 , electrical conductivity greater than 62% IACS at 20° C., a short-term heat-resistance temperature as high as 230° C., a long-term heat-resistance temperature as high as 210° C., and tensile strength greater than or equal to 170 MPa.
16. The lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 2 , wherein during casting, cooling is performed to a room temperature at a rate of 20-300° C./s and then high temperature annealing is performed at 480° C.-500° C. for 1-10 h.
17. The lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 2 , wherein the wire has nanoscale spherical Al 3 (Er, Zr) composite particles.
18. The lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to claim 2 , wherein the wire has density less than or equal to 2.714 g/cm 3 , electrical conductivity greater than 62% IACS at 20° C., a short-term heat-resistance temperature as high as 230° C., a long-term heat-resistance temperature as high as 210° C., and tensile strength greater than or equal to 170 MPa.
19. The method for preparing a lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to any one of claims 8 , wherein multiple passes of drawing are performed after the extrusion, a coefficient of elongation for the passes being 1.2-1.5and an accumulative total coefficient of elongation being 5.5-10.5; during the drawing, lubrication and cooling are performed with a common lubricating oil or an emulsion; and a temperature of the aluminum wire is controlled to be less than or equal to 180° C.
20. The method for preparing a lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to any one of claims 9 , wherein multiple passes of drawing are performed after the extrusion, a coefficient of elongation for the passes being 1.2-1.5 and an accumulative total coefficient of elongation being 5.5-10.5; during the drawing, lubrication and cooling are performed with a common lubricating oil or an emulsion; and a temperature of the aluminum wire is controlled to be less than or equal to 180° C.
21. The method for preparing a lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to any one of claims 10 , wherein multiple passes of drawing are performed after the extrusion, a coefficient of elongation for the passes being 1.2-1.5 and an accumulative total coefficient of elongation being 5.5-10.5; during the drawing, lubrication and cooling are performed with a common lubricating oil or an emulsion; and a temperature of the aluminum wire is controlled to be less than or equal to 180° C.
22. The method for preparing a lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to any one of claims 11 , wherein multiple passes of drawing are performed after the extrusion, a coefficient of elongation for the passes being 1.2-1.5 and an accumulative total coefficient of elongation being 5.5-10.5; during the drawing, lubrication and cooling are performed with a common lubricating oil or an emulsion; and a temperature of the aluminum wire is controlled to be less than or equal to 180° C.
23. The method for preparing a lightweight, high-conductivity, heat-resistant, and iron-containing aluminum wire according to any one of claims 12 , wherein multiple passes of drawing are performed after the extrusion, a coefficient of elongation for the passes being 1.2-1.5 and an accumulative total coefficient of elongation being 5.5-10.5; during the drawing, lubrication and cooling are performed with a common lubricating oil or an emulsion; and a temperature of the aluminum wire is controlled to be less than or equal to 180° C.