IP Library Granted Patent US 10,465,131
Granted Patent B2
US 10,465,131 · App. 14/902,068 · Granted Nov 5, 2019

Process for the production of light olefins and aromatics from a hydrocarbon feedstock

Inventor: Arno Johannes Maria Oprins (Maastricht, NL)
Assignees: SAUDI BASIC INDUSTRIES CORPORATION; SABIC GLOBAL TECHNOLOGIES B.V.
C10G69/06C10G65/10C10G67/0445C10G69/00C10G2300/1044C10G2300/1059C10G2400/20C10G2400/30Y02P30/40
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Quick Facts
Patent No.
US 10,465,131
App. No.
14/902,068
Granted
Nov 5, 2019
Kind
B2
Abstract

The present invention relates to a process for increasing the production of a light olefin hydrocarbon compound from a hydrocarbon feedstock, comprising the following steps of: (a) feeding a hydrocarbon feedstock into a reaction area for ringopening (b) separating reaction products, which are generated from said reaction area, into an overhead stream and a side stream; (c) feeding the side stream from (b) to a gasoline hydrocracker (GHC) unit, (d) separating reaction products of said GHC of step (c) into an overhead stream, which contains hydrogen, methane, ethane, and liquefied petroleum gas, and a stream, which contains aromatic hydrocarbon compounds, and a small amount of hydrogen and non-aromatic hydrocarbon compounds, (e) feeding the overhead stream from the gasoline hydrocracker (GHC) unit into a steam cracker unit.

Claims (11)

1. A process for increasing the production of a light olefin hydrocarbon compound from a hydrocarbon feedstock, consisting of the steps of:

feeding a hydrocarbon feedstock into a reaction area for ring opening, wherein the process conditions prevailing in said reaction area for ring opening are a temperature from 300° C. to 500° C. and a pressure from 2 to 10 MPa together with from 100 to 300 kg of hydrogen per 1,000 kg of feedstock over an aromatic hydrogenation catalyst, wherein said aromatic hydrogenation catalyst comprises from 0.0001 to 5 weight % of one or more metals selected from the group consisting of Ni, W, and Mo,

passing the resulting stream to a ring cleavage unit at a temperature from 200° C. to 600° C. and a pressure from 1 to 12 MPa together with from 50 to 200 kg of hydrogen per 1,000 kg of said resulting stream over a ring cleavage catalyst comprising from 0.0001 to 5 weight % of one or more metals selected from the group consisting of Pd, Ru, Ir, Os, Cu, Co, Ni, Pt, Fe, Zn, Ga, In, Mo, W, and V on a support selected from the group of synthetic zeolites having the characteristics of ZSM-5, ZSM-11, ZSM-12, ZSM-23, Beta and MCM-22;

separating reaction products, which are generated from said reaction area, into an overhead stream and a side stream;

feeding the side stream from (b) to a gasoline hydrocracker (GHC) unit operating at a temperature range of 400-580° C., a Weight Hourly Space Velocity (WHSV) of 0.1-10 h−1 and a pressure range of 0.3-5 MPa,

wherein said gasoline hydrocracker (GHC) unit is operated at a temperature higher than said ring opening reaction area, and wherein said gasoline hydrocracker (GHC) unit is operated at a pressure lower than said ring opening reaction area,

separating reaction products of said GHC of step (c) into an overhead gas stream, comprising C2-C4 paraffins, hydrogen and methane and a stream comprising aromatic hydrocarbon compounds and non-aromatic hydrocarbon compounds,

feeding the overhead gas stream from the gasoline hydrocracker (GHC) unit into a steam cracker unit;

separating reaction products of said steam cracking unit into an overhead stream, comprising C2-C6 alkanes, a middle stream comprising C2-olefins, C3-olefins and C4-olefins, and a first bottom stream comprising predominantly carbon black oil (CBO) and cracked distillates (CD), and a second bottom stream comprising aromatic hydrocarbon compounds and non-aromatic hydrocarbon compounds; and

feeding said first bottom stream into said reaction area for ring opening;

wherein the hydrocarbon feedstock consists of a fraction of at least one member selected from the group consisting of a conventional petroleum having an API gravity of more than 20° API as measured by the ASTM D287 standard and a light crude oil having an API gravity of more than 30° API.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 30, 2015
From: OPRINS, ARNO JOHANNES MARIA
To: SAUDI BASIC INDUSTRIES CORPORATION; SABIC GLOBAL TECHNOLOGIES B.V.
Reel/Frame 037398/0646 →
Priority Claims (1)
EP 13174767 · Jul 2, 2013 · regional
Continuity (1)
Related Publication 20170009157A1 · Jan 12, 2017