Electrophotographic composition
The present disclosure relates to an electrophotographic composition that comprises a polymer resin mixture and a liquid carrier. The polymer resin mixture comprises (i) an olefin polymer A having acid and/or ester side groups and a melt index of 22 to 100 g/10 min; and (ii) an olefin polymer B having a melt index of 1 to 20 g/10 min. The olefin polymer B forms 1 to 50 weight % of the polymer resin mixture.
1. A liquid electrophotographic varnish composition consisting of:
a polymer resin mixture consisting of:
(i) an olefin polymer A having acid and/or ester side groups and a melt index of 22 to 100 g/10 min, wherein the olefin polymer A forms 50 to 99 weight % of the polymer resin mixture or a blend of olefin polymers A; and
(ii) an olefin polymer B, wherein the olefin polymer B is a terpolymer of a) an olefin, b) an acrylic acid, methacrylic acid, an acrylate, or methacrylate, and c) a polar monomer selected from the group consisting of glycidyl methacrylate and maleic anhydride, wherein the olefin polymer B has a melt index of 1 to 20 g/10 min, and wherein the olefin polymer B forms 1 to 50 weight % of the polymer resin mixture; and
a liquid carrier.
2. The composition as claimed in claim 1 , wherein the olefin polymer A has a melting point of greater than 78 degrees C. and the olefin polymer B has a melting point of less than 75 degrees C.
3. The composition as claimed in claim 1 , wherein the olefin polymer B forms 5 to 25 weight % of the polymer resin mixture.
4. The composition as claimed in claim 1 , wherein the olefin polymer B has a melting point of 60 to 70 degrees C.
5. The composition as claimed in claim 1 , wherein the olefin polymer B is soluble in the liquid carrier.
6. The composition as claimed in claim 1 , wherein the olefin polymer B swells by at least 70% when soaked in the liquid carrier at a temperature of 45 degrees for 96 hours.
7. The composition as claimed in claim 1 , wherein the olefin polymer B has a melt index of 1 to 10 g/10 min.
8. The composition as claimed in claim 1 , wherein the terpolymer includes ethylene as the olefin, methyl acrylate as the acrylate, and glycidyl methacrylate as the polar monomer.
9. The composition as claimed in claim 1 , wherein the olefin polymer A is a copolymer of ethylene and acrylic acid or methacrylic acid.
10. The composition as claimed in claim 1 , wherein the olefin polymer A has a melt index of 25 g/10 min to 70 g/10 min.
11. The composition as claimed in claim 1 , wherein the blend of olefin polymers A consists of a first polymer having acid and/or ester side groups and a melt index of 22 to 30 g/10 min and a second polymer having acid and/or ester side groups and a melt index of 50 to 80 g/10 min.
12. The composition as claimed in claim 1 , wherein the olefin polymer A has an olefin content of 78 to 90 weight % and the olefin polymer B has an olefin content of 60 to 70 weight %.
13. A method of electrophotographically printing an image on a substrate, said method comprising:
electrophotographically printing an electrophotographic ink composition onto the substrate to form an image; and
electrophotographically printing the liquid electrophotographic varnish composition according to claim 1 over the image.
14. The composition as claimed in claim 1 , wherein the terpolymer includes ethylene as the olefin, the methacrylic acid, and glycidyl methacrylate as the polar monomer.
15. The composition as claimed in claim 1 , wherein the terpolymer includes ethylene as the olefin, ethyl acrylate as the acrylate, and maleic anhydride as the polar monomer.
16. The composition as claimed in claim 1 , wherein the terpolymer includes:
from 60 to 78 weight % of the olefin;
from about 20 to 35 weight % of the acrylic acid, the methacrylic acid, the acrylate, or the methacrylate; and
from about 0.1 to about 10 weight % of the polar monomer.
17. The composition as claimed in claim 1 wherein:
wherein the blend of olefin polymers A consists of a first polymer and a second polymer;
the first polymer is a copolymer of ethylene and methacrylic acid; and
the second polymer is copolymer of ethylene and acrylic acid.
18. A method of forming a liquid electrophotographic varnish composition, said method comprising:
melting (i) an olefin polymer A having acid and/or ester side groups and a melt index of 22 to 100 g/10 min; and (ii) an olefin polymer B to form a polymer resin mixture, wherein the olefin polymer B is a terpolymer of a) an olefin, b) an acrylic acid, methacrylic acid, an acrylate, or methacrylate, and c) a polar monomer selected from the group consisting of glycidyl methacrylate and maleic anhydride, wherein the olefin polymer B has a melt index of 1 to 20 g/10 min, and wherein the olefin polymer A forms 50 to 99 weight % of the polymer resin mixture and the olefin polymer B forms 1 to 50 weight % of the polymer resin mixture;
allowing the polymer resin mixture to cool;
grinding the polymer resin mixture to form particles consisting of the olefin polymer A and the olefin polymer B; and
dispersing the particles in a liquid carrier to form the liquid electrophotographic varnish composition consisting of the particles and the liquid carrier.