Vehicle mechanical component and piston
This vehicle mechanical component includes a mechanical component body, a heat insulating layer formed on the mechanical component body, and a protective layer formed on the heat insulating layer and including an inorganic compound that includes an alkoxide and scale-like inorganic solid particles dispersed in the inorganic compound.
1. A vehicle mechanical component comprising:
a mechanical component body;
a heat insulating layer formed on the mechanical component body; and
a protective layer formed on the heat insulating layer and including an inorganic compound that includes an alkoxide and scale-like inorganic solid particles dispersed in the inorganic compound, wherein
the protective layer further includes a void elongated in a transverse direction perpendicular to a thickness direction of the protective layer.
2. The vehicle mechanical component according to claim 1 , wherein
the scale-like inorganic solid particles are made of mica, talc, or wollastonite.
3. The vehicle mechanical component according to claim 1 , wherein
the void is formed between layers of the scale-like inorganic solid particles stacked in the protective layer.
4. The vehicle mechanical component according to claim 1 , wherein
a binder including a coupling agent and having an amino group is dispersed in the inorganic compound of the protective layer, and
the amino group of the binder and a constituent component of the heat insulating layer bind to each other.
5. The vehicle mechanical component according to claim 1 , wherein
the heat insulating layer includes a first heat insulating layer formed on the mechanical component body and a second heat insulating layer formed on a surface of the first heat insulating layer and including an inorganic compound, and
a functional group that binds to a constituent component of the second heat insulating layer is provided on the surface of the first heat insulating layer on a side of the second heat insulating layer by modification processing using an organic metallic compound.
6. The vehicle mechanical component according to claim 1 , wherein
the heat insulating layer includes a first heat insulating layer formed on the mechanical component body and a second heat insulating layer formed on a surface of the first heat insulating layer, and
a recess that the second heat insulating layer enters is provided on the surface of the first heat insulating layer on a side of the second heat insulating layer.
7. The vehicle mechanical component according to claim 1 , wherein
the heat insulating layer includes an anodized coating layer formed on a surface of the mechanical component body, and the anodized coating layer includes a micrometer-sized micropore extending from a surface thereof on a side of the protective layer and a nanometer-sized nanopore extending from the surface thereof on the side of the protective layer, and
an amount of the inorganic compound impregnated into the micropore and the nanopore is adjusted such that a void content of the micropore is larger than a void content of the nanopore.
8. The vehicle mechanical component according to claim 1 , wherein
the scale-like inorganic solid particles are dispersed in the inorganic compound to be at least 35 vol % and not more than 80 vol %.
9. The vehicle mechanical component according to claim 1 , wherein
the heat insulating layer includes a first heat insulating layer, formed on the mechanical component body, in which first heat insulating layer hollow particles are dispersed and a second heat insulating layer formed on a surface of the first heat insulating layer.
10. The vehicle mechanical component according to claim 9 , further comprising a primer layer, disposed on a surface of the mechanical component body between the mechanical component body and the first heat insulating layer, in which neither hollow particles nor solid particles are dispersed.
11. The vehicle mechanical component according to claim 10 , wherein
both a thickness of the first heat insulating layer and a thickness of the second heat insulating layer are larger than a thickness of the protective layer, and are larger than a thickness of the primer layer.
12. The vehicle mechanical component according to claim 9 , wherein
the second heat insulating layer includes a heat insulating layer inorganic compound including an alkoxide or an alkaline silicate and second heat insulating layer hollow particles dispersed in the heat insulating layer inorganic compound.
13. The vehicle mechanical component according to claim 1 , wherein
a thickness of the protective layer is at least 10 μm and not more than 500 μm.
14. A piston comprising:
a piston body;
a heat insulating layer formed on the piston body; and
a protective layer formed on the heat insulating layer and including an inorganic compound that includes an alkoxide and scale-like inorganic solid particles dispersed in the inorganic compound, wherein
the protective layer further includes a void elongated in a transverse direction perpendicular to a thickness direction of the protective layer.
15. The piston according to claim 14 , wherein
the scale-like inorganic solid particles are made of mica, talc, or wollastonite.
16. The piston according to claim 14 , wherein
the void is formed between layers of the scale-like inorganic solid particles stacked in the protective layer.
17. The piston according to claim 14 , wherein
a binder including a coupling agent and having an amino group is dispersed in the inorganic compound of the protective layer, and
the amino group of the binder and a constituent component of the heat insulating layer bind to each other.
18. The piston according to claim 14 , wherein
the heat insulating layer includes a first heat insulating layer formed on the piston body and a second heat insulating layer formed on a surface of the first heat insulating layer and including an inorganic compound, and
a functional group that binds to a constituent component of the second heat insulating layer is provided on the surface of the first heat insulating layer on a side of the second heat insulating layer by modification processing using an organic metallic compound.
19. The piston according to claim 14 , wherein
the heat insulating layer includes a first heat insulating layer formed on the piston body and a second heat insulating layer formed on a surface of the first heat insulating layer, and
a recess that the second heat insulating layer enters is provided on the surface of the first heat insulating layer on a side of the second heat insulating layer.
20. The piston according to claim 14 , wherein
the heat insulating layer includes an anodized coating layer formed on a surface of the piston body, and the anodized coating layer includes a micrometer-sized micropore extending from a surface thereof on a side of the protective layer and a nanometer-sized nanopore extending from the surface thereof on the side of the protective layer, and
an amount of the inorganic compound impregnated into the micropore and the nanopore is adjusted such that a void content of the micropore is larger than a void content of the nanopore.