Manufacturing method of organic light emitting diode display panel and organic light emitting diode display panel
The present invention provides a manufacturing method of an OLED display panel and an OLED display panel. The manufacturing method of the OLED display panel of the present invention utilizes an inverted OLED element and manufactures an interface modification layer between the cathode of the OLED element and the light emitting layer by ink jet printing with an interface modification printing liquid. The interface modification printing liquid comprises an electron transporting material, metal nanoparticles which are surface-modified, a surface tension modifier and a viscosity modifier. The interface modification layer is a material layer comprising the electron transporting material and the metal nanoparticles. The electron transporting material can enhance the injection and transport of carriers from the cathode. The strong local electric field generated by the metal nanoparticles with the surface plasma resonance can enhance the injection efficiency of the electrons.
1. An organic light emitting diode display panel, comprising a substrate and a plurality of organic light emitting diode elements, the organic light emitting diode element is an inverted organic light emitting diode element and comprises a cathode, a light emitting layer and an anode from bottom to top in order, an interface modification layer is configured between the cathode and the light emitting layer; wherein
the interface modification layer is formed by ink jet printing with an interface modification printing liquid, wherein the interface modification printing liquid comprises an electron transporting material, metal nanoparticles, a surface tension modifier and a viscosity modifier, wherein the metal nanoparticles are surface-modified metal nanoparticles to inhibit agglomeration of the metal nanoparticles and to enhance a solubility of the metal nanoparticles and the interface modification layer comprises the electron transporting material and the metal nanoparticles.
2. The organic light emitting diode display panel according to claim 1 , wherein the metal nanoparticles are gold nanoparticles, silver nanoparticles or copper nanoparticles;
the metal nanoparticles are metal nanoparticles which are modified by organic amine in the interface modification printing liquid;
the electron transporting material is zinc oxide or titanium oxide;
the surface tension modifier is a combination of one or more of a co-solvent, a surfactant, an imidazole and a derivative thereof, phenol, and hydroquinone;
the viscosity modifier is a combination of one or more of alcohols, ethers, esters, phenols and amines;
a material of the anode comprises at least one of gold and silver.
3. The organic light emitting diode display panel according to claim 1 , further comprising a pixel definition layer configured on the substrate, wherein a plurality of through holes are spaced and configured in the pixel definition layer and the plurality of organic light emitting diode elements are respectively arranged in the plurality of through holes;
The organic light emitting diode element comprises a cathode, an interface modification layer, a light emitting layer, a hole transporting layer and an anode from bottom to top in order.
4. The organic light emitting diode display panel according to claim 3 , wherein a material of the cathodes is a transparent conductive metal oxide substance; in the interface modification layer, a material of the electron transporting layers is zinc oxide and the metal nanoparticles are gold nanoparticles; a material of the light emitting layers comprises poly(9,9-noctylfluorene-2,7-diyl); a material of the hole transporting layers is molybdenum oxide; a material of the anodes is silver.