Bi-nuclear main group metal phosphorescent emitter
A bi-nuclear phosphorescent emitter according to the following formula is disclosed. The emitter may include metal atoms M 1 and M 2 , fluorescent emitter ligands L F , L F ′, terminal ligands L T , L T ′, and bridging ligands L V , L V ′, wherein M 1 and M 2 are In, Tl, Sn, Pb, Sb, and Bi; L F and L F ′ are comprise substituted or non-substituted C6-C70 aromatics or heteroaromatics; L V and L V ′ are fluorinated or non-fluorinated, bi-dentate C2-C30 heteroalkyl or heteroaromatics; L T and L T ′ are fluorinated or non-fluorinated, mono-, bi-, or tri-dentate C2-C30 O—, S—, N, heteroalkyl or heteroaromatics; and n and m are 1 or 2 independently of one another.
1. A bi-nuclear phosphorescent emitter according to the following formula
wherein the emitter comprises metal atoms M 1 and M 2 , fluorescent emitter ligands L F , L F ′, terminal ligands L T , L T ′, and bridging ligands L V , L V ′,
wherein each of M 1 and M 2 is an element selected from the group consisting of In, Tl, Sn, Pb, Sb, and Bi;
wherein each of L F , L F ′ is selected from the group consisting of 4,7-di(9H-carbazol-9-yl)-1,10-phenanthroline, 2,6-bis(3-(9H-carbazol-9-yl)phenyl)pyridine, and 3,5-bis(3-(9H-carbazol-9-yl)phenyl)pyridine;
wherein each of L V and L V ′ is a compound selected from the group consisting of fluorinated and non-fluorinated, bi-dentate C2-C30 heteroalkyl and heteroaromatics;
wherein each of L T and L T ′ is a compound selected from the group consisting of fluorinated and non-fluorinated, mono-, bi-, or tri-dentate C2-C30 O—, S—, N—, heteroalkyl or heteroaromatics; and
wherein n is 1 or 2, and m is 1 or 2.
2. The emitter of claim 1 , wherein:
M 1 and M 2 are selected independently of one another from the group consisting of Sb, As, and Bi; and
n, m=2.
3. The emitter of claim 1 , wherein:
M 1 and M 2 are selected independently of one another from the group consisting of Pb and Sn.
4. The emitter of claim 1 , wherein the emitter is a homonuclear emitter with M 1 =M 2 =Bi.
5. The emitter of claim 1 , wherein distances between at least one metal atom and the ligands L V , L V ′, L T , L T ′ coordinated thereon are greater than or equal to 2.2 Å and less than or equal to 3.0 Å.
6. The emitter of claim 1 , wherein at least one of L V , L V ′ is selected from the group consisting of fluorinated and non-fluorinated C2-C30 O—, S—, N—, heteroalkyl, heterocycloalkyl, and heteroaromatics.
7. The emitter of claim 1 , wherein the emitter corresponds to the following formula:
wherein R 1 , R 2 are selected independently of one another from the group consisting of fluorinated and non-fluorinated C1-C30 alkyl, cycloalkyl, aryl, heteroalkyl, heterocycloalkyl, and heteroaryl; and
wherein E 1 , E 2 , E 3 , E 4 are selected independently of one another from the group consisting of O, S, and NR, wherein R═H, D.
8. The emitter of claim 1 , wherein at least one of the ligands L V , L V ′ is selected from the group consisting of fluorinated and non-fluorinated aliphatic and aromatic C2-C30 carboxylates.
9. The emitter of claim 1 , wherein at least one of the ligands L V , L V ′ is selected from the group consisting of acetate, fluoroacetate, fluorobenzoate, fluoromethylbenzoate, fluoromethylfluorobenzoate, di-fluoromethyl-benzoate, and di-fluoromethyl-fluorobenzoate.
10. The emitter of claim 1 , wherein at least one of the ligands L T , L T ′ is selected from the group consisting of fluorinated or non-fluorinated aliphatic and aromatic C2-C30 alcoholates, carboxylates, benzoates, v acetylacetonates.
11. The emitter of claim 1 , wherein at least one of the ligands L T , L T ′ is selected from the group consisting of acetate, fluoroacetate, fluorobenzoate, fluoromethylbenzoate, fluoromethylfluorobenzoate, di-fluoromethyl-benzoate, and di-fluoromethyl-fluorobenzoate.
12. The emitter of claim 1 , wherein each of the ligands L V , L V ′, L T , L T ′ is selected from the group comprising acetate, fluoroacetate, fluorobenzoate, fluoromethylbenzoate, fluoromethylfluorobenzoate, di-fluoromethyl-benzoate, and di-fluoromethyl-fluorobenzoate.