IP Library Granted Patent US 10,530,013
Granted Patent B2
US 10,530,013 · App. 15/724,668 · Granted Jan 7, 2020

Method of manufacturing non-aqueous electrolyte secondary battery

Inventors: Hiroki Iguchi (Nagoya, JP); Hideaki Fujita (Kyotanabe, JP)
Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
H01M10/058H01M10/0569
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Quick Facts
Patent No.
US 10,530,013
App. No.
15/724,668
Granted
Jan 7, 2020
Kind
B2
Abstract

A method of manufacturing a non-aqueous electrolyte secondary battery includes: (A) constructing an electrode group including a positive electrode and a negative electrode; (B) impregnating the electrode group with a first electrolyte solution; (C) charging the electrode group impregnated with the first electrolyte solution to a voltage of 4.3 V or more; and (E) manufacturing the non-aqueous electrolyte secondary battery by impregnating the electrode group with a second electrolyte solution after the charging. The first electrolyte solution includes a first solvent, a first lithium salt, and biphenyl. The first solvent does not include 1,2-dimethoxyethane. The second electrolyte solution includes a second solvent and a second lithium salt. The second solvent includes 1,2-dimethoxyethane.

Claims (26)

1. A method of manufacturing a non-aqueous electrolyte secondary battery, the method comprising:

constructing an electrode group including a positive electrode and a negative electrode;

impregnating the electrode group with a first electrolyte solution;

charging the electrode group impregnated with the first electrolyte solution to a voltage of 4.3 V or more; and

manufacturing the non-aqueous electrolyte secondary battery by impregnating the electrode group with a second electrolyte solution after the charging,

the first electrolyte solution including a first solvent, a first lithium salt, and biphenyl,

the first solvent not including 1,2-dimethoxyethane,

the second electrolyte solution including a second solvent and a second lithium salt,

the second solvent including 1,2-dimethoxyethane.

2. The method of manufacturing the non-aqueous electrolyte secondary battery according to claim 1 , wherein

the negative electrode includes composite particles,

the composite particles each include graphite and amorphous carbon,

the amorphous carbon covers a surface of the graphite, and

the first solvent includes ethylene carbonate.

3. The method of manufacturing the non-aqueous electrolyte secondary battery according to claim 1 , wherein the second solvent includes more than or equal to 10 volume % and less than or equal to 40 volume % of 1,2-dimethoxyethane.

4. The method of manufacturing the non-aqueous electrolyte secondary battery according to claim 1 , wherein the second solvent further includes more than or equal to 10 volume % and less than or equal to 30 volume % of ethylene carbonate, and more than or equal to 10 volume % and less than or equal to 30 volume % of ethyl methyl carbonate.

5. The method of manufacturing the non-aqueous electrolyte secondary battery according to claim 4 , wherein

the second solvent further includes more than or equal to 10 volume % and less than or equal to 30 volume % of dimethyl carbonate, and

in the second solvent, dimethyl carbonate has a volume ratio less than that of a sum of 1,2-dimethoxyethane and ethyl methyl carbonate.

6. The method of manufacturing the non-aqueous electrolyte secondary battery according to claim 1 , wherein the first electrolyte solution includes more than or equal to 1 mass % and less than or equal to 4 mass % of biphenyl.

7. The method of manufacturing the non-aqueous electrolyte secondary battery according to claim 1 , wherein the positive electrode includes a compound expressed by a formula (I):

LiNi a Co b Mn c O 2   (I)

where 0<a<1, 0<b<1, 0<c<1, and a+b+c=1.

8. The method of manufacturing the non-aqueous electrolyte secondary battery according to claim 1 , wherein the second solvent includes more than or equal to 20 volume % and less than or equal to 40 volume % of 1,2-dimethoxyethane.

9. The method of manufacturing the non-aqueous electrolyte secondary battery according to claim 1 , wherein the second solvent includes more than or equal to 30 volume % and less than or equal to 40 volume % of 1,2-dimethoxyethane.

10. The method of manufacturing the non-aqueous electrolyte secondary battery according to claim 1 , wherein the first electrolyte solution includes more than or equal to 2 mass % and less than or equal to 4 mass % of biphenyl.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 4, 2017
From: IGUCHI, HIROKI; FUJITA, HIDEAKI
To: TOYOTA JIDOSHA KABUSHIKI KAISHA
Reel/Frame 043782/0012 →
Priority Claims (1)
JP 2016-205075 · Oct 19, 2016 · national
Continuity (1)
Related Publication 20180108938A1 · Apr 19, 2018