IP Library Granted Patent US 10,532,968
Granted Patent B2
US 10,532,968 · App. 16/071,553 · Granted Jan 14, 2020

Method for purifying phenol

Inventors: Si Nae Lee (Daejeon, KR); Sung Kyu Lee (Daejeon, KR); Joon Ho Shin (Daejeon, KR)
Assignee: LG CHEM, LTD.
C07C37/78B01D3/32B01D3/36C07C39/04C07C45/84B01D2257/70
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Quick Facts
Patent No.
US 10,532,968
App. No.
16/071,553
Granted
Jan 14, 2020
Kind
B2
Abstract

The present invention relates to a method for purifying phenol, which comprises: supplying a feed comprising phenol, acetone, hydroxyacetone and water to a distillation column at 60° C. to 95° C.; separating the feed into a first fraction, which comprises the acetone, and separates to the upper part of the distillation column and a second fraction, which comprises the phenol, and separates to the lower part of the distillation column; and recovering the first fraction and the second fraction, respectively.

Claims (12)

1. A method for purifying phenol, comprising:

supplying a feed comprising phenol, acetone, hydroxyacetone and water to a distillation column at 60 to 95° C.;

separating the feed into a first fraction which comprises the acetone and separates to the upper part of the distillation column and a second fraction which comprises the phenol and separates to the lower part of the distillation column; and

recovering the first fraction and the second fraction, respectively,

wherein the distillation column comprises a middle inlet to which the feed is input; a first line from which the first fraction is extracted; and a second line from which a second fraction is extracted,

wherein the distillation column does not comprise a middle outlet, and

wherein the feed comprises 40 to 70 wt % of the phenol, 15 to 45 wt % of the acetone, 0.02 to 5 wt % of the hydroxyacetone, and 9 to 11 wt % of water with respect to the total weight of the feed.

2. The method of claim 1 , wherein the feed is prepared by oxidizing an alkylaryl compound to prepare a reaction mixture comprising an alkylaryl hydroperoxide and an unreacted alkylaryl compound and performing a cleavage reaction on the reaction mixture.

3. The method of claim 2 , wherein the feed comprises one or more selected from the group consisting of cumene, α-methyl styrene, methanol, acetaldehyde, formaldehyde, cumylphenol, dicumyl peroxide, an α-methyl styrene dimer, mesityl oxide, 2-methylbenzofuran and phenol tar.

4. The method of claim 1 , wherein the feed is supplied to the column at 75 to 95° C.

5. The method of claim 1 , wherein the feed has a pH of 3 to 10.

6. The method of claim 1 , wherein the hydroxyacetone in the second fraction is contained at 200 ppm or less based on weight of the second fraction.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 20, 2018
From: LEE, SI NAE; LEE, SUNG KYU; SHIN, JOON HO
To: LG CHEM, LTD.
Reel/Frame 046411/0321 →
Priority Claims (1)
KR 10-2017-0148530 · Nov 9, 2017 · national
Continuity (1)
Related Publication 20190023634A1 · Jan 24, 2019