Polycyclic compound and organic electroluminescence device including the same
A polycyclic compound is represented by Formula 1, where X 1 , X 2 , L, R 1 to R 8 , and a to d are as defined in the specification.
1. A polycyclic compound represented by the following Formula 1:
where X 1 and X 2 are each independently any one of C, Si, Ge, or Sn,
L is a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroarylene group having 2 to 30 ring carbon atoms,
R 1 to R 4 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted silyl group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring carbon atoms,
R 5 is a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring carbon atoms,
R 6 to R 8 are each independently a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring carbon atoms, or R 6 to R 8 may form a ring by combining adjacent groups with each other, and
a to d are each independently an integer of 1 to 4.
2. The polycyclic compound as claimed in claim 1 , wherein at least one of X 1 or X 2 is Si.
3. The polycyclic compound as claimed in claim 1 , wherein one of X 1 or X 2 is any one of Si, Ge, or Sn, and the other one of X 1 or X 2 is C.
4. The polycyclic compound as claimed in claim 1 , wherein L is a substituted or unsubstituted phenylene group, or a substituted or unsubstituted divalent biphenyl group.
5. The polycyclic compound as claimed in claim 4 , wherein L is represented by any one of the following L-1 to L-4:
6. The polycyclic compound as claimed in claim 1 , wherein L is a substituted or unsubstituted heteroarylene group including one of N, O, or S as a hetero atom.
7. The polycyclic compound as claimed in claim 6 , wherein L is represented by one of the following L-5 to L-7:
8. The polycyclic compound as claimed in claim 1 , wherein R 5 is a methyl group, or a substituted or unsubstituted phenyl group.
9. The polycyclic compound as claimed in claim 1 , wherein R 6 is a methyl group, or a substituted or unsubstituted phenyl group.
10. The polycyclic compound as claimed in claim 1 , wherein R 7 and R 8 are each independently a methyl group, or a substituted or unsubstituted phenyl group, or combine with each other to form a substituted or unsubstituted fluorene ring.
11. The polycyclic compound as claimed in claim 1 , wherein the polycyclic compound represented by Formula 1 is any one selected from the group consisting of compounds represented in the following Compound Group 1:
12. An organic electroluminescence device, comprising:
a first electrode;
a hole transport region on the first electrode;
an emission layer on the hole transport region;
an electron transport region disposed on the emission layer; and
a second electrode on the electron transport region,
wherein the hole transport region includes a polycyclic compound represented by the following Formula 1:
where X 1 and X 2 are each independently any one of C, Si, Ge, or Sn,
L is a substituted or unsubstituted arylene group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroarylene group having 2 to 30 ring carbon atoms,
R 1 to R 4 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted silyl group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having ring 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring carbon atoms,
R 5 is a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring carbon atoms,
R 6 to R 8 are each independently a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, a substituted or unsubstituted aryloxy group having 6 to 30 ring carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 ring carbon atoms, or R 6 to R 8 may form a ring by combining adjacent groups with each other, and
a to d are each independently an integer of 1 to 4.
13. The organic electroluminescence device as claimed in claim 12 , wherein the hole transport region comprises:
a hole injection layer; and
a hole transport layer between the hole injection layer and the emission layer, and
the hole transport layer includes the polycyclic compound represented by Formula 1.
14. The organic electroluminescence device as claimed in claim 12 , wherein the hole transport region includes:
a hole injection layer;
a hole transport layer on the hole injection layer; and
an electron blocking layer between the hole transport layer and the emission layer, and
the electron blocking layer includes the polycyclic compound represented by Formula 1.
15. The organic electroluminescence device as claimed in claim 12 , wherein the emission layer emits blue light.
16. The organic electroluminescence device as claimed in claim 12 , wherein at least one of X 1 or X 2 is Si.
17. The organic electroluminescence device as claimed in claim 12 , wherein L is a substituted or unsubstituted phenylene group, a substituted or unsubstituted divalent biphenyl group, or a substituted or unsubstituted heteroarylene group including any one of N, O or S as a hetero atom.
18. The organic electroluminescence device as claimed in claim 17 , wherein L is represented by any one of the following L-1 to L-7:
19. The organic electroluminescence device as claimed in claim 12 , wherein R 6 is a methyl group, or a substituted or unsubstituted phenyl group.
20. The organic electroluminescence device as claimed in claim 12 , wherein the hole transport region includes at least one of compounds represented in the following Compound Group 1: