Tough shrinkable films
The present disclosure relates to a shrink film comprising a polyester composition comprising: (1) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) about 70 to about 100 mole % of terephthalic acid residues; (ii) about 0 to about 30 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and (b) a diol component comprising: (i) about 0.01 to about 30 mole % neopentyl glycol residues; (ii) about 0.01 to about less than 15 mole % 1,4-cyclohexanedimethanol residues; (iii) about 50 to 90 mole % ethylene glycol residues; and (iv) about 2 to 15 mole % total diethylene glycol residues in the final polyester composition; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the diol component is 100 mole %.
1. A shrink film comprising a polyester composition comprising:
(1) at least one polyester which comprises:
(a) a dicarboxylic acid component comprising:
(i) about 70 to about 100 mole % of terephthalic acid residues;
(ii) about 0 to about 30 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and
(b) a diol component comprising:
(i) about 0.01 to about 30 mole % neopentyl glycol residues;
(ii) about 0.01 to about less than 15 mole % 1,4-cyclohexanedimethanol residues;
(iii) about 50 to 90 mole % ethylene glycol residues; and
(iv) about 2 to 15 mole % total diethylene glycol residues in the final polyester composition;
wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the diol component is 100 mole %.
2. The shrink film of claim 1 , wherein the inherent viscosity of the polyester is from 0.50 to 0.80 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.25 g/50 ml at 25° C.
3. The shrink film of claim 1 , wherein the polyester has a Tg of from 60° C. to 80° C. as determined using a TA DSC 2920 from Thermal Analyst Instrument at a scan rate of 20° C./min.
4. The shrink film of claim 1 , wherein the sum of one or more diol monomer components capable of forming an amorphous component in the final polyester composition is from 25 to 45 mole % wherein the total diol component is 100 mole %.
5. The shrink film of claim 1 , wherein the sum of the residues of 1,4-cyclohexanedimethanol and neopentyl glycol in the final polyester composition is from 20 to 40 mole % wherein the total diol component is 100 mole %.
6. The shrink film of claim 1 , wherein the ethylene glycol residues are present in an amount of 65 to 75 mole %.
7. The shrink film of claim 1 , wherein the 1,4-cyclohexanedimethanol residues are present in an amount of 1 to about 10 mole %.
8. The shrink film of claim 1 , wherein the diethylene glycol residues are present in an amount of 2 to 12 mole %.
9. The shrink film of claim 1 , wherein the diethylene glycol residues are present in an amount of 2 to 9 mole %.
10. The shrink film of claim 1 , wherein the 1,4-cyclohexanedimethanol residues are present in an amount of 0.01 to about 10 mole %, diethylene glycol residues are present in an amount of 2 to 9 mole %, neopentyl glycol residues in an amount of 5 to 30 mole %, and ethylene glycol residues are present in an amount of 65 mole % or greater.
11. The shrink film of claim 10 , wherein the 1,4-cyclohexanedimethanol residues are present in an amount of 2 to 7 mole %, diethylene glycol residues are present in an amount of less than 10 mole %, neopentyl glycol residues in an amount of 10 to 20 mole %, and ethylene glycol residues are present in an amount of greater than 60 mole %.
12. The shrink film of claim 1 , further comprising at least one voiding agent.
13. The shrink film of claim 1 , wherein the film is oriented in one or more directions.
14. The shrink film of claim 13 , wherein the film has a break strain percentage of 200 to 600% at 500 mm/min as measured according to ASTM Method D882.
15. The shrink film of claim 13 , wherein the film has shrinkage in the machine direction of 4% or less when immersed in water at 65° C. for 10 seconds.
16. The shrink film of claim 13 , wherein the film has shrinkage in the transverse direction of 60% or greater when immersed in water at 85° C. for 10 seconds.
17. The shrink film of claim 13 , wherein the film has a shrink force of 5 MPa or greater.
18. The shrink film of claim 13 , wherein the film has a pre-oriented thickness of about 50 to 400 microns and is oriented on a tenter frame at a ratio of 6.5:1 to 3:1 at a temperature from the Tg of the film to the Tg plus 55° C. to a thickness from about 10 to about 80 microns.
19. The shrink film of claim 13 , wherein the film has shrinkage in the transverse direction in the amount of 50 to 90% and shrinkage in the machine direction of 4% or less when immersed in water at 95° C. for 10 seconds.
20. A label or a sleeve applied to an article of manufacture, a shaped article, a container, a plastic bottle, a glass bottle, packaging, a battery, a hot fill container, or an industrial article comprising the shrink film of claim 1 , claim 12 or claim 13 .
21. The shrink film of claim 1 , wherein the residues of 1,4-cyclohexanedimethanol are present in an amount of less than 10 mole%.