Adhesive resin layer and adhesive resin film
The present invention provides an adhesive resin layer and an adhesive resin film which can prevent generation of air bubbles even when they are thermally deformed after adhering to a substrate, and have good followability to deformation of a substrate of a laminate in which a substrate, an adhesive resin layer, and a substrate are laminated in an order. More particularly, the present invention is a monolayered adhesive resin layer comprising an acrylic-based adhesive resin composition, wherein the adhesive resin composition contains at least an acrylic-based polymer, an acrylic-based monomer or an acrylic-based oligomer, and a thermopolymerization initiator, the adhesive resin layer has pressure sensitive adhesiveness on both surfaces at an ambient temperature, and in differential scanning calorimetry at a temperature raising rate of 10° C./min, heat generation is observed at 80° C. or higher, and at least one peak is confirmed between 120° C. and 210° C.
1. A monolayered adhesive resin layer comprising an acrylic-based adhesive resin composition, wherein
said adhesive resin composition consists essentially of (A) a crosslinked acrylic-based polymer, (B) an acrylic-based monomer or an acrylic-based oligomer as a flowable resin component having reactivity, (C) a thermopolymerization initiator, and (D) a crosslinking agent, wherein
said adhesive resin composition contains 0.001 to 0.5 parts by weight of said (C) thermopolymerization initiator, based on 100 parts by weight of said (A) acrylic-based polymer, and
said adhesive resin layer has pressure sensitive adhesiveness on both surfaces at an ambient temperature, and in differential scanning calorimetry (DSC) at a temperature raising rate of 10° C./min, heat generation is observed at 80° C. or higher, and at least one peak is confirmed between 120° C. and 210° C.
2. The adhesive resin layer according to claim 1 , wherein said (C) thermopolymerization initiator is a peroxide.
3. The adhesive resin layer according to claim 1 , wherein said adhesive resin composition contains 5 to 50 parts by weight of said (B) acrylic-based monomer or acrylic-based oligomer, based on 100 parts by weight of said (A) acrylic-based polymer.
4. The adhesive resin layer according to claim 1 , wherein said adhesive resin composition contains an acrylic-based monomer having a hydroxy group, as at least a part of said (B) acrylic-based monomer or acrylic-based oligomer.
5. The adhesive resin layer according to claim 1 , wherein said adhesive resin composition contains curable urethane acrylate, as at least a part of said (B) acrylic-based monomer or acrylic-based oligomer.
6. An adhesive resin film comprising the adhesive resin layer according to claim 1 laminated between two separators.
7. An adhesive resin layer for forming a laminate in which two substrates are laminated with the adhesive resin layer according to claim 1 interposed between the two substrates.
8. An adhesive resin layer, wherein a laminate obtained by laminating two substrates with the adhesive resin layer according to claim 1 interposed between the two substrates is subjected to thermal deformation in a state where said laminate is held between two dies, and said adhesive resin layer has a pressure sensitive adhesive force of 10 N/25 mm or more even after being thermally cured.