Method for preparing glass-ceramics, capable of adjusting machinability or translucency through change in temperature of heat treatment
The present invention relates to a method for preparing a lithium disilicate glass-ceramics containing silicate as a main component, and more particularly, to a method for preparing a glass-ceramics, which is capable of adjusting machinability or translucency according to a crystalline size by using a first heat treatment or a second heat treatment. To this end, a method for preparing a glass-ceramics containing a silica crystalline phase includes: performing a first heat treatment on a glass composition at a temperature of 400 to 850° C., so that a lithium disilicate crystalline phase and a silica crystalline phase each having a size of 5 to 2,000 nm are formed through the first heat treatment. After the first heat treatment, the method further includes performing a second heat treatment at a temperature of 780 to 880° C., so that translucency is adjusted by a temperature of the second heat treatment.
1. A method for preparing a glass-ceramics containing a silica crystalline phase, the method comprising:
performing a first heat treatment on a glass composition at a temperature of 480 to 800° C., so that a lithium disilicate crystalline phase and a silica crystalline phase each having a size of 30 to 500 nm are formed through the first heat treatment; and
performing a second heat treatment at a temperature of 780 to 880° C., so that translucency of the glass ceramics is adjusted based on the temperature of the second heat treatment,
wherein the glass composition comprises:
60 to 83 wt % SiO 2 ;
10 to 15 wt % Li 2 O;
2 to 6 wt % P 2 O 5 working as a nuclei formation agent;
1 to 5 wt % Al 2 O 3 for increasing a glass transition temperature and a softening point and enhancing chemical durability of glass;
0.1 to 3 wt % SrO for increasing the softening point of the glass;
0.1 to 2 wt % ZnO;
1 to 5 wt % colorants; and
2.5 to 6 wt % mixture of Na 2 O and K 2 O for increasing a thermal expansion coefficient of the glass,
wherein the lithium disilicate crystalline phase and the silica crystalline phase each have a transmittance of 18 to 55% at a wavelength of 550 nm, and have a first translucency value at a temperature of 780 to 820° C., a second translucency value at a temperature of 821 to 840° C., a third translucency value at a temperature of 841 to 860° C., and a fourth translucency value at a temperature of 861 to 880° C. depending on the temperature of the second heat treatment,
wherein the translucency values satisfy the following expression 1:
HT>MT>LT>MO
where HT is the first translucency value, MT is the second translucency value, LT is the third translucency value, and MO is the fourth translucency value, and
wherein a retention time is 1 minute to 2 hours.
2. The method of claim 1 , wherein the lithium disilicate crystalline phase and the silica crystalline phase each have a size of 0.3 to 5.5 μm after the second heat treatment.