Organic light emitting diode and organic light emitting display device including the same
An organic light emitting diode includes an emitting material layer including first and second layers; a first electrode on a side of the emitting material layer; and a second electrode on the other side of the light emitting material layer and facing the first electrode, wherein the first layer includes a first compound, and the second layer includes a second compound, wherein the first compound has a difference, between a singlet energy and a triplet energy, less than 0.3 eV, and wherein the singlet energy of the first compound is greater than a singlet energy of the second compound.
1. An organic light emitting diode, comprising:
an emitting material layer including first and second layers;
a first electrode on a side of the emitting material layer; and
a second electrode on the other side of the light emitting material layer and facing the first electrode,
wherein the first layer includes a first compound, and the second layer includes a second compound, wherein the first compound is of Formula 1-8 and the second compound is of Formula 1-6
wherein the first compound has a difference, between a singlet energy and a triplet energy, less than 0.3 eV, and
wherein the singlet energy of the first compound is greater than a singlet energy of the second compound.
2. The organic light emitting diode of claim 1 , wherein the first layer further includes a third compound, the second layer further includes a fourth compound, where the third compound and the fourth compound are of Formula 1-7
wherein a singlet energy and a triplet energy of the third compound are greater than the singlet energy and the triplet energy of the first compound, respectively, and
wherein a singlet energy of the fourth compound is greater than the singlet energy of the second compound.
3. The organic light emitting diode of claim 2 , wherein the third compound has a wt % greater than the first compound, and the fourth compound has a wt % greater than the second compound.
4. The organic light emitting diode of claim 2 , wherein the wt % of the first compound in the first layer is greater that of the second compound in the second layer.
5. The organic light emitting diode of claim 1 , further comprising an energy control layer between the first and second layers, wherein a triplet energy of the energy control layer is greater than the triplet energy of the first compound.
6. The organic light emitting diode of claim 5 , wherein the energy control layer includes a material of the chemical formula
wherein
Ar 1 is a C 5 to C 30 aryl or heteroaryl, and
Ar 2 is a carbazole or bicarbazole.
7. The organic light emitting diode of claim 1 , wherein the emitting material layer further includes a third layer which faces the first layer with the second layer therebetween,
wherein a third compound of the third layer is of the Formula 1-8
and has a difference, between a singlet energy and a triplet energy, of less than 0.3 eV,
wherein the singlet energy of the third compound is greater than the singlet energy of the second compound.
8. The organic light emitting diode of claim 1 , wherein the emitting material layer further includes a third layer which faces the second layer with the first layer therebetween,
wherein a third compound of the third layer is of the Formula 1-6
and has a singlet energy less than the singlet energy of the first compound.
9. The organic light emitting diode of claim 1 , wherein a color coordinate of a light emitted from the emitting material layer is substantially identical to a color coordinate of a light emitted from the second compound.
10. An organic light emitting display device, comprising:
a substrate;
a thin film transistor on the substrate; and
the organic light emitting diode, of claim 1 , connected to the thin film transistor.