Positive active material for rechargeable lithium battery, method of preparing the same, and rechargeable lithium battery including the same
View Patent ↗A positive active material for a rechargeable lithium battery, a method of preparing the same, and a rechargeable lithium battery including the same are disclosed, and the positive active material for a rechargeable lithium battery includes: a layered lithium composite oxide core; a first coating layer on the surface of the core and magnesium doped at a lithium site in the core; a NiO-phase second coating layer on the first coating layer wherein the NiO-phase has a rock salt structure; and a third coating layer on the second coating layer and including lithium magnesium phosphate.
1. A positive active material for a rechargeable lithium battery, comprising:
a layered lithium composite oxide core;
a first coating layer on the surface of the core, the first coating layer comprising the layered lithium composite oxide comprised in the core being doped with magnesium at a lithium site;
a NiO-phase second coating layer on the first coating layer wherein the NiO-phase has a rock salt structure; and
a third coating layer on the second coating layer, the third coating layer comprising lithium magnesium phosphate.
2. The positive active material of claim 1 , wherein the core is represented by Chemical Formula 1:
Li a Ni b CO c Mn d M e O 2 [Chemical Formula 1]
wherein, in Chemical Formula 1, M is a metal of Al, Zr, B or a combination thereof, 0.98≤a≤1.2, 0.1≤b≤0.9, 0.1≤c≤1, 0.1≤d≤0.9, 0≤e≤0.05, and b+c+d+e=1.
3. The positive active material of claim 1 , wherein the first coating layer is represented by Chemical Formula 2:
Li a-x Mg x Ni b Co c Nn d M e O 2 [Chemical Formula 2]
wherein, in Chemical Formula 2, M is a metal of Al, Zr, B or a combination thereof, 0.98≤a≤1.2, 0.1≤b≤0.9, 0.1≤c≤0.9, 0≤e≤0.05, b+c+d+e=1, and 0.01≤x≤0.1.
4. The positive active material of claim 1 , wherein the third coating layer is represented by Chemical Formula 3:
Li a MgPO 4 [Chemical Formula 3]
wherein, in Chemical Formula 1, 0.1≤a≤0.9.
5. The positive active material of claim 1 , wherein the total amount of the first, second, and third coating layers is greater than 0 wt % and less than or equal to 3 wt % based on 100 wt % of the total positive active material.
6. The positive active material of claim 1 , wherein a thickness of the third coating layer is greater than 0 nm and less than or equal to 10 nm.
7. The positive active material of claim 1 , wherein a thickness of the second coating layer is greater than 0 nm and less than or equal to 10 nm.
8. The positive active material of claim 1 , wherein in the first coating layer, a doping amount of magnesium in a lithium site is less than or equal to 1.9 mol %.
9. The positive active material of claim 1 , wherein the total thickness of the first, second, and third coating layers may be greater than 0 nm and less than or equal to 500 nm.
10. The positive active material of claim 1 , wherein the positive active material has a primary particle shape, and the primary particle has a diameter of less than or equal to 500 nm.
11. The positive active material of claim 10 , wherein the primary particles are aggregated to form a secondary particle, and the secondary particle has a diameter of 1 to 10 μm.
12. The positive active material of claim 11 , which further comprises a fourth coating layer comprising the lithium magnesium phosphate on the surface of the secondary particle.
13. A rechargeable lithium battery comprising:
a positive electrode including the positive active material for rechargeable lithium battery of claim 1 ;
a negative electrode including a negative active material; and
an electrolyte.