Cell
The present invention provides a cell that has a high theoretical voltage and theoretical capacity, and can be discharged and recharged multiple times. The cell includes a cathode, an anode, and an electrolyte, wherein the cathode contains a cathode active material containing an alkali metal compound represented by the formula (1): A x O y (1) (wherein A is an alkali metal atom, x is 0.5 to 2.5, and y is 0.5 to 2.5), the anode contains an anode active material containing at least one selected from the group consisting of an alkali metal, tin, titanium, boron, nitrogen, silicon, and carbon, and the cathode, the anode, and the electrolyte are hermetically sealed in the cell.
1. A secondary cell comprising:
a positive electrode;
a negative electrode; and
an electrolyte,
wherein the positive electrode comprises:
a positive electrode active material comprising an alkali metal compound represented by following formula (1):
A x O y (1)
wherein A is an alkali metal atom, x is in a range from 0.5 to 2.5, and y is in a range from 0.5 to 2.5; and
a catalyst for the positive electrode,
wherein the catalyst for the positive electrode comprises at least one element selected from the group consisting of Ag, Au, Cu, Fe, Co, and Ni, and
the catalyst for the positive electrode is in a form of a solid solution in a crystal structure of the alkali metal compound represented by the formula (1),
reactions at the positive electrode include one represented by a following formula:
A 2 O 2 +2A + +2 e − ⇔2A 2 O
wherein A is the alkali metal atom,
the negative electrode comprises a negative electrode active material comprising at least one material selected from the group consisting of an alkali metal, tin, titanium, boron, nitrogen, silicon, and carbon, and
the positive electrode, the negative electrode, and the electrolyte are hermetically sealed in the secondary cell.
2. The secondary cell according to claim 1 ,
wherein the positive electrode comprises a current collector and an active material layer, and
the active material layer comprises the alkali metal compound represented by the formula (1) in an amount of 5% by mass or more relative to mass of the active material layer.
3. The secondary cell according to claim 1 ,
wherein when the secondary cell is fully charged, the negative electrode comprises the alkali metal at a ratio, determined on a molar basis relative to an alkali metal peroxide represented by following formula (2) in the positive electrode, of not more than 100:
A 2 O 2 (2)
wherein A is the alkali metal atom.
4. The secondary cell according to claim 1 ,
wherein A is Li.
5. The secondary cell according to claim 1 ,
wherein the negative electrode active material in the negative electrode comprises at least one material selected from the group consisting of an alkali metal and carbon.
6. The secondary cell according to claim 1 ,
wherein the alkali metal in the negative electrode active material is Li, and
the carbon in the negative electrode active material is graphite.
7. The secondary cell according to claim 1 ,
wherein reactions at the negative electrode and overall reactions, which are combinations of reactions at the positive electrode and reactions at the negative electrode, include reactions represented by following formulas:
the reactions at the negative electrode: A ⇔A + +e −
the overall reactions: A+1/2A 2 O 2 ⇔A 2 O
wherein A is the alkali metal atom.
8. The secondary cell according to claim 1 ,
wherein the alkali metal compound is represented by A 2 O, or A 2 O 2 , or a combination thereof.
9. The secondary cell according to claim 1 ,
wherein A is Li or Na.
10. A composition for forming a positive electrode comprising:
a positive electrode active material; and
a catalyst for a positive electrode,
wherein the positive electrode active material comprises:
an alkali metal compound represented by the following formula (1):
A x O y (1)
wherein A is an alkali metal atom, x is in a range from 0.5 to 2.5, and y is in a range from 0.5 to 2 . 5 , and
wherein the catalyst for the positive electrode comprises at least one element selected from the group consisting of Ag, Au, Cu, Fe, Co, and Ni and
the catalyst for the positive electrode is in a form of a solid solution in a crystal structure of the alkali metal compound represented by the formula (1).
11. A method for producing the coposition according to claim 10 , comprising:
producing the positive electrode material by mixing the alkali metal compound and the catalyst for the positive electrode using a planetary ball mill.
12. The composition according to claim 10 ,
wherein the alkali metal compound is represented by A 2 O, or A 2 O 2 , or a combination thereof.
13. The composition according to claim 10 ,
wherein A is Li or Na.
14. The composition according to claim 10 ,
wherein A is Li.