Carbon dioxide sequestration using molten carbonate fuel cell and hydrogen separation technology

1. A carbon dioxide capture system comprising:

a fuel cell assembly comprising an anode section and a cathode section;

an electrochemical hydrogen separator (EHS) configured to receive an anode exhaust stream from the anode section of the fuel cell assembly, to generate a first EHS output stream comprising hydrogen, and to generate a second EHS output stream comprising concentrated carbon dioxide; and

a liquid-vapor separator (LVS) configured to receive the second EHS output stream, and separate the second EHS output stream into a first LVS output stream comprising liquid carbon dioxide, and a second LVS output stream comprising non-condensable gas and carbon dioxide vapor;

wherein the anode exhaust stream is compressed before being received by the EHS, such that the first EHS output stream comprises high pressure hydrogen and the second EHS output stream comprises high pressure concentrated carbon dioxide.

2. The carbon dioxide capture system according to claim 1 , further comprising:

a first heat exchanger configured to receive the second EHS output stream and the second LVS output stream, to cool the second EHS output stream, and to heat the second LVS output stream; and

a second heat exchanger configured to receive the cooled second EHS output stream from the first heat exchanger and to further cool the second EHS output stream;

wherein the LVS is configured to receive the cooled second EHS output stream from the second heat exchanger.

3. The carbon dioxide capture system according to claim 2 , further comprising:

a third heat exchanger configured to receive the heated second LVS output stream from the first heat exchanger and to further heat the second LVS output stream.

4. The carbon dioxide capture system according to claim 3 , further comprising:

a fourth heat exchanger configured to receive the heated second LVS output stream from the third heat exchanger and further heat the second LVS output stream.

5. The carbon dioxide capture system according to claim 4 , further comprising an expander configured to expand the heated second LVS output stream.

6. The carbon dioxide capture system according to claim 5 , further comprising an anode gas oxidizer (AGO) combustor configured to receive the expanded second LVS output stream, oxidize the expanded second LVS output stream, and provide an AGO output stream to the cathode section of the fuel cell assembly.

7. The carbon dioxide capture system according to claim 6 , wherein the AGO combustor is configured to receive a cathode exhaust stream from the fuel cell assembly.

8. The carbon dioxide capture system according to claim 7 , wherein:

the fourth heat exchanger is configured to further heat the second LVS output stream using the AGO output stream.

9. A carbon dioxide capture system comprising:

a fuel cell assembly comprising an anode section and a cathode section;

an electrochemical hydrogen separator (EHS) configured to receive an anode exhaust stream from the anode section of the fuel cell assembly, to generate a first EHS output stream comprising hydrogen, and to generate a second EHS output stream comprising concentrated carbon dioxide; and

a liquid-vapor separator (LVS) configured to receive the second EHS output stream, and separate the second EHS output stream into a first LVS output stream comprising liquid carbon dioxide, and a second LVS output stream comprising non-condensable gas and carbon dioxide vapor;

further comprising a plurality of compressors and a plurality of heat exchangers that are alternately disposed and configured to receive the anode exhaust stream from the anode section of the fuel cell assembly, and to compress and cool the anode exhaust stream before the anode exhaust stream is received by the EHS.

10. A liquid fuel generation system comprising:

a fuel cell assembly comprising an anode section and a cathode section;

an electrochemical hydrogen separator (EHS) configured to receive a first portion of an anode exhaust stream from the anode section of the fuel cell assembly, to generate a first EHS output stream comprising high pressure hydrogen, and to generate a second EHS output stream comprising high pressure concentrated carbon dioxide;

a liquid fuel production assembly configured to receive a second portion of the anode exhaust stream and the first EHS output stream, and generate a liquid fuel; and

a heat exchanger configured to heat the second EHS output stream.

11. The liquid fuel generation system according to claim 10 , further comprising an expander configured to expand the heated second EHS output stream.

12. The liquid fuel generation system according to claim 11 , further comprising an anode gas oxidizer (AGO) combustor configured to receive the expanded second EHS output stream, oxidize the expanded EHS output stream, and provide an AGO output stream to the cathode section of the fuel cell assembly.

13. The liquid fuel generation system according to claim 12 , wherein the AGO combustor is configured to receive a cathode exhaust stream from the fuel cell assembly.

14. The liquid fuel generation system according to claim 13 , wherein the heat exchanger is configured to heat the second LVS output stream using the AGO output stream before the second LVS output stream is sent to an expander.

15. The liquid fuel generation system according to claim 10 , further comprising a plurality of compressors and a plurality of heat exchangers that are alternately disposed and configured to receive the anode exhaust stream from the anode section of the fuel cell assembly, and compress and cool the anode exhaust stream before the anode exhaust stream is received by the EHS.

16. A carbon dioxide capture system comprising:

a fuel cell assembly comprising an anode section and a cathode section;

an electrochemical hydrogen separator (EHS) configured to receive an anode exhaust stream from the anode section of the fuel cell assembly, to generate a first EHS output stream comprising hydrogen, and to generate a second EHS output stream comprising concentrated carbon dioxide; and

a liquid-vapor separator (LVS) configured to receive the second EHS output stream, and separate the second EHS output stream into a first LVS output stream comprising liquid carbon dioxide, and a second LVS output stream comprising non-condensable gas and carbon dioxide vapor;

further comprising a plurality of compressors and a plurality of heat exchangers that are alternately disposed and configured to receive the anode exhaust stream from the anode section of the fuel cell assembly, and to compress and cool the anode exhaust stream after the anode exhaust stream is received by the EHS.