Polyolefin pellet for preparing fiber and fiber comprising the same
The present invention relates to a polyolefin pellet for preparing a fiber, and a fiber comprising the same. According to the present invention, provided is a polyolefin, which exhibits a high molecular weight range and a narrow molecular weight distribution and in which the formation of a gel deteriorating the quality of a fiber is reduced. Therefore, by using the polyolefin pellet, the present invention exhibits a molecular weight, a density and a narrow molecular weight distribution, which are equivalent to those of conventional polyolefin, but has high tenacity and an excellent drawing characteristic and can be highly oriented because gel formation is reduced, and therefore, the present invention can be applied to various industrial products due to a high draw ratio and crystallinity during a multifilament operation using the same.
1. A polyolefin pellet for preparing fiber wherein
a density is 0.94 to 0.96 g/cm 3 ;
a molecular weight distribution (PDI) is 2.0 to 3.0;
a melt index (MI: 190° C., 2.16 kg) is 0.1 to 1.5 g/10 min; and
when the polyolefin pellet is manufactured into a casting film at 190° C., the number of gels with a particle diameter of 250 μm or more and less than 650 μm on a surface of the casting film is less than 50 per unit area (m 2 ),
wherein a gel is an area of the casting film which has a refractive index difference generated by a laser analyzer compared to remaining areas of the casting film.
2. The polyolefin pellet for preparing fiber according to claim 1 , wherein the weight average molecular weight is 100,000 to 300,000 g/mol.
3. The polyolefin pellet for preparing fiber according to claim 1 , wherein the polyolefin is obtained by polymerizing olefin monomers in the presence of a metallocene catalyst, a hydrocarbyl aluminum scavenger, and hydrogen gas.
4. The polyolefin pellet for preparing fiber according to claim 3 , wherein the mole ratio of the hydrocarbyl aluminum scavenger and moisture ((H 2 O) in a reactor is 0.8:1 to 1.2:1.
5. The polyolefin pellet for preparing fiber according to claim 3 , wherein the introduction amount of the hydrogen gas is 30 to 90 L/min.
6. The polyolefin pellet for preparing fiber according to claim 3 , wherein the metallocene catalyst is a hybrid supported metallocene catalyst in which two or more different kinds of metallocene catalyst are supported in a carrier.
7. A fiber comprising the polyolefin according to claim 1 .
8. The fiber according to claim 7 , wherein tenacity measured according to ASTM D 638 is 9 to 20 gf/denier.
9. The fiber according to claim 7 , wherein a draw ratio (RPM 2 /RPM 1 ) is 10 to 24 times.
10. Multifilament material comprising the fiber of claim 8 .
11. The multifilament material according to claim 10 , wherein the multifilament material is geogrid, fiber stone, protective gloves, a marine rope, a fishing net, or industrial fabric.