Polyarylene sulfide resin, method for producing same, poly(arylene sulfonium salt), and method for producing poly(arylene sulfonium salt)
The present invention relates to a polyarylene sulfide resin, a method for producing the same, a poly(arylene sulfonium salt), and a method for producing the same. The production method comprises a step of obtaining a poly(arylene sulfonium salt) comprising a terminal group including at least one functional group selected from the group consisting of a carboxy group, a hydroxy group and an amino group, and a step of dealkylating or dearylating the poly(arylene sulfonium salt) to obtain a polyarylene sulfide resin, and a polyarylene sulfide resin comprising a terminal group including a functional group obtainable by the production method.
1. A polyarylene sulfide resin comprising:
a main chain including a constitutional unit represented by the following formula (5-1); and
a terminal group bonding to a terminal of the main chain and represented by the following formula (3-1b), (3-2b), (3-3b), (3-4b), (3-5b) or (3-6b):
wherein, in formula (5-1), Ar 7 and Ar 8 each independently represent a phenylene group optionally having a substituent, wherein the substituent is an alkyl group having 1 to 10 carbon atoms, a hydroxy group, an amino group, a mercapto group, a carboxy group or a sulfo group;
in formula (5-1), Ar 9b represents a phenylene group optionally having a substituent, wherein the substituent is an alkyl group having 1 to 10 carbon atoms, a hydroxy group, an amino group, a mercapto group, a carboxy group or a sulfo group; wherein the phenylene group is not 1,3-phenylene; and
in formulas (3-1b), (3-2b), (3-3b), (3-4b), (3-5b) and (3-6b), R 3 represents a direct bond or an alkylene group having 1 to 10 carbon atoms; and Ar 5b represents an aryl group.
2. A polyarylene sulfide resin comprising:
a main chain including a constitutional unit represented by the following formula (5-1); and
a terminal group bonding to a terminal of the main chain and represented by the following formula (4-1b), (4-2b), (4-3b) or (4-4b):
wherein, in formula (5-1), Ar 7 and Ar 8 each independently represent a phenylene group optionally having a substituent;
in formula (5-1), Ar 9b represents a 1,4-phenylene group optionally having a substituent; wherein the phenylene group is not 1,3-phenylene; and
in formulas (4-1b), (4-2b), (4-3b) and (4-4b), R 4 represents a direct bond or an alkylene group having 1 to 10 carbon atoms; and Ar 6b represents an aryl group.
3. A molding comprising the polyarylene sulfide resin according to claim 1 .
4. A molding comprising the polyarylene sulfide resin according to claim 2 .