All-solid battery and method for manufacturing the same
Provided are a method of manufacturing an all-solid battery and an all-solid battery manufactured by the method. The all-solid batter may have edge portions that can be more effectively insulated. In particular, the all-solid battery may include a cathode layer, an anode layer, and an electrolyte layer, a first insulator disposed at an edge of the cathode layer and a second insulator disposed between the cathode layer and the first insulator, thereby forming a membrane of the second insulator for preventing contact between the cathode layer and the anode layer in pressing.
1. A method of manufacturing an all-solid battery, comprising:
forming a cathode layer;
forming an anode layer having an area greater than an area of the cathode layer;
forming a solid electrolyte layer between the cathode layer and the anode layer;
disposing a first insulator at least an edge of the cathode layer;
disposing a second insulator between the cathode layer and the first insulator;
forming a battery cell by stacking the cathode layer, the anode layer, the solid electrolyte layer, the first insulator, and the second insulator; and
forming a membrane of the second insulator between the cathode layer and the first insulator by pressing the battery cell.
2. The method of claim 1 , wherein the second insulator is in contact with the first insulator, the cathode layer, and the solid electrolyte layer.
3. The method of claim 1 , wherein a gap exists between the first insulator and the edge of the cathode layer, and at least a portion of the second insulator flows into the gap when the battery cell is pressed.
4. The method of claim 1 , wherein the second insulator is disposed by applying a slurry comprising a second insulating material between the cathode layer and the first insulator.
5. The method of claim 1 , wherein a second insulator is disposed by attaching a second insulating material formed in a tape between the cathode layer and the first insulator.
6. The method of claim 1 , wherein the second insulator comprises a second insulating material having a melting point less than a melting point of the first insulator and a transition temperature less than a transition temperature of the first insulator.
7. The method of claim 6 , wherein the second insulator comprises a polymer having a melting point of about 90° C. to 200° C. and the second insulator is pressed by cold isostatic pressing at room temperature.
8. The method of claim 6 , wherein the second insulator comprises a polymer having a melting point of about 60° C. to 90° C. and the battery is pressed by a hot isostatic pressing at a temperature of about 90° C. or greater or by a warm isostatic pressing at a temperature of about 90° C. or less.
9. The method of claim 1 , wherein the first insulator comprises one selected from the group consisting of polyimide, SBR (Styrene-Butadiene Rubber), Nafion (Tetrafluoroethylene), Teflon (Polytetrafluoroethylene, PEFE), PAA (Poly acrylic acid) and PVA (Poly vinyl alcohol), and the second insulator is made of one selected from a group consisting of polyethylene oxide (PEO), polyvinylidene fluoride (PVDF), and a polyvinylidene fluoride copolymer.
10. The method of claim 1 , wherein the battery cell is pressed at temperature less than a melting point of the second insulator and greater than a transition temperature of the second insulator.
11. The method of claim 1 , wherein the battery is pressed at temperature greater than a melting point of the second insulator.
12. An all-solid battery comprising:
a cathode layer,
an anode layer having an area greater than an area of the cathode layer,
a solid electrolyte layer disposed between the cathode layer and the anode layer,
a first insulator disposed at an edge of the cathode layer, and
a second insulator disposed between the cathode layer and the first insulator,
wherein the cathode layer, the anode layer, the solid electrolyte, the first insulator, and the second insulator are stacked to form a battery cell,
wherein a membrane of the second insulator is formed between the cathode layer and the first insulator by pressing the battery cell.
13. The all-solid battery of claim 12 , wherein the second insulator is in contact with the first insulator, the cathode layer, and the solid electrolyte layer.
14. The all-solid battery of claim 12 , wherein a gap exists between the first insulator and the edge of the cathode layer, and when the stacked battery is pressed, the second insulator is melted and at least a portion of the second insulator forms the membrane of the second insulator by flowing into the gap.
15. The all-solid battery of claim 12 , wherein the second insulator comprise a second insulating material having a melting point less than a melting point of the first insulator and a transition temperature less than a transition temperature of the first insulator.
16. The all-solid battery of claim 15 , wherein the melting point of the second insulator is greater than a temperature in the pressing and a transition temperature of the second insulator is less than the temperature in the pressing.
17. They battery of claim 15 , wherein the melting point of the second insulator is less than the temperature in the pressing.
18. The all-solid battery of claim 12 , wherein the first insulator comprises one selected from the group consisting of polyimide, SBR (Styrene-Butadiene Rubber), Nafion (Tetrafluoroethylene), Teflon (Polytetrafluoroethylene, PEFE), PAA (Poly acrylic acid) and PVA (Poly vinyl alcohol), and the second insulator is made of one selected from a group consisting of polyethylene oxide (PEO), polyvinylidene fluoride (PVDF), and a polyvinylidene fluoride copolymer.
19. A vehicle comprising an all-solid battery of claim 12 .