High performance glass fiber composition, and glass fiber and composite material thereof
Provided are a high performance glass fiber composition, and a glass fiber and a composite material thereof. The content, given in weight percentage, of each component of the glass fiber composition is as follows: 52-67% of SiO 2 , 12-24% of Al 2 O 3 , 0.05-4.5% of Sm 2 O 3 +Gd 2 O 3 , less than 2% of Li 2 O+Na 2 O+K 2 O, 10-24% of CaO+MgO+SrO, less than 16% of CaO, less than 13% of MgO, less than 3% of TiO 2 , and less than 1.5% of Fe 2 O 3 . The composition significantly improves the mechanical properties and the thermal stability of glass, significantly reduces the liquidus temperature and forming temperature of glass, and under equal conditions, significantly reduces the crystallisation rate of glass. The composition is particularly suitable for the tank furnace production of a high performance glass fiber having excellent thermal stability.
1. A composition for producing a high performance glass fiber, comprising the following components with corresponding percentage amounts by weight:
SiO 2
54-62%
Al 2 O 3
12-24%
Sm 2 O 3 + Gd 2 O 3
0.05-4.5%
Sm 2 O 3
0.05-3%
R 2 O = Li 2 O + Na 2 O + K 2 O
<2%
CaO + MgO + SrO
12.5-24%
CaO
greater than or equal to 6.5% and
less than 16%
MgO
6-12%
TiO 2
<3%
Fe 2 O 3
<1.5%
wherein, a weight percentage ratio C1=(Li 2 O+Sm 2 O 3 +Gd 2 O 3 )/Al 2 O 3 is 0.02-0.15.
2. The composition of claim 1 , comprising 0.1-1.5 wt. % of Li 2 O.
3. The composition of claim 1 , wherein a combined weight percentage SiO 2 +Al 2 O 3 is less than 82%.
4. The composition of claim 1 , comprising the following components with corresponding percentage amounts by weight:
SiO 2
54-62%
Al 2 O 3
12-24%
SiO 2 + Al 2 O 3
<82%
Sm 2 O 3 + Gd 2 O 3
0.05-4.5%
Sm 2 O 3
0.05-3%
R 2 O = Li 2 O + Na 2 O + K 2 O
<2%
Li 2 O
0.1-1.5%
CaO + MgO + SrO
12.5-24%
CaO
greater than or equal to 6.5% and
less than 16%
MgO
6-12%
TiO 2
<3%
Fe 2 O 3
<1.5%
Wherein, a weight percentage ratio C1=(Li 2 O+Sm 2 O 3 +Gd 2 O 3 )/Al 2 O 3 is 0.02-0.15.
5. The composition of claim 1 , further comprising 0.05-5 wt. % of Y 2 O 3 .
6. The composition of claim 5 , wherein a weight percentage ratio C2=Y 2 O 3 /(Sm 2 O 3 +Gd 2 O 3 +Y 2 O 3 ) is greater than 0.4.
7. The composition of claim 1 , comprising the following components with corresponding percentage amounts by weight:
SiO 2
54-62%
Al 2 O 3
12-24%
Sm 2 O 3 + Gd 2 O 3
0.05-4.5%
Sm 2 O 3
0.05-3%
Y 2 O 3
0.05-5%
R 2 O = Li 2 O + Na 2 O + K 2 O
<2%
Li 2 O
0.1-1.5%
CaO + MgO + SrO
12.5-24%
CaO
greater than or equal to 6.5% and
less than 16%
MgO
6-12%
TiO 2
<3%
Fe 2 O 3
<1.5%
Wherein, a weight percentage ratio C1=(Li 2 O+Sm 2 O 3 +Gd 2 O 3 )/Al 2 O 3 is 0.02-0.15.
8. The composition of claim 1 , further comprising 0.05-3 wt. % of La 2 O 3 .
9. The composition of claim 8 , wherein a combined weight percentage Gd 2 O 3 +La 2 O 3 is 0.5%-1.5%.
10. The composition of claim 8 , wherein a combined weight percentage Gd 2 O 3 +La 2 O 3 +TiO 2 is 1%-3.5%.
11. The composition of claim 1 , comprising the following components with corresponding percentage amounts by weight:
SiO 2
54-62%
Al 2 O 3
12-24%
Sm 2 O 3 + Gd 2 O 3
0.05-4.5%
Sm 2 O 3
0.05-3%
La 2 O 3
0.05-3%
R 2 O = Li 2 O + Na 2 O + K 2 O
<2%
Li 2 O
0.1-1.5%
CaO + MgO + SrO
12.5-24%
CaO
greater than or equal to 6.5% and
less than 16%
MgO
6-12%
TiO 2
<3%
Fe 2 O 3
<1.5%
Wherein, a weight percentage ratio C1=(Li 2 O+Sm 2 O 3 +Gd 2 O 3 )/Al 2 O 3 is 0.02-0.15.
12. The composition of claim 1 , comprising the following components with corresponding percentage amounts by weight:
SiO 2
54-62%
Al 2 O 3
13-22%
SiO 2 + Al 2 O 3
70-81%
Sm 2 O 3 + Gd 2 O 3
0.1-4%
Sm 2 O 3
0.05-3%
R 2 O = Li 2 O + Na 2 O + K 2 O
<2%
Li 2 O
0.1-1.5%
CaO + MgO + SrO
12.5-24%
CaO
greater than or equal to 6.5% and
less than 14%
MgO
6-12%
TiO 2
<3%
Fe 2 O 3
<1.5%
Wherein, a weight percentage ratio C1=(Li 2 O+Sm 2 O 3 +Gd 2 O 3 )/Al 2 O 3 is 0.02-0.15.
13. The composition of claim 1 , comprising 0.1-2 wt. %.
14. The composition of claim 1 , further comprising 0-1 wt. % of CeO 2 .
15. A glass fiber, being produced using the composition of claim 1 .
16. A composite material, comprising the glass fiber of claim 15 .