IP Library Granted Patent US 10,590,312
Granted Patent B2
US 10,590,312 · App. 15/527,524 · Granted Mar 17, 2020

Color-changing adhesive composition

Inventors: Adrian T. Jung (Kaarst, DE); Santhosh K. Chandrabalan (Minneapolis, MN); Joanna K. Wegrzynska (Gomunice, PL); Daniel W. Wuerch (Maplewood, MN); Christian E. Claus (Düsseldorf, DE)
Assignee: 3M INNOVATIVE PROPERTIES COMPANY
C09J11/06C08G59/4021C08G59/4215C08G59/5013C09J163/00
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Quick Facts
Patent No.
US 10,590,312
App. No.
15/527,524
Granted
Mar 17, 2020
Kind
B2
Abstract

The present disclosure relates to a color-changing adhesive composition, for example, a color-changing adhesive composition suitable in the preparation of composite materials. The present disclosure also relates to methods of preparing composite materials using color-changing adhesive compositions and to composite-materials comprising such color-changing compositions.

Claims (29)

1. An adhesive composition comprising

a dye,

a sprayable adhesive,

one or more propellants selected from liquefied hydrocarbons and compressed gases; and

without a curable epoxy resin;

wherein the dye is chosen from triarylmethane compounds;

wherein the adhesive composition is sprayable via the one or more propellants and has an initial color;

wherein the adhesive composition is capable of changing color to a final color upon contacting a curing composition comprising one or more curing agents.

2. An adhesive composition according to claim 1 , wherein the one or more curing agents are chosen from trioxatridecane diamine, dicyandiamide curing agent, and anhydride curing agent methyl endomethylene tetrahydrophthalic anhydride.

3. An adhesive composition according to claim 1 , wherein the dye is chosen from Brilliant Green, Malachit Green, Crystal Violet, Phenolphthalein, and mixtures thereof.

4. An adhesive composition according to claim 1 , wherein the dye is chosen from Brilliant Green, Malachit Green, and mixtures thereof.

5. An adhesive composition according to claim 1 , wherein the dye is Brilliant Green.

6. An adhesive composition according to claim 1 , wherein the adhesive is a pressure-sensitive adhesive.

7. An adhesive composition according to claim 1 , comprising at least 10% by weight of an organic solvent.

8. An article comprising the adhesive composition according to claim 1 .

9. An article comprising the adhesive composition according to claim 1 , wherein the article is selected from rotor blades for wind turbines, watercrafts, aircrafts, motor vehicles, and pieces of furniture.

10. An adhesive composition according to claim 1 , wherein the final color is colorless.

11. An adhesive composition comprising

a dye,

a sprayable adhesive,

one or more propellants selected from liquefied hydrocarbons and compressed gases, and

without a curable epoxy resin;

wherein the dye is Brilliant Green;

wherein the adhesive composition is sprayable via the one or more propellants and has an initial color;

wherein the adhesive composition is capable of changing color to a final color upon contacting a curing composition comprising one or more curing agents;

wherein the initial color is different from the final color; and

wherein the one or more curing agents are chosen from trioxatridecane diamine, dicyandiamide curing agent, and anhydride curing agent methyl endomethylene tetrahydrophthalic anhydride.

12. An adhesive composition according to claim 11 , comprising at least 10% by weight of an organic solvent.

13. An adhesive composition according to claim 11 , wherein the final color is colorless.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 13, 2017
From: JUNG, ADRIAN; CHANDRABALAN, SANTHOSH K.; WEGRZYNSKA, JOANNA; WUERCH, DANIEL W.; CLAUS, CHRISTIAN
To: 3M INNOVATIVE PROPERTIES COMPANY
Reel/Frame 043580/0522 →
Continuity (2)
Provisional Application 62081426 · Nov 18, 2014
Related Publication 20170355886A1 · Dec 14, 2017