High-strength cold-rolled steel sheet and method for manufacturing the same

1. A high-strength cold-rolled steel sheet having a chemical composition comprising, by mass %:

C: 0.15% to 0.25%;

Si: 1.2% to 2.5%;

Mn: 2.1% to 3.5%;

P: 0.05% or less;

S: 0.005% or less;

Al: 0.01% to 0.08%;

N: 0.010% or less;

Ti: 0.002% to 0.050%;

B: 0.0002% to 0.0100%; and

the balance being Fe and inevitable impurities,

wherein the cold-rolled steel sheet has a microstructure including (i) ferrite having an average crystal grain diameter of 2 μm or less in an amount in a range of 10% to 25% in terms of volume fraction, (ii) retained austenite in an amount in a range of 5% to 20% in terms of volume fraction, (iii) martensite having an average crystal grain diameter of 2 μm or less in an amount in a range of 5% to 15% in terms of volume fraction, and (iv) the balance being a multi-phase structure including bainite and tempered martensite, the bainite and tempered martensite having an average crystal grain diameter of 5 μm or less, the tempered martensite being present in the microstructure in an amount in a range of 20% to 60% in terms of volume fraction, the bainite being present in the microstructure in an amount in a range of 10% to 40% in terms of volume fraction, and

relational expression (1) is satisfied:

0.35≤ V 2/ V 1≤0.75  (1)

where V1 is a volume fraction of phases which are different from ferrite and V2 is a volume fraction of tempered martensite.

2. The high-strength cold-rolled steel sheet according to claim 1 , wherein the chemical composition further comprises, by mass %, at least one selected from the group consisting of V: 0.05% or less, and Nb: 0.05% or less.

3. The high-strength cold-rolled steel sheet according to claim 1 , wherein the chemical composition further comprises, by mass %, at least one selected from the group consisting of Cr: 0.50% or less, Mo: 0.50% or less, Cu: 0.50% or less, Ni: 0.50% or less, Ca: 0.0050% or less, and REM: 0.0050% or less.

4. A method for manufacturing a high-strength cold-rolled steel sheet, the method comprising:

a hot rolling process in which a rolling operation is performed on a steel slab having a chemical composition comprising, by mass %, C: 0.15% to 0.25%, Si: 1.2% to 2.5%, Mn: 2.1% to 3.5%, P: 0.05% or less, S: 0.005% or less, Al: 0.01% to 0.08%, N: 0.010% or less, Ti: 0.002% to 0.050%, B: 0.0002% to 0.0100%, and the balance being Fe and inevitable impurities, at a temperature in a range of 1150° C. to 1300° C. under a condition of a finishing delivery temperature in a range of 850° C. to 950° C., in which (i) cooling is started within 1 second after the rolling operation, (ii) a first cooling operation is performed under conditions of a first average cooling rate of 80° C./s or more and a first cooling stop temperature of 650° C. or lower, (iii) a second cooling operation is performed after the first cooling operation under conditions of a second average cooling rate of 5° C./s or more and a second cooling stop temperature of lower than the first cooling stop temperature and 550° C. or lower, and (iv) a coiling operation is performed after the second cooling operation;

optionally, a pickling process in which a pickling operation is performed after the hot rolling process;

a cold rolling process in which a cold rolling operation is performed (i) after the hot rolling process and (ii) if the pickling process is performed, after the pickling process; and

an annealing process in which a first heating operation is performed after the cold rolling process at an arbitrary first average heating rate under a condition of a first heating end-point temperature in a range of 250° C. to 350° C., in which (i) a second heating operation is performed after the first heating operation under conditions of a second average heating rate in a range of 6° C./s to 25° C./s and a second heating end-point temperature in a range of 550° C. to 680° C., (ii) a third heating operation is performed after the second heating operation under conditions of a third average heating rate of 10° C./s or less and a third heating end-point temperature in a range of 760° C. to 850° C., (iii) a first soaking operation is performed after the third heating operation under conditions of a first soaking temperature in a range of 760° C. to 850° C. and a first soaking time of 30 seconds or more, (iv) a third cooling operation is performed after the first soaking operation under conditions of a third average cooling rate of 3° C./s or more and a third cooling stop temperature in a range of 100° C. to 300° C., (v) a fourth heating operation is performed after the third cooling operation under a condition of a fourth heating end-point temperature in a range of 350° C. to 450° C., (vi) a second soaking operation is performed after the fourth heating operation under conditions of a second soaking temperature in a range of 350° C. to 450° C. and a second soaking time of 30 seconds or more, and (vii) a fourth cooling operation is performed after the second soaking operation under a condition of a fourth cooling stop temperature in a range of 0° C. to 50° C. thereby producing the high-strength cold-rolled steel sheet of claim 1 .

5. The high-strength cold-rolled steel sheet according to claim 2 , wherein the chemical composition further comprises, by mass %, at least one selected from the group consisting of Cr: 0.50% or less, Mo: 0.50% or less, Cu: 0.50% or less, Ni: 0.50% or less, Ca: 0.0050% or less, and REM: 0.0050% or less.

6. The method for manufacturing the high-strength cold-rolled steel sheet according to claim 4 , wherein the chemical composition further comprises, by mass %, at least one selected from the group consisting of V: 0.05% or less, and Nb: 0.05% or less.

7. The method for manufacturing the high-strength cold-rolled steel sheet according to claim 4 , wherein the chemical composition further comprises, by mass %, at least one selected from the group consisting of Cr: 0.50% or less, Mo: 0.50% or less, Cu: 0.50% or less, Ni: 0.50% or less, Ca: 0.0050% or less, and REM: 0.0050% or less.

8. The method for manufacturing the high-strength cold-rolled steel sheet according to claim 6 , wherein the chemical composition further comprises, by mass %, at least one selected from the group consisting of Cr: 0.50% or less, Mo: 0.50% or less, Cu: 0.50% or less, Ni: 0.50% or less, Ca: 0.0050% or less, and REM: 0.0050% or less.