IP Library Granted Patent US 10,591,950
Granted Patent B2
US 10,591,950 · App. 15/491,433 · Granted Mar 17, 2020

Copolymerized bis-(ethylene oxy) methane polysulfide polymer and hydroxyl terminated poly butadiene as a solid fueled ramjet fuel

Inventors: Brian McDonald (Taft, TN); Jeremy Rice (Huntsville, AL); John Stewart (Redstone Arsenal, AL)
G06D5/00C10L5/00C10L5/406F02K7/105F02K9/95C10L2200/0259C10L2200/0263C10L2250/04C10L2270/04
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Quick Facts
Patent No.
US 10,591,950
App. No.
15/491,433
Granted
Mar 17, 2020
Kind
B2
Abstract

The application relates to a Ramjet solid fuel having an ignition temperature of less than 400° C., the fuel comprising a bis-(ethylene oxy) methane polysulfide polymer (BMPP) and hydroxyl-terminated polybutadiene (HTPB), the copolymer having a BMPP/HTPB weight ratio of from 1/3 to 3/1; and the fuel comprising at least 85 weight % copolymer. The BMPP comprises from 5 to 8 weight percent mercaptan. Furthermore, the BMPP is selected from HS(RSS) a CH 2 CH((SSR) c CSH)CH 2 (SSR) b SH  a) where R═—(CH 2 ) 2 OCH 2 O(CH 2 ) 2 — and a+b+c<7; and H(SC 2 H 4 OCH 2 OC 2 H4S) n H where n =7.  b)

Claims (9)

1. A Ramjet solid fuel having an ignition temperature of less than 400° C., the fuel consisting essentially of a copolymer of bis-(ethylene oxy) methane polysulfide polymer (BMPP) and hydroxyl-terminated polybutadiene (HTPB); isophorone diisocyanate (IDPI); and butyltin; the copolymer having a BMPP/HTPB weight ratio of from 1/3 to 3/1; and the fuel thus consisting essentially of between 83 and 87 weight % copolymer, between 11 and 16 weight % IPDI (Isophorone diisocyanate), and between 0 and 2% butyltin;

wherein the BMPP comprises from 5 to 8 weight percent mercaptan;

and wherein BMPP is selected from

HS(RSS) a CH 2 CH((SSR) c CSH)CH 2 (SSR) b SH  a)

Where R═—(CH 2 ) 2 OCH 2 O(CH 2 ) 2 —

And a+b+c<7; and

H(SC 2 H 4 OCH 2 OC 2 H4S) n H  b)

Where n=7.

2. The Ramjet solid fuel according to claim 1 , wherein the ignition temperature is less than 312° C.

Continuity (1)
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