Wavelength converting member and light emitting device
A wavelength converting member comprising a first wavelength converting layer containing: a first fluorescent material having a light emission peak wavelength in a range of 620 nm or more and 660 nm or less; a second fluorescent material having a light emission peak wavelength in a range of 510 nm or more and 560 nm or less; and a resin, wherein the average particle diameter, as measured according to a Fisher Sub-Sieve Sizer method, of the first fluorescent material is in a range of 2 μm or more and 30 μm or less, wherein the second fluorescent material comprises a β-SiAlON fluorescent material, the circularity of the β-SiAlON fluorescent material is 0.7 or more, and the volume average particle diameter, as measured according to a laser diffraction scattering particle size distribution measuring method, of the β-SiAlON fluorescent material is in a range of 2 μm or more and 30 μm or less, and wherein the thickness of the first wavelength converting layer is in a range of 50 μm or more and 200 μm or less.
1. A light emitting device, comprising a sheet-shaped wavelength converting member and a light emitting element having a light emission peak wavelength in a range of 400 nm or more and 480 nm or less,
wherein the sheet-shaped wavelength converting member comprising a first wavelength converting layer containing:
a first fluorescent material having a light emission peak wavelength in a range of 620 nm or more and 660 nm or less;
a second fluorescent material having a light emission peak wavelength in a range of 510 nm or more and 560 nm or less; and
a resin,
wherein an average particle diameter, as measured according to a Fisher Sub-Sieve Sizer method, of the first fluorescent material is in a range of 2 μm or more and 30 μm or less,
wherein the second fluorescent material comprises a β-SiAlON fluorescent material, a circularity of the β-SiAlON fluorescent material is 0.7 or more, and a volume average particle diameter, as measured according to a laser diffraction scattering particle size distribution measuring method, of the β-SiAlON fluorescent material is in a range of 2 μm or more and 30 μm or less, and a ratio of an average particle diameter of the β-SiAlON fluorescent material, as measured according to the Fisher Sub-Sieve Sizer method, to the volume average particle diameter of the β-SiAlON fluorescent material, as measured according to the laser diffraction scattering particle size distribution measuring method, is 0.67 or more,
wherein a thickness of the first wavelength converting layer is in a range of 50 μm or more and 200 μm or less, and
wherein the sheet-shaped wavelength converting member has a first main surface that is one surface of the first wavelength converting layer, and a second main surface on a side opposite to the first main surface, and the first main surface is bonded to the light emitting element.
2. A light emitting device, comprising a sheet-shaped wavelength converting member and a light emitting element having a light emission peak wavelength in a range of 400 nm or more and 480 nm or less,
wherein the sheet-shaped wavelength converting member comprising:
a second wavelength converting layer containing a first fluorescent material having a light emission peak wavelength in a range of 620 nm or more and 660 nm or less and a first resin; and
a third wavelength converting layer containing a second fluorescent material having a light emission peak wavelength in a range of 510 nm or more and 560 nm or less and a second resin,
wherein an average particle diameter, as measured according to a Fisher Sub-Sieve Sizer method, of the first fluorescent material is in a range of 2 μm or more and 30 μm or less,
wherein the second fluorescent material comprises a β-SiAlON fluorescent material, a circularity of the β-SiAlON fluorescent material is 0.7 or more, and a volume average particle diameter, as measured according to a laser diffraction scattering particle size distribution measuring method, of the β-SiAlON fluorescent material is in a range of 2 μm or more and 30 μm or less, and a ratio of an average particle diameter of the β-SiAlON fluorescent material, as measured according to the Fisher Sub-Sieve Sizer method, to the volume average particle diameter of the β-SiAlON fluorescent material, as measured according to the laser diffraction scattering particle size distribution measuring method, is 0.67 or more,
wherein a thickness of each of the second wavelength converting layer and the third wavelength converting layer is in a range of 10 μm or more and 150 μm or less,
wherein the sheet-shaped wavelength converting member has a first main surface that is one surface of the third wavelength converting layer and a second main surface on a side opposite to the first main surface, and the first main surface is bonded to the light emitting element, and
wherein the second wavelength converting layer and the third wavelength converting layer are bonded together.
3. The light emitting device according to claim 1 , wherein an aspect ratio of the β-SiAlON fluorescent material is 0.62 or more.
4. The light emitting device according to claim 2 , wherein an aspect ratio of the β-SiAlON fluorescent material is 0.62 or more.
5. The light emitting device according to claim 1 ,
wherein the first fluorescent material comprises:
a Mn 4+ -activated fluoride fluorescent material;
a fluorescent material containing an Eu 2+ -activated silicon nitride containing at least one element selected from Sr and Ca, and Al; and
at least one fluorescent material containing an Eu 2+ -activated aluminum nitride containing at least alkaline earth metal element and at least one alkali metal elements, and
wherein the second fluorescent material further comprises:
a chlorosilicate-based fluorescent material;
a Mn 2+ -activated aluminate fluorescent material containing at least one alkaline earth metal element selected from the group consisting of Ba, Sr, and Ca; and
at least one γ-AlON fluorescent material.
6. The light emitting device according to claim 2 ,
wherein the first fluorescent material comprises:
a Mn 2+ -activated fluoride fluorescent material;
a fluorescent material containing an Eu 2+ -activated silicon nitride containing at least one element selected from Sr and Ca, and Al; and
at least one fluorescent material containing an Eu 2+ -activated aluminum nitride containing at least one alkaline earth metal element and at least one alkali metal element, and
wherein the second fluorescent material further comprises:
a chlorosilicate-based fluorescent material;
a Mn 2+ -activated aluminate fluorescent material containing at least one element selected from the group consisting of Ba, Sr, and Ca; and
at least one γ-AlON fluorescent material.
7. The light emitting device according to claim 1 , wherein a mass ratio of the resin contained in the first wavelength converting layer to a total of the first fluorescent material and the second fluorescent material falls within a range of 100:50 to 100:260.
8. The light emitting device according to claim 2 , wherein a mass ratio of the first resin contained in the second wavelength converting layer to the first fluorescent material falls within a range of 100:50 to 100:260, and a mass ratio of the second resin contained in the third wavelength converting layer to the second fluorescent material falls within a range of 100:50 to 100:150.
9. The light emitting device according to claim 1 , wherein the sheet-shaped wavelength converting member further comprises a translucent layer containing no fluorescent material.
10. The light emitting device according to claim 2 , wherein the sheet-shaped wavelength converting member further comprises a translucent layer containing no fluorescent material.
11. The light emitting device according to claim 10 , wherein the second wavelength converting layer is located between the translucent layer and the third wavelength converting layer, and wherein the second wavelength converting layer comprises a Mn 4+ -activated fluoride fluorescent material.
12. The light emitting device according to claim 1 , wherein the resin is a silicone resin or an epoxy resin.
13. The light emitting device according to claim 2 , wherein at least one of the first resin and the second resin is a silicone resin or an epoxy resin.
14. The light emitting device according to claim 9 , wherein at least one of the first wavelength converting layer and the translucent layer comprises a filler, wherein the filler is at least one selected from the group consisting of silicon oxide, zirconium oxide, titanium oxide, zinc oxide, and aluminum oxide.
15. The light emitting device according to claim 10 , wherein at least one of the second wavelength converting layer, the third wavelength converting layer, and the translucent layer comprises a filler, wherein the filler is at least one selected from the group consisting of silicon oxide, zirconium oxide, titanium oxide, zinc oxide, and aluminum oxide.