Conformal coating of lithium anode via vapor deposition for rechargeable lithium ion batteries
A negative lithium-containing electrode for an electrochemical cell is provided, along with methods of making such a negative lithium-containing electrode. The method includes depositing a first precursor and a second precursor in a vapor deposition process onto one or more surface regions of a negative electrode material comprising lithium. The first precursor and the second precursor react to form an inorganic-organic composite surface coating on the one or more surface regions. The first precursor comprises an organic mercapto-containing silane and the second precursor comprises an inorganic silane.
1. A method of making a negative lithium-containing electrode for an electrochemical cell, the method comprising:
depositing a first precursor and a second precursor in a vapor deposition process onto one or more surface regions of a negative electrode material comprising lithium, wherein the first precursor and the second precursor react to form an inorganic-organic composite surface coating on the one or more surface regions, wherein the first precursor comprises an organic mercapto-containing silane and the second precursor comprises an inorganic silane, and the inorganic-organic composite surface coating comprises a first lithium silicate (Li x SiO y ) moiety, where 0≤x≤4 and 0≤y≤2.
2. The method of claim 1 , wherein the first precursor comprises 3-mercaptopropyltrimethoxysilane and the second precursor comprises tetraethyl orthosilicate.
3. The method of claim 1 , wherein the inorganic-organic composite surface coating further comprises a second mercaptoalkyl moiety.
4. The method of claim 1 , wherein the first precursor is selected from the group consisting of: 3-mercaptopropyltrimethoxysilane, 3-mercaptopropyltriethoxysilane (mercaptomethyl)methyldiethoxysilane, 3-mercaptopropylmethyldimethoxysilane, 11-mercaptoundecyloxytrimethylsilane, and combinations thereof and the second precursor is selected from the group consisting of: tetraethyl orthosilicate, tetramethyl orthosilicate, tetraisopropyl orthosilicate, and combinations thereof.
5. The method of claim 1 , wherein the first precursor and the second precursor are provided in a liquid admixture from which the first precursor and second precursor are vaporized.
6. The method of claim 1 , wherein the depositing of the first precursor and the second precursor occurs in a reaction chamber having an inert atmosphere.
7. The method of claim 6 , wherein a temperature in the reaction chamber is greater than or equal to about 90° C.
8. The method of claim 1 , wherein the negative electrode material comprises:
(i) a metal film comprising lithium;
(ii) a plurality of particles, so that the inorganic-organic composite surface coating is applied to the plurality of particles that subsequently form a negative electrode; and
(iii) a pre-fabricated electrode layer and the inorganic-organic composite surface coating is applied to at least one surface of the pre-fabricated electrode layer.
9. The method of claim 1 , wherein the inorganic-organic composite surface coating deposited on the one or more surface regions provides greater than or equal to about 75% to less than or equal to about 100% surface area coverage of the negative electrode material.
10. A negative lithium-containing electrode for an electrochemical cell, comprising a negative electrode material comprising lithium having one or more exposed surface regions with an inorganic-organic composite surface coating disposed thereon comprising a first lithium silicate (Li x SiO y ) moiety, where 0≤x≤4 and 0≤y≤2, and a second mercapto-containing moiety.
11. The negative lithium-containing electrode of claim 10 , wherein the second mercapto-containing moiety is selected from the group consisting of: a mercaptopropyl group, a mercaptomethyl group, a mercaptoundecyl group, and combinations thereof.
12. The negative lithium-containing electrode of claim 10 , wherein the inorganic-organic composite surface coating comprises a first lithium silicate (Li x SiO y ) moiety, where 0≤x≤4 and 0≤y≤2, and a second mercaptoalkyl moiety.
13. The negative lithium-containing electrode of claim 10 , wherein the inorganic-organic composite surface coating is disposed on the one or more exposed surface regions provides greater than or equal to about 75% to less than or equal to about 100% surface area coverage of the negative electrode material.
14. The negative lithium-containing electrode of claim 10 , wherein the negative electrode material is a metal film comprising lithium and the inorganic-organic composite surface coating is applied to at least one surface of the metal film.
15. The negative lithium-containing electrode of claim 10 , wherein the negative electrode material is contained in a pre-fabricated electrode layer and the inorganic-organic composite surface coating is applied to at least one surface of the pre-fabricated electrode layer.
16. The negative lithium-containing electrode of claim 10 , wherein the negative electrode material comprises a plurality of particles, so that the inorganic-organic composite surface coating is applied to the plurality of particles that subsequently form the negative lithium-containing electrode.
17. The negative lithium-containing electrode of claim 10 , wherein the inorganic-organic composite surface coating has a thickness of greater than or equal to about 2 nm to less than or equal to about 100 nm.
18. The negative lithium-containing electrode of claim 10 , wherein the inorganic-organic composite surface coating is disposed using a vapor deposition process.
19. The negative lithium-containing electrode of claim 10 , wherein the inorganic-organic composite surface coating is a hermetic, pinhole-free interfacial inorganic-organic composite surface coating.
20. The negative lithium-containing electrode of claim 10 , wherein the inorganic-organic composite surface coating uniformly coats the one or more exposed surface regions of the negative electrode material.