Prevention of starch degradation in pulp, paper or board making processes
The invention relates to biocidal systems comprising zinc ions and an oxidizing or non-oxidizing biocide, their use, and methods for preventing or decreasing starch degradation in starch-containing process waters from pulp, paper or board production processes.
1. A method of controlling starch degradation in starch-containing process water from pulp, paper or board production, comprising: treating the process water with zinc ions and a biocide, wherein the biocide is an oxidizing biocide and selected from: chlorine, alkali and alkaline earth hypochlorite salts, hypochlorous acid, chlorinated isocyanurates, bromine, alkali and alkaline earth hypobromite salts, hypobromous acid, bromine chloride, chlorine dioxide, ozone, hydrogen peroxide, peroxy compounds, halogenated hydantoins, monochloramines, monobromamines, dihaloamines, trihaloamines, an optionally substituted N-hydrogen compound combined with an oxidant, ammonium salts reacted with an oxidant, or a combination thereof.
2. The method of claim 1 , wherein the zinc ions are derived from an inorganic or organic zinc salt.
3. The method of claim 1 , wherein the zinc ion source is selected from: ZnBr 2 , ZnCl 2 , ZnF 2 , ZnI 2 , ZnO, Zn(OH) 2 , ZnS, ZnSe, ZnTe, Zn 3 N 2 , Zn 3 P 2 , Zn 3 As 2 , Zn 3 Sb 2 , ZnO 2 , ZnH 2 , ZnC 2 , ZnCO 3 , Zn(NO 3 ) 2 , Zn(ClO 3 ) 2 , ZnSO 4 , Zn 3 (PO 4 ) 2 , ZnMoO 4 , ZnCrO 4 , Zn(AsO 2 ) 2 , Zn(AsO 4 ) 2 , Zn(O 2 CCH 3 ) 2 ), zinc metal, and a combination thereof.
4. The method of claim 1 , wherein the oxidizing biocide is selected from: alkali and alkaline earth hypochlorite salts, hypochlorous acid, chlorine dioxide, and hydrogen peroxide.
5. The method of claim 1 , wherein the oxidizing biocide is a peroxy compound selected from peracetic acid, performic acid, percarbonate salts, or persulfate salts.
6. The method of claim 1 , wherein the oxidizing biocide is a halogenated hydantoin selected from monohalodimethylhydantoins or dihalodimethylhydantoins.
7. The method of claim 1 , wherein the oxidizing biocide is a halogenated hydantoin selected from monochlorodimethylhydantoin or chlorobromodimethylhydantoin.
8. The method of claim 1 , wherein the oxidizing biocide is monochloramine or chlorine dioxide.
9. The method of claim 1 , wherein the oxidizing biocide is an optionally substituted N-hydrogen compound combined with an oxidant and the optionally substituted N-hydrogen compound is selected from ammonium salts, ammonia, urea, hydantoin, isothiazoline-1,1-dioxide, ethanolamine, pyrrolidone, 2-pyrrolidone, ethylene urea, N-methylolurea, N-methylurea, acetylurea, pyrrole, indole, formamide, benzamide, acetamide, imidazoline, or morpholine.
10. The method of claim 1 , wherein the oxidizing biocide is an ammonium salt reacted with an oxidant.
11. The method of claim 1 , wherein the oxidizing biocide is urea reacted with an oxidant.
12. The method of claim 1 , wherein the oxidizing biocide is an ammonium salt reacted with hypochlorite and/or urea reacted with hypochlorite.
13. The method of claim 1 , wherein the oxidizing biocide is ammonium bromide or ammonium sulfate reacted with hypochlorite.
14. The method of claim 1 , wherein the oxidizing biocide is selected from monochloramine, chlorine dioxide, performic acid, an ammonium salt reacted with hypochlorite, or urea reacted with hypochlorite.
15. The method of claim 1 , wherein the Zn ions and the oxidizing biocide are used in a ratio of about 1:1 to 100:1 and/or 1:5 to 20:1 and/or 1:10 to 10:1.
16. The method of claim 1 , wherein the oxidizing biocide is used in an amount to provide a concentration of about 0.1 to 100 ppm, based on the active compound content of the oxidizing biocide in the starch-containing process water.
17. The method of claim 1 , wherein the zinc source is used in an amount to provide about 0.1 to 1000 mg/l zinc ions and/or 3 to 100 mg/l zinc ions and/or 5 to 50 mg/l zinc ions in the starch-containing waters to be treated.
18. The method of claim 1 , wherein the zinc ions and the biocide are continuously, intermittently or alternately added to the starch-containing process water.
19. The method of claim 1 , wherein the zinc ions and the biocide are added simultaneously to the starch-containing process water.
20. The method of claim 1 , wherein the biocide is added prior to the addition of the zinc ions.
21. The method of claim 1 , wherein the zinc ions are added prior to the addition of the biocide.
22. A method of controlling starch degradation in starch-containing process water from pulp, paper or board production, comprising: treating the process water with zinc ions and a biocide;
wherein the zinc ion source is selected from: ZnBr 2 , ZnCl 2 , ZnF 2 , ZnI 2 , ZnO, Zn(OH) 2 , ZnS, ZnSe, ZnTe, Zn 3 N 2 , Zn 3 P 2 , Zn 3 As 2 , Zn 3 Sb 2 , ZnO 2 , ZnH 2 , ZnC 2 , ZnCO 3 , Zn(NO 3 ) 2 , Zn(ClO 3 ) 2 , ZnSO 4 , Zn 3 (PO 4 ) 2 , ZnMoO 4 , ZnCrO 4 , Zn(AsO 2 ) 2 , Zn(AsO 4 ) 2 , Zn(O 2 CCH 3 ) 2 ), zinc metal, and a combination thereof; and
wherein the biocide is an oxidizing biocide and selected from: chlorine, alkali and alkaline earth hypochlorite salts, hypochlorous acid, chlorine dioxide, hydrogen peroxide, peroxy compounds, halogenated hydantoins, monochloramines, monobromamines, dihaloamines, ammonium salts reacted with an oxidant, urea reacted with an oxidant, or a combination thereof.