Negative electrode for rechargeable lithium battery, and rechargeable lithium battery including same
A negative electrode for a rechargeable lithium battery includes a negative active material layer on a current collector. The negative active material layer includes a carbon-based negative active material. A Degree of Divergence (DD) value of the negative electrode is greater than or equal to about 19. The DD value may be calculated based on the following equation: DD(Degree of Divergence)=( I a /I total )*100 where I a is a sum of peak intensities at non-planar angles measured by XRD using a CuKα ray and I total is a sum of peak intensities at all angles measured by XRD using a CuKα ray.
1. A negative electrode for a rechargeable lithium battery, comprising
a current collector; and
a negative active material layer on the current collector and including a carbon-based negative active material, wherein a Degree of Divergence (DD) value of the negative electrode defined by Equation 1 is 19 to 60:
DD(Degree of Divergence)=( I a /I total )*100 (1)
wherein:
I a is a sum of peak intensities at 2θ=42.4±0.2°, 43.4±0.2°, 44.6±0.2°, and 77.5±0.2° measured by XRD using a CuKα ray, and
I total is a sum of peak intensities at 2θ=26.5±0.2°, 42.4±0.2°, 43.4±0.2°, 44.6±0.2°, 54.7±0.2°, and 77.5±0.2° measured by XRD using a CuKα ray.
2. The negative electrode as claimed in claim 1 , wherein a BET specific surface area of the negative electrode is less than about 5.0 m 2 /g.
3. The negative electrode as claimed in claim 1 , wherein the negative electrode has a level (L/L) of a single negative active material layer of about 6 mg/cm 2 to about 65 mg/cm 2 .
4. The negative electrode as claimed in claim 1 , wherein the peak intensity is a peak integral area value.
5. The negative electrode as claimed in claim 1 , wherein the negative electrode has a ratio (I (004) /I (002) ) of a peak intensity at a (004) plane relative to a peak intensity at a (002) plane of greater than or equal to about 0.04 measured by XRD using a CuKα ray.
6. The negative electrode as claimed in claim 1 , wherein the negative electrode has a ratio (I (004) /I (002) ) of a peak intensity at a (004) plane relative to a peak intensity at a (002) plane of greater than or equal to about 0.04 and less than or equal to about 0.07 measured by XRD using a CuKα ray.
7. The negative electrode as claimed in claim 1 , wherein the carbon-based negative active material is artificial graphite or a mixture of artificial graphite and natural graphite.
8. The negative electrode as claimed in claim 1 , wherein the negative active material layer includes a Si-based negative active material, a Sn-based negative active material, a lithium vanadium oxide, or a combination thereof.
9. The negative electrode as claimed in claim 1 , wherein:
the negative electrode has an active region facing a positive electrode and an inactive region not facing the positive electrode, and
a DD value of the inactive region is 19 to 60.
10. A rechargeable lithium battery, comprising
the negative electrode as claimed in claim 1 ;
a positive electrode including a positive active material; and
an electrolyte.
11. The rechargeable lithium battery as claimed in claim 10 , wherein the rechargeable lithium battery is a high power battery.
12. The rechargeable lithium battery as claimed in claim 10 , wherein the rechargeable lithium battery is a cylindrical battery or a pouch type battery.
13. The rechargeable lithium battery as claimed in claim 12 , wherein the cylindrical battery is a 18650 type cylindrical battery or a 21700 type cylindrical battery.
14. A negative electrode for a rechargeable lithium battery, comprising
a current collector; and
a negative active material layer on the current collector,
wherein a Degree of Divergence (DD) value of the negative electrode defined by Equation 1 is 19 to 60,
DD(Degree of Divergence)=( I a /I total )*100 (1)
wherein:
I a is a sum of peak intensities at 2θ=42.4 ±0.2°, 43.4 ±0.2°, 44.6 ±0.2°, and 77.5 ±0.2° measured by XRD using a CuKα ray, and
I total is a sum of peak intensities at 2θ=26.5 ±0.2°, 42.4 ±0.2°, 43.4 ±0.2°, 44.6 ±0.2°, 54.7 ±0.2°, and 77.5 ±0.2° measured by XRD using a CuKα ray.
15. The negative electrode as claimed in claim 14 , wherein the negative active material layer includes a carbon-based negative active material.
16. The negative electrode as claimed in claim 14 , wherein a BET specific surface area of the negative electrode is less than about 5.0m 2 /g.
17. The negative electrode as claimed in claim 14 , wherein the negative electrode has a loading level (L/L) of about 6 mg/cm 2 to about 65 mg/cm 2 on one side of the current collector.