Device for simultaneously producing carbon nanotubes and hydrogen
A method for simultaneously producing carbon nanotubes and hydrogen according to the present invention is a method for simultaneously producing carbon nanotubes and hydrogen, in which using a carbon source containing carbon atoms and hydrogen atoms and being decomposed in a heated state, and a catalyst for producing carbon nanotubes and H 2 from the carbon source, the above carbon nanotubes are synthesized on a support in a heated state, placed in a reactor, and simultaneously, the above H 2 is synthesized from the above carbon source, the method comprising a synthesis step of flowing a source gas comprising the above carbon source over the above support, on which the above catalyst is supported, to synthesize the above carbon nanotubes on the above support and simultaneously synthesize the above H 2 in a gas flow.
1. An apparatus for simultaneously producing carbon nanotubes and hydrogen, comprising:
a carbon source feeding apparatus for feeding a carbon source containing carbon atoms and hydrogen atoms and being decomposed in a heated state;
a catalytic reaction apparatus for decomposing the carbon source by a catalyst supported on a support to synthesize carbon nanotubes on the support and synthesize H 2 in a gas flow;
a carbon nanotube recovery apparatus for recovering the carbon nanotubes from the catalytic reaction apparatus, the carbon nanotube recovery apparatus configured to recover the carbon nanotubes together with the support in a state in which the carbon nanotubes are held on the support and emit the carbon nanotubes through an emission port to a location outside the catalytic reaction apparatus; and
a H 2 recovery apparatus for recovering the H 2 from the catalytic reaction apparatus, the H 2 recovery apparatus configured to recover the H 2 from an emission gas emitted from the catalytic reaction apparatus.
2. The apparatus for simultaneously producing carbon nanotubes and hydrogen according to claim 1 , further comprising a support feeding apparatus for feeding the support, on which a catalyst source, which is a source of the catalyst is supported, to the catalytic reaction apparatus.
3. The apparatus for simultaneously producing carbon nanotubes and hydrogen according to claim 1 , further comprising a support feeding apparatus for feeding the support, on which the catalyst is supported, to the catalytic reaction apparatus.
4. The apparatus for simultaneously producing carbon nanotubes and hydrogen according to claim 1 , wherein:
the catalytic reaction apparatus comprises:
an upper part;
a lower part; and
a heater covering at least a portion of the lower part;
the carbon source feeding apparatus comprises a feed pipe connected to the lower part of the reaction apparatus;
the carbon nanotube recovery apparatus comprises a cyclone connected to the upper part of the reaction apparatus; and
the H 2 recovery apparatus is connected to the cyclone of the carbon nanotube recovery apparatus.
5. The apparatus for simultaneously producing carbon nanotubes and hydrogen according to claim 1 , further comprising a plurality of support particles within the catalytic reaction apparatus, the support particles comprising a carrier layer and at least one catalyst nanoparticle partly buried in the carrier layer.
6. An apparatus for simultaneously producing carbon nanotubes and hydrogen comprising:
a carbon source feeding apparatus for feeding a carbon source containing carbon atoms and hydrogen atoms and being decomposed in a heated state;
a catalytic reaction apparatus for decomposing the carbon source by a catalyst supported on a support to synthesize carbon nanotubes on the support and synthesize H 2 in a gas flow;
a carbon nanotube recovery apparatus for recovering the carbon nanotubes from the catalytic reaction apparatus configured to recover the carbon nanotubes from a emission gas emitted from the catalytic reaction apparatus and emit the carbon nanotubes through an emission port to a location outside the catalytic reaction apparatus;
a H 2 recovery apparatus for recovering the H 2 from the catalytic reaction apparatus, the H 2 recovery apparatus configured to recover the H 2 from the emission gas;
a separation gas feeding apparatus for feeding a separation gas for separating the carbon nanotubes from the support into a gas flow:
an oxidizing gas feeding apparatus for feeding an oxidizing gas for removing carbon remaining on the support from which the carbon nanotubes are separated;
a switching apparatus configured to sequentially switch:
between the carbon source feeding apparatus and the separation gas feeding apparatus; and
between the separation gas feeding apparatus and the oxidizing gas feeding apparatus.
7. The apparatus for simultaneously producing carbon nanotubes and hydrogen according to claim 6 , wherein:
the catalytic reaction apparatus comprises:
an upper part;
a lower part; and
a heater covering at least a portion of the lower part;
the carbon source feeding apparatus comprises a feed pipe connected to the lower part of the reaction apparatus;
the carbon nanotube recovery apparatus comprises a cyclone connected to the upper part of the reaction apparatus; and
the H 2 recovery apparatus is connected to the cyclone of the carbon nanotube recovery apparatus.
8. The apparatus for simultaneously producing carbon nanotubes and hydrogen according to claim 7 , wherein the separation gas feeding apparatus comprises a feed pipe connected to the catalytic reaction apparatus.
9. The apparatus for simultaneously producing carbon nanotubes and hydrogen according to claim 8 , wherein the oxidizing gas feeding apparatus comprises a feed pipe connected to the catalytic reaction apparatus.
10. The apparatus for simultaneously producing carbon nanotubes and hydrogen according to claim 9 , further comprising a catalyst source feeding apparatus, the catalyst source feeding apparatus comprising a feed pipe connected to the catalytic reaction apparatus.
11. The apparatus for simultaneously producing carbon nanotubes and hydrogen according to claim 10 , further comprising a carrier source gas feeding apparatus, the carrier source gas feeding apparatus comprising a feed pipe connected to the catalytic reaction apparatus.
12. The apparatus for simultaneously producing carbon nanotubes and hydrogen according to claim 11 , wherein the switching apparatus is further configured to sequentially switch:
between the oxidizing gas feeding apparatus and the carrier source gas feeding apparatus; and
between the carrier source gas feeding apparatus and the catalyst source feeding apparatus.