Method for producing photoelectric conversion element by using photoelectric conversion film including semiconducting carbon nanotubes having different chiralities
View Patent ↗A method for producing the photoelectric conversion element includes, in carbon nanotubes including semiconducting carbon nanotubes having different chiralities from each other and metallic carbon nanotubes, changing a chirality distribution in the semiconducting carbon nanotubes, separating the carbon nanotubes into the semiconducting carbon nanotubes and the metallic carbon nanotubes after changing the chirality distribution, covering the semiconducting carbon nanotubes with a polymer after performing separating, and forming a photoelectric conversion film including the semiconducting carbon nanotubes between a pair of electrodes after performing covering with the polymer.
1. A method for producing a photoelectric conversion element, comprising:
in carbon nanotubes including metallic carbon nanotubes and semiconducting carbon nanotubes having different chiralities from each other, changing a chirality distribution of the semiconducting carbon nanotubes;
separating the carbon nanotubes into the semiconducting carbon nanotubes and the metallic carbon nanotubes after changing the chirality distribution,
covering the semiconducting carbon nanotubes with a polymer after performing separating, and
forming a photoelectric conversion film including the semiconducting carbon nanotubes as a photoelectric conversion material which absorbs light and generates a charge between a pair of electrodes after performing covering with the polymer.
2. The method for producing a photoelectric conversion element according to claim 1 ,
wherein covering the semiconducting carbon nanotubes with the polymer is performed in an organic solvent in which the polymer is soluble.
3. The method for producing a photoelectric conversion element according to claim 2 ,
wherein the organic solvent is at least one selected from the group consisting of ortho-dichlorobenzene, chlorobenzene, and chloroform.
4. The method for producing a photoelectric conversion element according to claim 2 ,
wherein the organic solvent is at least one selected from the group consisting of toluene and xylene.
5. The method for producing a photoelectric conversion element according to claim 1 ,
wherein separating the carbon nanotubes into the semiconducting carbon nanotubes and the metallic carbon nanotubes is performed by using at least one selected from the group consisting of gel chromatography and aqueous two-phase extraction.
6. The method for producing a photoelectric conversion element according to claim 1 ,
wherein separating the carbon nanotubes into the semiconducting carbon nanotubes and the metallic carbon nanotubes is performed by using at least one selected from the group consisting of density-gradient centrifugation, selective solubilization, electrophoresis, and electrical breakdown.
7. The method for producing a photoelectric conversion element according to claim 1 ,
wherein the polymer is a semiconductive polymer.
8. The method for producing a photoelectric conversion element according to claim 2 , further comprising:
removing part of the polymer that does not cover the semiconducting carbon nanotubes and remains in the organic solvent from the organic solvent after performing covering with the polymer and before forming the photoelectric conversion film.
9. The method for producing a photoelectric conversion element according to claim 1 , wherein forming the photoelectric conversion film includes:
mixing the semiconducting carbon nanotubes and an n-type semiconductor material with each other; and
forming a photoelectric conversion film including the semiconducting carbon nanotubes and the n-type semiconductor material between the pair of electrodes.
10. The method for producing a photoelectric conversion element according to claim 9 ,
wherein the n-type semiconductor material contains at least one selected from the group consisting of fullerene and a fullerene derivative.
11. The method for producing a photoelectric conversion element according to claim 1 ,
wherein the photoelectric conversion element has absorption sensitivity to light having a wavelength range of 1,000 nm to 1,500 nm.
12. A method for producing a photoelectric conversion element, comprising:
separating carbon nanotubes including semiconducting carbon nanotubes having different chiralities from each other and metallic carbon nanotubes into the semiconducting carbon nanotubes and the metallic carbon nanotubes;
changing a chirality distribution of the semiconducting carbon nanotubes after performing separating;
covering the semiconducting carbon nanotube with a polymer after changing the chirality distribution; and
forming a photoelectric conversion film including the semiconducting carbon nanotubes as a photoelectric conversion material which absorbs light and generates a charge between a pair of electrodes after performing covering with the polymer.
13. The method for producing a photoelectric conversion element according to claim 12 ,
wherein covering the semiconducting carbon nanotubes with the polymer is performed in an organic solvent in which the polymer is soluble.
14. The method for producing a photoelectric conversion element according to claim 13 ,
wherein the organic solvent is at least one selected from the group consisting of ortho-dichlorobenzene, chlorobenzene, and chloroform.
15. The method for producing a photoelectric conversion element according to claim 13 ,
wherein the organic solvent is at least one selected from the group consisting of toluene and xylene.
16. The method for producing a photoelectric conversion element according to claim 12 ,
wherein separating the carbon nanotubes into the semiconducting carbon nanotubes and the metallic carbon nanotubes is performed by using at least one selected from the group consisting of gel chromatography and aqueous two-phase extraction.
17. The method for producing a photoelectric conversion element according to claim 12 ,
wherein separating the carbon nanotubes into the semiconducting carbon nanotubes and the metallic carbon nanotubes is performed by using at least one selected from the group consisting of density-gradient centrifugation, selective solubilization, electrophoresis, and electrical breakdown.
18. The method for producing a photoelectric conversion element according to claim 12 ,
wherein the polymer is a semiconductive polymer.
19. The method for producing a photoelectric conversion element according to claim 13 , further comprising:
removing part of the polymer that does not cover the semiconducting carbon nanotubes and remains in the organic solvent from the organic solvent after performing covering with the polymer and before forming the photoelectric conversion film.
20. The method for producing a photoelectric conversion element according to claim 12 , wherein forming the photoelectric conversion film includes:
mixing the semiconducting carbon nanotubes and an n-type semiconductor material with each other: and
forming a photoelectric conversion film including the semiconducting carbon nanotubes and the n-type semiconductor material between the pair of electrodes.
21. The method for producing a photoelectric conversion element according to claim 20 ,
wherein the n-type semiconductor material contains at least one selected from the group consisting of fullerene and a fullerene derivative.
22. The method for producing a photoelectric conversion element according to claim 12 ,
wherein the photoelectric conversion element has absorption sensitivity to light having a wavelength range of 1,000 nm to 1,500 nm.
23. The method for producing a photoelectric conversion element according to claim 1 , further comprising:
forming an image sensor including the photoelectric conversion film.
24. The method for producing a photoelectric conversion element according to claim 12 , further comprising:
forming an image sensor including the photoelectric conversion film.