IP Library › Granted Patent US 10,639,826
Granted Patent B2
US 10,639,826 · App. 16/119,039 · Granted May 5, 2020

Conductive pre-impregnated composite sheet and method for making the same

Inventors: Daniel J. Braley (St. Peters, MO); Justine M. Truscello (St. Louis, MO); Daniel R. Ferriell (St. Louis, MO); John H. Belk (St. Louis, MO); Stephen R. Heinz (O'Fallon, MO)
Assignee: The Boeing Company
B29C43/003B29C43/24B29C43/305B29C70/025B29C70/504B29C70/882B32B3/266B32B5/022B32B5/024B32B5/026B32B5/16B32B5/24B32B5/26B32B7/06B32B15/02B32B15/092B32B15/14B32B15/20B32B19/02B32B19/041B32B19/045B32B19/06B32B27/08B32B27/10B32B27/12B32B27/322B32B27/36B32B27/38B32B29/02B29K2105/0872B29K2105/167B29K2995/0005B29L2009/008B29L2031/3082B32B2255/02B32B2255/20B32B2255/205B32B2260/021B32B2260/046B32B2262/02B32B2262/0261B32B2262/0269B32B2262/0276B32B2262/065B32B2262/10B32B2262/101B32B2262/105B32B2262/106B32B2307/202B32B2307/204B32B2307/206B32B2307/212B32B2307/748B32B2605/18
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Quick Facts
Patent No.
US 10,639,826
App. No.
16/119,039
Granted
May 5, 2020
Kind
B2
Abstract

A method for making a conductive pre-impregnated composite sheet includes the steps of joining a nanomaterial composite sheet, a fiber-reinforcing sheet and a resin system to form a combined sheet, heating the combined sheet, compacting the combined sheet, and cooling the combined sheet to form conductive pre-impregnated composite sheet including the fiber-reinforcing sheet, and the nanomaterial composite sheet coupled to the fiber-reinforcing sheet, wherein the fiber-reinforcing sheet and the nanomaterial composite sheet are embedded in the resin system.

Claims (43)

1. A conductive pre-impregnated composite sheet comprising:

a fiber-reinforcing sheet;

a nanomaterial composite sheet coupled to the fiber-reinforcing sheet, wherein the nanomaterial composite sheet comprises:

a nonwoven veil having a first surface and a second surface, opposite the first surface; and

a nonwoven mat of nanomaterials coupled to the first surface of the nonwoven veil; and

a resin system in which the fiber-reinforcing sheet and the nanomaterial composite sheet are embedded.

2. The conductive pre-impregnated composite sheet of claim 1 wherein the fiber-reinforcing sheet comprises carbon fibers.

3. The conductive pre-impregnated composite sheet of claim 1 wherein the fiber-reinforcing sheet is nonwoven.

4. The conductive pre-impregnated composite sheet of claim 1 wherein the fiber-reinforcing sheet comprises a nonwoven carbon fiber sheet.

5. The conductive pre-impregnated composite sheet of claim 1 wherein the fiber-reinforcing sheet comprises a plurality of unidirectional, continuous carbon fiber tows.

6. The conductive pre-impregnated composite sheet of claim 1 wherein the nanomaterial composite sheet is electrically conductive along at least one axial direction.

7. The conductive pre-impregnated composite sheet of claim 1 wherein the nonwoven veil comprises a nonwoven carbon fiber veil.

8. The conductive pre-impregnated composite sheet of claim 1 wherein the nanomaterial composite sheet comprises a metallic coating applied to the second surface of the nonwoven veil.

9. The conductive pre-impregnated composite sheet of claim 8 wherein the metallic coating comprises nickel.

10. The conductive pre-impregnated composite sheet of claim 8 wherein the metallic coating is opaque to electromagnetic radiation having a frequency less than 100 MHz.

11. The conductive pre-impregnated composite sheet of claim 1 wherein the nonwoven mat of nanomaterials is conductive.

12. The conductive pre-impregnated composite sheet of claim 1 wherein the nonwoven mat of nanomaterials comprises a network of the nanomaterials deposited on and entangled with the first surface of the nonwoven veil.

13. The conductive pre-impregnated composite sheet of claim 12 wherein:

the nonwoven veil is porous;

the network of the nanomaterials is deposited on and entangled with the first surface of the nonwoven veil by filtering a slurry of the nanomaterials through the nonwoven veil; and

at least some of the nanomaterials penetrate through at least a portion of a thickness of the nonwoven veil.

14. The conductive pre-impregnated composite sheet of claim 1 wherein the nonwoven mat of nanomaterials is opaque to electromagnetic radiation having a frequency greater than 100 MHz.

15. The conductive pre-impregnated composite sheet of claim 1 wherein the nonwoven mat of nanomaterials comprises at least one of carbon nanomaterials and boron nanomaterials.

16. The conductive pre-impregnated composite sheet of claim 1 wherein:

the resin system comprises a resin film;

the fiber-reinforcing sheet, the nanomaterial composite sheet, and the resin film are joined to form a combined sheet;

the combined sheet is heated to a temperature in which resin from the resin film begins to flow; and

the combined sheet is compacted to embed the fiber-reinforcing sheet and the nanomaterial composite sheet in the resin system.

17. The conductive pre-impregnated composite sheet of claim 16 wherein the nanomaterial composite sheet is located between the resin film and the fiber-reinforcing sheet in the combined sheet.

18. The conductive pre-impregnated composite sheet of claim 1 wherein:

the resin system comprises resin pre-impregnated within the fiber-reinforcing sheet;

the fiber-reinforcing sheet and the nanomaterial composite sheet are joined to form a combined sheet;

the combined sheet is heated to a temperature in which the resin begins to flow; and

the combined sheet is compacted to embed the fiber-reinforcing sheet and the nanomaterial composite sheet in the resin system.

19. The conductive pre-impregnated composite sheet of claim 1 wherein the fiber-reinforcing sheet is coupled to the second surface of the nonwoven veil, opposite the nonwoven mat of nanomaterials.

20. A composite structure comprising:

at least one fiber-reinforced polymer sheet; and

a conductive pre-impregnated composite sheet, wherein the conductive pre-impregnated composite sheet comprises:

a fiber-reinforcing sheet;

a nanomaterial composite sheet coupled to the fiber-reinforcing sheet, wherein the nanomaterial composite sheet comprises:

a nonwoven veil having a first surface and a second surface, opposite the first surface; and

a nonwoven mat of nanomaterials coupled to the first surface of the nonwoven veil; and

a resin system in which the fiber-reinforcing sheet and the nanomaterial composite sheet are embedded.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 31, 2018
From: BRALEY, DANIEL J.; TRUSCELLO, JUSTINE M.; FERRIELL, DANIEL R; BELK, JOHN H.; HEINZ, STEPHEN R.
To: THE BOEING COMPANY
Reel/Frame 046767/0694 →
Continuity (2)
Division 15095546 · Apr 11, 2016
Related Publication 20180370087A1 · Dec 27, 2018