IP Library Granted Patent US 10,641,728
Granted Patent B2
US 10,641,728 · App. 15/696,807 · Granted May 5, 2020

Printed gas sensor

Inventors: Joseph R. Stetter (Hayward, CA); Vinay Patel (Fremont, CA); Melvin W. Findlay (Buckanan, GA); Michael T. Carter (Denver, CO)
Assignee: SENSIRION AG
G01N27/4045B01J31/06C09D11/03C09D11/106C09D11/52B32B37/185B32B38/0004B32B38/145B32B2309/105B32B2310/0806B32B2310/0843B32B2323/10B32B2457/00
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Quick Facts
Patent No.
US 10,641,728
App. No.
15/696,807
Granted
May 5, 2020
Kind
B2
Abstract

A printed gas sensor is disclosed. The sensor may include a partially porous substrate, an electrode layer, an electrolyte layer, and an encapsulation layer. The electrode layer comprises one or more electrodes that are formed on one side of the porous substrate. The electrolyte layer is in electrolytic contact with the one or more electrodes. The encapsulation layer encapsulates the electrode layer and electrolyte layer thereby forming an integrated structure with the partially porous substrate.

Claims (50)

1. A catalyst ink composition for a printed gas sensor electrode comprising:

a mixture comprising:

about 67-79% of a metal catalyst;

about 5-15% graphite carbon; and

one of about 15% to 25% of a thermoplastic polymer powder; and

a 3 mL ethylcellulose solution.

2. The catalyst ink composition of claim 1 , wherein the thermoplastic polymer powder comprises PTFE powder.

3. The catalyst ink composition of claim 1 , wherein the thermoplastic polymer powder comprises polypropylene powder.

4. The catalyst ink composition of claim 1 , wherein the thermoplastic polymer powder comprises polyethylene powder.

5. The catalyst ink composition of claim 1 , wherein the metal catalyst comprises Pt, Pd, Au, Ag, Ru, Ir, Co, Fe, Ni, C, or a combination thereof.

6. The catalyst ink composition of claim 1 , wherein the ethylcellulose solution further comprises octanol, isophorone, nonanol, deconol, or a combination thereof.

7. The catalyst ink composition of claim 1 , further comprising a surfactant.

8. The catalyst ink composition of claim 7 , wherein the surfactant comprises water, triton-100, carbopol, or a combination thereof.

9. A catalyst ink composition for a printed gas sensor electrode comprising:

a mixture comprising:

about 67-79% Pt;

about 5-15% graphite carbon; and

one of about 22-25% PTFE powder, about 14-17% polypropylene powder, and about 14-17% polyethylene powder; and

a 3 mL ethylcellulose solution.

10. The catalyst ink composition of claim 9 , wherein:

the PTFE powder comprises a particle diameter of about 0.1 μm to about 5 μm;

the polypropylene powder comprises a particle diameter of about 0.1 μm to about 5 μm; and

the polyethylene powder comprises a particle diameter of about 0.2 μm to about 4 μm.

11. The catalyst ink composition of claim 9 , wherein the ethylcellulose solution further comprises octanol, isophorone, nonanol, deconol, or a combination thereof.

12. The catalyst ink composition of claim 9 , wherein the mixture comprises:

about 74-79% Pt;

about 8-9% graphite carbon; and

about 14-17% polyethylene powder.

13. The catalyst ink composition of claim 12 , wherein the polyethylene powder comprises a particle diameter of about 2 μm to about 4 μm.

14. The catalyst ink composition of claim 9 , wherein the mixture comprises:

about 74-79% Pt;

about 8-9% graphite carbon; and

about 14-17% polypropylene powder.

15. The catalyst ink composition of claim 14 , wherein the polypropylene powder comprises a particle diameter of about 5 μm to about 7 μm.

16. The catalyst ink composition of claim 9 , wherein the mixture comprises:

about 67-71% Pt;

about 7-8% graphite carbon; and

about 22-25% PTFE powder.

17. The catalyst ink composition of claim 16 , wherein the PTFE powder comprises a particle diameter of about 1 μm to about 5 μm.

18. A method of manufacturing a printed gas sensor, the method comprising:

printing a catalyst ink composition onto a non-ionically conductive wick;

heating the catalyst ink composition to a curing temperature for a curing period, thereby curing the catalyst ink composition and forming an electrode on the non-ionically conductive wick; and

positioning the non-ionically conductive wick and the electrode within an electrolyte cavity formed by a substrate coupled to an encapsulation layer.

19. The method of claim 18 , further comprising loading an electrolyte into the electrolyte cavity.

20. The method of claim 18 , wherein, the catalyst ink composition comprises:

a mixture comprising:

about 67-79% Pt;

about 5-15% graphite carbon; and

one of about 22-25% PTFE powder, about 14-17% polypropylene powder, and about 14-17% polyethylene powder; and

a 3 mL ethylcellulose solution.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 21, 2019
From: SPEC SENSORS, LLC
To: SENSIRION AG
Reel/Frame 049554/0164 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 6, 2017
From: STETTER, JOSEPH R.; PATEL, VINAY; FINDLAY, MELVIN; CARTER, MICHAEL T.
To: SPEC SENSORS, LLC
Reel/Frame 043508/0148 →
Continuity (4)
Division 14317222 · Jun 27, 2014
Continuation In Part 13740327 · Jan 14, 2013
Division 12953672 · Nov 24, 2010
Related Publication 20180045672A1 · Feb 15, 2018