Heterocyclic compound and organic light emitting device using same
The present application provides a hetero-cyclic compound which may significantly improve the service life, efficiency, electrochemical stability, and thermal stability of an organic light emitting device, and an organic light emitting device in which the hetero-cyclic compound is contained in an organic compound layer.
1. A hetero-cyclic compound represented by the following Formula 1:
in Formula 1,
Y is S or O,
X 1 and X 2 are the same as or different from each other, and are each independently N or CR 10 , wherein at least one of X 1 and X 2 is N,
R 4 to R 9 are hydrogen,
one of R 1 , R 2 , and R 10 is -(L)m-(Z)n, the others are hydrogen,
L is monocyclic or polycyclic substituted or unsubstituted C 6 to C 10 arylene; polycyclic substituted or unsubstituted C 15 to C 60 arylene; or monocyclic or polycyclic substituted or unsubstituted C 2 to C 60 heteroarylene,
m is an integer of 0 to 3,
n is an integer of 1 or 2,
Z is represented by any one of the following structural formulae:
in the structural formulae, Z 1 to Z 3 are the same as or different from each other, and are each independently S or O,
Z 4 to Z 9 are the same as or different from each other, and are each independently CR′R″, NR′, S, or O, and
R′ and R″ are the same as or different from each other, and are each independently hydrogen; straight-chained or branched substituted or unsubstituted C 1 to C 60 alkyl; or monocyclic or polycyclic substituted or unsubstituted C 6 to C 60 aryl.
2. The hetero-cyclic compound of claim 1 , wherein Formula 1 is represented by the following Formula 2 or 3:
in Formulae 2 and 3, the definitions of Y, X 1 , X 2 , R 1 , R 2 , and R 4 to R 9 are the same as those defined in Formula 1.
3. The hetero-cyclic compound of claim 1 , wherein Formula 1 is represented by any one of the following Formulae 4 to 7:
in Formulae 4 to 7,
Y, R 1 , R 2 , and R 4 to R 9 are the same as those defined in Formula 1, and
R 3 is the same as the definition of R 10 of Formula 1.
4. A hetero-cyclic compound represented by any one of the following Formulae 8 to 11:
in Formulae 8 to 11,
A is selected from the group consisting of a direct bond; monocyclic or polycyclic substituted or unsubstituted C 6 to C 10 arylene; polycyclic substituted or unsubstituted C 15 to C 60 arylene; and monocyclic or polycyclic substituted or unsubstituted C 2 to C 60 heteroarylene,
R 16 to R 19 are hydrogen,
p, q, r, and s are an integer of 0 to 4,
R 6 to R 9 are hydrogen, and
Y is S or O.
5. The hetero-cyclic compound of claim 4 , wherein A is selected from the group consisting of monocyclic or polycyclic substituted or unsubstituted C 6 to C 10 arylene; polycyclic substituted or unsubstituted C 15 to C 60 arylene; and monocyclic or polycyclic substituted or unsubstituted C 2 to C 60 heteroarylene.
6. A hetero-cyclic compound selected from the following compounds:
7. An organic light emitting device comprising:
a positive electrode;
a negative electrode; and
one or more organic material layers provided between the positive electrode and the negative electrode, wherein one or more layers of the organic material layers comprise the hetero-cyclic compound of claim 1 .
8. The organic light emitting device of claim 7 , wherein the organic material layer comprises one or more layers selected from the group consisting of a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, and an electron injection layer.
9. The organic light emitting device of claim 8 , wherein the organic material layer comprising the hetero-cyclic compound is an electron transport layer.
10. The organic light emitting device of claim 8 , wherein the organic material layer comprising the hetero-cyclic compound is a light emitting layer.
11. The organic light emitting device of claim 8 , wherein the organic material layer comprising the hetero-cyclic compound is a hole blocking layer.