Tire including an outer sidewall that comprises an incompatible polymer
A tire is provided with an external sidewall, said external sidewall comprising at least one elastomeric composition based on: (a) an elastomeric matrix comprising at least one diene elastomer, (b) a crosslinking system, and (c) at least one polymer incompatible with the elastomeric matrix. A process for the preparation of an elastomeric composition for an external sidewall is also disclosed.
1. A tire provided with an external sidewall, said external sidewall comprising at least one elastomeric composition based on:
(a) an elastomeric matrix comprising at least one diene elastomer,
(b) a crosslinking system,
(c) at least one polymer incompatible with the elastomeric matrix, and
(d) carbon black,
wherein the content of carbon black ranges from 10 to 70 phr,
wherein the at least one diene elastomer is selected from the group consisting of polybutadienes, synthetic polyisoprenes, natural rubber, butadiene copolymers, isoprene copolymers, butadiene/styrene copolymers, isoprene/butadiene copolymers, isoprene/styrene copolymers, isoprene/butadiene/styrene copolymers, and mixtures thereof,
wherein the content of the at least one diene elastomer ranges from 70 to 100 phr,
wherein the at least one incompatible polymer is selected from the group consisting of polybutenes, and
wherein the content of the at least one incompatible polymer ranges from 5 to 15 phr.
2. The tire according to claim 1 , wherein the at least one incompatible polymer is selected from the group consisting of polymers having a number-average molecular weight of less than or equal to 20,000 g/mol.
3. The tire according to claim 2 , wherein the at least one incompatible polymer is selected from the group consisting of polymers having a number-average molecular weight ranging from 200 to 4000 g/mol.
4. The tire according to claim 1 , wherein the at least one incompatible polymer is a polyisobutylene.
5. The tire according to claim 1 , wherein the at least one incompatible polymer is selected from the group consisting of liquids exhibiting a kinematic viscosity at 100° C. ranging from 20 to 200,000 SUS according to Standard ASTM D2161.
6. The tire according to claim 5 , wherein the at least one incompatible polymer is selected from the group consisting of liquids exhibiting a kinematic viscosity at 100° C. ranging from 200 to 50,000 SUS according to Standard ASTM D2161.
7. The tire according to claim 1 , wherein the at least one incompatible polymer is in the form of vesicles in the elastomeric composition.