Organic light emitting display device
An organic light emitting display device is provided. The organic light emitting display device may include at least one light emitting part between an anode and a cathode, and the at least one light emitting part having at least one organic layer and a light emitting layer, wherein the at least one organic layer comprises a compound represented by Chemical Formula 1 or 2.
1. An organic light emitting display device, comprising:
at least one light emitting part between an anode and a cathode, the at least one light emitting part having at least one organic layer and a light emitting layer,
wherein the at least one organic layer comprises a hole injection layer,
wherein the hole injection layer comprises a compound represented by Chemical Formula 2:
in the Chemical Formula 2, R 1 to R 6 include independently one among hydrogen, a substituted or unsubstituted aryl group with 6 to 12 carbon atoms, a substituted or unsubstituted heteroaryl group with 1 to 12 carbon atoms and 1 to 4 heteroatoms one among O, N, S, and Si, a substituted or unsubstituted alkyl group with 1 to 12 carbon atoms, a substituted or unsubstituted alkoxy group with 1 to 12 carbon atoms, a substituted or unsubstituted ether group with 1 to 12 carbon atoms, a cyano group, a fluorine group, a trifluoromethyl group, a trifluoromethoxy group, and a trimethylsilyl group, and at least one of R 1 to R 6 comprises a cyano group, and
in Chemical Formula 2, Z 1 and Z 2 are independently represented by the following Chemical Formula 3:
where A and B independently represent one among a hydrogen atom, a substituted or unsubstituted aryl group with 6 to 12 carbon atoms, a substituted or unsubstituted heteroaryl group with 1 to 12 carbon atoms and 1 to 4 heteroatoms one among O, N, S, and Si, a substituted or unsubstituted alkyl group with 1 to 12 carbon atoms, a substituted or unsubstituted alkoxy group with 1 to 12 carbon atoms, a substituted or unsubstituted ether group with 1 to 12 carbon atoms, a cyano group, a fluorine group, a trifluoromethyl group, a trifluoromethoxy group, and a trimethylsilyl group,
wherein Z 1 and Z 2 are attached via a double bond between a carbon atom bound to A and B of Chemical Formula 3 and the indacene ring of Chemical Formula 2.
2. The organic light emitting display device of claim 1 , wherein the substituent of the aryl group, heteroaryl group, alkyl group, alkoxy group, and ether group is one among an alkyl with 1 to 12 carbon atoms, an aryl with 6 to 15 carbon atoms, a hetero alkyl with 1 to 15 carbon atoms and 1 to 4 heteroatoms one among O, N, S, and Si, a cyano group, a fluorine group, a trifluoromethyl group, a trifluoromethoxy group, and a trimethylsilyl group.
3. The organic light emitting display device of claim 1 , wherein the compound represented by the above Chemical Formula 2 is one among the following compounds:
4. The organic light emitting display device of claim 1 , wherein a dopant of the hole injection layer includes the compound.
5. An organic light emitting display device, comprising:
at least one light emitting part between an anode and a cathode, the at least one light emitting part having a hole injection layer and a light emitting layer; and
a charge generation layer having a P-type charge generation layer between the at least one light emitting part and the cathode,
wherein the hole injection layer comprises a compound represented by Chemical Formula 2:
in the Chemical Formula 2, R 1 to R 6 each independently represents one among a hydrogen atom, a substituted or unsubstituted aryl group with 6 to 12 carbon atoms, a substituted or unsubstituted heteroaryl group with 1 to 12 carbon atoms and 1 to 4 heteroatoms one among O, N, S, and Si, a substituted alkyl group with 1 to 12 carbon atoms, a substituted or unsubstituted alkoxy group with 1 to 12 carbon atoms, a substituted or unsubstituted ether group with up to 12 carbon atoms, a cyano group, a fluorine group, a trifluoromethyl group, a trifluoromethoxy group, and a trimethylsilyl group, and at least one among R 1 to R 6 comprises a cyano group, and
in Chemical Formula 2, Z 1 and Z 2 are independently represented by the following Chemical Formula 3:
where A and B independently represent one among a hydrogen atom, a substituted or unsubstituted aryl group with 6 to 12 carbon atoms, a substituted or unsubstituted heteroaryl group with up to 12 carbon atoms and 1 to 4 heteroatoms one among O, N, S, and Si, a substituted or unsubstituted alkyl group with 1 to 12 carbon atoms, a substituted or unsubstituted alkoxy group with 1 to 12 carbon atoms, a substituted or unsubstituted ether group with up to 12 carbon atoms, a cyano group, a fluorine group, a trifluoromethyl group, a trifluoromethoxy group, and a trimethylsilyl group,
wherein Z 1 and Z 2 are attached via a double bond between a carbon atom bound to A and B of Chemical Formula 3 and the indacene ring of Chemical Formula 2.
6. The organic light emitting display device of claim 5 , wherein the substituent of the aryl group, heteroaryl group, alkyl group, alkoxy group, and ether group is one among an alkyl with 1 to 12 carbon atoms, an aryl with 6 to 15 carbon atoms, a hetero alkyl with 1 to 15 carbon atoms and 1 to 4 heteroatoms one among O, N, S, and Si, a cyano group, a fluorine group, a trifluoromethyl group, a trifluoromethoxy group, and a trimethylsilyl group.
7. The organic light emitting display device of claim 5 , wherein the compound represented by the above Chemical Formula 2 is one among the following compounds:
8. The organic light emitting display device of claim 5 , wherein a dopant of the hole injection layer includes the compound.
9. The organic light emitting display device of claim 5 , wherein a dopant of the P-type charge generation layer includes the compound.
10. The organic light emitting display device of claim 5 , wherein the P-type charge generation layer includes the compound.
11. An organic light emitting display device, comprising:
a first and second light emitting part between an anode and a cathode, the at least one light emitting part having a hole injection layer and a light emitting layer; and
a charge generation layer having a P-type charge generation layer between the first light emitting part and the second light emitting part,
wherein the hole injection layer comprises a compound represented by Chemical Formula 2:
where R 1 to R 6 each independently represents one among a hydrogen atom, a substituted or unsubstituted aryl group with 6 to 12 carbon atoms, a substituted or unsubstituted heteroaryl group with 1 to 12 carbon atoms and 1 to 4 heteroatoms one among O, N, S, and Si, a substituted alkyl group with 1 to 12 carbon atoms, a substituted or unsubstituted alkoxy group with 1 to 12, carbon atoms, a substituted or unsubstituted ether group with 1 to 12 carbon atoms, a cyano group, a fluorine group, a trifluoromethyl group, a trifluoromethoxy group, and a trimethylsilyl group, and at least one among R 1 to R 6 comprises a cyano group, and
Z 1 and Z 2 are independently represented by the following Chemical Formula 3:
where A and B independently represent one among a hydrogen atom, a substituted or unsubstituted aryl group with 6 to 12 carbon atoms, a substituted or unsubstituted heteroaryl group with up to 12 carbon atoms and 1 to 4 heteroatoms one among O, N, S, and Si, a substituted or unsubstituted alkyl group with 1 to 12 carbon atoms, a substituted or unsubstituted alkoxy group with 1 to 12 carbon atoms, a substituted or unsubstituted ether group with up to 12 carbon atoms, a cyano group, a fluorine group, a trifluoromethyl group, a trifluoromethoxy group, and a trimethylsilyl group,
wherein Z 1 and Z 2 are attached via a double bond between a carbon atom bound to A and B of Chemical Formula 3.
12. The organic light emitting display device of claim 11 , further comprising:
a third light emitting part on the second light emitting part; and
a second charge generation layer having a second P-type charge generation layer between the second light emitting part and the third light emitting part,
wherein at least one among the hole injection layer, the P-type charge generation layer, and the second P-type generation layer comprises the compound.