IP Library › Granted Patent US 10,668,456
Granted Patent B2
US 10,668,456 · App. 15/672,497 · Granted Jun 2, 2020

Titanium oxide particle, composition for forming photocatalyst, and photocatalyst

Inventors: Takeshi Iwanaga (Kanagawa, JP); Hiroyoshi Okuno (Kanagawa, JP); Hideaki Yoshikawa (Kanagawa, JP); Yasunobu Kashima (Kanagawa, JP); Sakae Takeuchi (Kanagawa, JP)
Assignee: FUJI XEROX CO., LTD.
B01J31/12B01J21/063B01J21/18B01J31/02B01J31/122B01J31/14B01J31/143B01J35/004B01J35/0013B01J35/023B01J37/0215B01J37/0221B01J37/031B01J37/033B01J37/035C07F7/1804C07F7/28C09C1/3684B01J31/0274C01P2002/85C01P2004/51
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Quick Facts
Patent No.
US 10,668,456
App. No.
15/672,497
Granted
Jun 2, 2020
Kind
B2
Abstract

A titanium oxide particle includes a metal having a hydrocarbon group, which is bonded to a surface of the titanium oxide particle through an oxygen atom, and absorbs light having a wavelength of 450 nm and light having a wavelength of 750 nm, wherein an element ratio C/Ti between carbon C and titanium Ti in a surface of the titanium oxide particle is from 0.3 to 1.2, and a reduced amount of C/Ti on the surface of the titanium oxide particle before and after irradiation with an ultraviolet ray having a wavelength of 352 nm and at an irradiation intensity of 1.3 mW/cm 2 for 20 hours is from 0.1 to 0.9.

Claims (40)

1. A titanium oxide particle, comprising:

a core of titanium oxide; and

a metal compound having a hydrocarbon group, which is bonded to a surface of the core through an oxygen atom,

wherein the titanium oxide particle absorbs light having a wavelength of 450 nm and light having a wavelength of 750 nm,

an element ratio C/Ti between carbon C and titanium Ti on a surface on the titanium oxide particles is from 0.3 to 1.2, and

the element ratio of C/Ti on the surface of the titanium oxide particle after irradiation with an ultraviolet ray having a wavelength of 352 nm and at an irradiation intensity of 1.3 mW/cm 2 for 20 hours is reduced in an amount from 0.1 to 0.9.

2. The titanium oxide particle according to claim 1 ,

which has an absorption in a whole range of a wavelength of 400 nm to 800 nm in a visible absorption spectrum.

3. The titanium oxide particle according to claim 1 , which is prepared by subjecting a core of titanium oxide to a surface treatment with a metal-containing compound to obtain the titanium oxide particle,

the metal-containing compound being a compound represented by R 1 n SiR 2 m wherein R 1 represents an aliphatic hydrocarbon group or an aromatic hydrocarbon group which has 1 to 20 carbon atoms and is saturated or unsaturated, R 2 represents a halogen atom or an alkoxy group, n represents an integer of 1 to 3, m represents an integer of 1 to 3, provided that n+m=4 is satisfied, when n represents an integer of 2 or 3, plural R 1 's may be the same or different, and when m represents an integer of 2 or 3, plural R 2 's may be the same or different.

4. The titanium oxide particle according to claim 3 ,

wherein R 1 is a straight chain shape saturated aliphatic hydrocarbon group.

5. The titanium oxide particle according to claim 3 ,

wherein R 1 is a hexyl group.

6. The titanium oxide particle according to claim 3 , wherein R 1 is an aromatic hydrocarbon group having 6 to 18 carbon atoms.

7. The titanium oxide particle according to claim 6 ,

wherein R 1 is a phenyl group.

8. The titanium oxide particle according to claim 3 ,

wherein R 2 is an alkoxy group having 1 to 10 carbon atoms.

9. The titanium oxide particle according to claim 3 ,

wherein R 2 is a methoxy group.

10. The titanium oxide particle according to claim 3 ,

wherein R 2 is a chlorine atom.

11. The titanium oxide particle according to claim 1 ,

which has a volume average particle diameter of from 10 nm to 1 μm.

12. A composition for forming a photocatalyst, comprising:

the titanium oxide particle according to claim 1 ; and

at least one compound selected from the group consisting of a dispersion medium and a binder.

13. The composition for forming a photocatalyst according to claim 12 ,

wherein the dispersion medium contains water or an organic solvent.

14. The composition for forming a photocatalyst according to claim 13 ,

wherein the organic solvent is an alcohol solvent.

15. The composition for forming a photocatalyst according to claim 12 ,

wherein the binder comprises at least one selected from the group consisting of a fluorine resin, a silicone resin, a polyester resin, and an acrylic resin.

16. The composition for forming a photocatalyst according to claim 12 ,

comprising a coloring material included in the binder.

17. A photocatalyst comprising the titanium oxide particle according to claim 1 .

18. The photocatalyst according to claim 17 , further comprising a promotor.

19. The photocatalyst according to claim 17 , further comprising an antiseptic agent.

20. The photocatalyst according to claim 17 , further comprising a thickener.

Assignments (2)
CHANGE OF NAME Recorded Aug 12, 2021
From: FUJI XEROX CO., LTD.
To: FUJIFILM BUSINESS INNOVATION CORP.
Reel/Frame 058287/0056 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 9, 2017
From: IWANAGA, TAKESHI; OKUNO, HIROYOSHI; YOSHIKAWA, HIDEAKI; KASHIMA, YASUNOBU; TAKEUCHI, SAKAE
To: FUJI XEROX CO., LTD.
Reel/Frame 043247/0523 →
Priority Claims (1)
JP 2016-240463 · Dec 12, 2016 · national
Continuity (1)
Related Publication 20180161763A1 · Jun 14, 2018