High performance glass fiber composition, and glass fiber and composite material thereof
Provided are a high-performance glass fiber composition, and a glass fiber and composite material thereof. The content, given in weight percentage, of each component of the glass fibre composition is as follows: 52-64% of SiO 2 , 12-24% of Al 2 O 3 , 0.05-8% of Y 2 O 3 +La 2 O 3 +Gd 2 O 3 , less than 2.5% of Li 2 O+Na 2 O+K 2 O, more than 1% of K 2 O, 10-24% of CaO+MgO+SrO, 2-14% of CaO, less than 13% of MgO, less than 2% of TiO 2 , and less than 1.5% of Fe 2 O 3 . The composition significantly increases the mechanical strength and the elastic modulus of glass, significantly reduces the liquidus temperature and the forming temperature of glass, and under equal conditions, significantly reduces the crystallization rate, the surface tension and the bubble rate of glass. The composition is particularly suitable for the tank furnace production of a high-strength high-modulus glass fiber having a low bubble rate.
1. A high-performance glass fiber composition, containing the following contents of components in weight percentage:
SiO 2
52-64%
Al 2 O 3
12-24%
RE 2 O 3 = Y 2 O 3 + La 2 O 3 + Gd 2 O 3
0.05-8%
R 2 O = Li 2 O + Na 2 O + K 2 O
<2.5%
K 2 O
≥1.1%
CaO + MgO + SrO
10-24%
CaO
2-14%
MgO
<13%
TiO 2
<2%
Fe 2 O 3
<1.5%.
2. The high-performance glass fiber composition according to claim 1 , wherein the content of Li 2 O in weight percentage is 0.1-1%.
3. The high-performance glass fiber composition according to claim 1 , wherein the content of Y 2 O 3 in weight percentage is 0.05-6%.
4. The high-performance glass fiber composition according to claim 1 , wherein the content of Y 2 O 3 in weight percentage is 0.5-5%.
5. The high-performance glass fiber composition according to claim 1 , wherein the content of La 2 O 3 in weight percentage is 0.05-2%.
6. The high-performance glass fiber composition according to claim 1 , wherein the content of Gd 2 O 3 in weight percentage is 0.05-1%.
7. The high-performance glass fiber composition according to claim 1 , further containing CeO 2 , the content of which in weight percentage is 0-1%.
8. The high-performance glass fiber composition according to claim 1 , wherein the content of SrO in weight percentage is less than 2.5%.
9. The high-performance glass fiber composition according to claim 1 , wherein the content of SrO in weight percentage is 0.1-2%.
10. The high-performance glass fiber composition according to claim 1 , wherein the content of CaO in weight percentage is 4-11%.
11. The high-performance glass fiber composition according to claim 1 , wherein the content of MgO in weight percentage is 6-12%.
12. The high-performance glass fiber composition according to claim 1 , wherein the content of SiO 2 +Al 2 O 3 in weight percentage is less than 80%.
13. The high-performance glass fiber composition according to claim 1 , wherein a ratio C1 in weight percentage of K 2 O to R 2 O, C1=K 2 O/R 2 O, is greater than 0.44.
14. The high-performance glass fiber composition according to claim 1 , wherein a ratio C2 in weight percentage of (MgO+SrO) to CaO, C2=(MgO+SrO)/CaO, is greater than 0.9.
15. The high-performance glass fiber composition according to claim 1 , containing the following contents of components in weight percentage:
SiO 2
52-64%
Al 2 O 3
12-24%
RE 2 O 3 = Y 2 O 3 + La 2 O 3 + Gd 2 O 3
0.05-8%
La 2 O 3
0.05-2%
R 2 O = Li 2 O + Na 2 O + K 2 O
<2.5%
K 2 O
≥1.1%
CaO + MgO + SrO
10-24%
CaO
2-14%
MgO
<13%
TiO 2
<2%
Fe 2 O 3
<1.5%
and, a ratio C1 in weight percentage of K 2 O to R 2 O, C1=K 2 O/R 2 O, is greater than 0.44.
16. The high-performance glass fiber composition according to claim 1 , containing the following contents of components in weight percentage:
SiO 2
52-64%
Al 2 O 3
12-24%
RE 2 O 3 = Y 2 O 3 + La 2 O 3 + Gd 2 O 3
0.05-8%
R 2 O = Li 2 O + Na 2 O + K 2 O
<2.5%
K 2 O
≥1.1%
Li 2 O
0.1-1%
CaO + MgO + SrO
10-24%
CaO
2-14%
MgO
<13%
SrO
<2.5%
TiO 2
<2%
Fe 2 O 3
<1.5%
and, a ratio C1 in weight percentage of K 2 O to R 2 O, C1=K 2 O/R 2 O, is greater than 0.44, and a ratio C2 in weight percentage of (MgO+SrO) to CaO, C2=(MgO+SrO)/CaO, is greater than 0.9.
17. The high-performance glass fiber composition according to claim 1 , containing the following contents of components in weight percentage:
SiO 2
52-64%
Al 2 O 3
12-24%
RE 2 O 3 = Y 2 O 3 + La 2 O 3 + Gd 2 O 3
0.05-8%
Y 2 O 3
0.05-6%
R 2 O = Li 2 O + Na 2 O + K 2 O
<2.5%
K 2 O
≥1.1%
Li 2 O
0.1-1%
CaO + MgO + SrO
10-24%
CaO
2-14%
MgO
<13%
SrO
<2.5%
TiO 2
<2%
Fe 2 O 3
<1.5%
and, a ratio C1 in weight percentage of K 2 O to R 2 O, C1=K 2 O/R 2 O, is greater than 0.44, and a ratio C2 in weight percentage of (MgO+SrO) to CaO, C2=(MgO+SrO)/CaO, is greater than 0.9.
18. The high-performance glass fiber composition according to claim 1 , containing the following contents of components in weight percentage:
SiO 2
52-64%
Al 2 O 3
12-24%
RE 2 O 3 = Y 2 O 3 + La 2 O 3 + Gd 2 O 3
1-6%
R 2 O = Li 2 O + Na 2 O + K 2 O
<2.5%
K 2 O
≥1.1%
Li 2 O
0.1-1%
CaO + MgO + SrO
10-24%
CaO
4-11%
MgO
6-12%
SrO
<2.5%
TiO 2
<2%
Fe 2 O 3
<1.5%
and, a ratio C1 in weight percentage of K 2 O to R 2 O, C1=K 2 O/R 2 O, is greater than or equal to 0.5, and a ratio C2 in weight percentage of (MgO+SrO) to CaO, C2=(MgO+SrO)/CaO, is greater than or equal to 1.
19. A glass fiber, made of the glass fiber composition according to claim 1 .
20. A composite material, comprising the glass fiber according to claim 19 .