Method of manufacturing grain-oriented electrical steel sheet
Provided is a method of manufacturing a grain-oriented electrical steel sheet including: a heating process of heating a slab having a predetermined chemical composition at T1° C. of 1150° C. to 1300° C., retaining the slab for 5 minutes to 30 hours, lowering the temperature of the slab to T2° C. of T1−50° C. or lower, heating the slab at T3° C. of 1280° C. to 1450° C., and retaining the slab for 5 minutes to 60 minutes; a hot-rolling process of hot-rolling the slab that is heated to obtain a hot-rolled steel sheet; a cold-rolling process; an intermediate annealing process of performing intermediate annealing with respect to the hot-rolled steel sheet at least one time before the cold-rolling process or before a final pass of the cold-rolling process after interrupting the cold-rolling; an annealing separating agent applying process; and a secondary film applying process. In the cold-rolling process, a retention treatment is performed during a plurality of passes. In the retention treatment, retention at a temperature T° C. satisfying 170+[Bi]×5000≤T≤300 is performed one time to four times. A heating rate in the decarburization annealing process is 50° C./second or faster.
1. A method of manufacturing a grain-oriented electrical steel sheet, comprising:
a heating process of heating a slab, which contains, in terms of mass %, C: 0.030% to 0.150%, Si: 2.50% to 4.00%, Mn: 0.02% to 0.30%, one or two of S and Se: 0.005% to 0.040% in a total amount, an acid-soluble Al: 0.015% to 0.040%, N: 0.0030% to 0.0150%, Bi: 0.0003% to 0.0100%, Sn: 0% to 0.50%, Cu: 0% to 0.20%, one or two of Sb and Mo: 0% to 0.30% in a total amount, and the remainder including Fe and impurities, to a surface temperature T1° C. of 1150° C. to 1300° C., retaining the slab for 5 minutes to 30 hours, lowering the surface temperature of the slab to T2° C. of T1-200° C. to T1-50° C., heating the surface temperature of the slab to T3° C. of 1280° C. to 1450° C., and retaining the slab for 5 minutes to 60 minutes;
a hot-rolling process of hot-rolling the slab that is heated to obtain a hot-rolled steel sheet;
a cold-rolling process of performing a cold-rolling including a plurality of passes with respect to the hot-rolled steel sheet to obtain a cold-rolled steel sheet having a sheet thickness of 0.30 mm or less;
an intermediate annealing process of performing an intermediate annealing with respect to the hot-rolled steel sheet at least one time before the cold-rolling process or before a final pass of the cold-rolling process after interrupting the cold-rolling;
a decarburization annealing process of decarburization annealing with respect to the cold-rolled steel sheet;
an annealing separating agent applying process of applying an annealing separating agent to the cold-rolled steel sheet after the decarburization annealing;
a final annealing process of performing a final annealing with respect to the cold-rolled steel sheet after the annealing separating agent applying process; and
a secondary film applying process of applying an insulating film onto the cold-rolled steel sheet after the final annealing,
wherein in the intermediate annealing process, the intermediate annealing, in which a retention is performed at a temperature of 1000° C. to 1200° C. for 5 seconds to 180 seconds, is performed, in the cold-rolling process, a retention treatment, in which the hot-rolled steel sheet is retained one or more times at a temperature of 130° C. to 300° C. for 3 minutes to 120 minutes, is performed during the plurality of passes,
in the retention treatment, a retention at a temperature 1° C. satisfying the following Expression (1) is performed one time to four times, and
a heating rate in the decarburization annealing process is 50° C./second or faster,
170+[Bi]×5000≤ T≤ 300 (1)
(here, [Bi] in Expression (1) represents the amount of Bi in terms of mass % in the slab).
2. The method of manufacturing a grain-oriented electrical steel sheet according to claim 1 ,
wherein the slab contains, in terms of mass %, Sn: 0.05% to 0.50%.
3. The method of manufacturing a grain-oriented electrical steel sheet according to claim 1 or 2 ,
wherein the slab contains, in terms of mass %, Cu: 0.01% to 0.20%.
4. The method of manufacturing a grain-oriented electrical steel sheet according to claim 1 or 2 ,
wherein the slab contains, in terms of mass %, one or two of Sb and Mo in a total amount of 0.0030% to 0.30%.
5. The method of manufacturing a grain-oriented electrical steel sheet according to claim 1 or 2 ,
wherein in the final annealing process, an X value, which is calculated with the following Expression (2), is set to 0.0003 Nm 3 /(hm 2 ) or greater,
X =Atmosphere gas flow rate/total steel sheet surface area (2).
6. The method of manufacturing a grain-oriented electrical steel sheet according to claim 3 ,
wherein the slab contains, in terms of mass %, one or two of Sb and Mo in a total amount of 0.0030% to 0.30%.
7. The method of manufacturing a grain-oriented electrical steel sheet according to claim 3 ,
wherein in the final annealing process, an X value, which is calculated with the following Expression (2), is set to 0.0003 Nm 3 /(h·m 2 ) or greater,
X =Atmosphere gas flow rate/total steel sheet surface area (2).
8. The method of manufacturing a grain-oriented electrical steel sheet according to claim 4 ,
wherein in the final annealing process, an X value, which is calculated with the following Expression (2), is set to 0.0003 Nm 3 /(h·m 2 ) or greater,
X =Atmosphere gas flow rate/total steel sheet surface area (2).
9. The method of manufacturing a grain-oriented electrical steel sheet according to claim 6 ,
wherein in the final annealing process, an X value, which is calculated with the following Expression (2), is set to 0.0003 Nm 3 /(h·m 2 ) or greater,
X =Atmosphere gas flow rate/total steel sheet surface area (2).