Molybdenum alloys for medical devices
A medical device having improved surface hardness and wear resistance properties. The medical device has a body that includes a molybdenum and rhenium alloy. The outer surface of the body has a nitride surface layer that includes nitrogen, molybdenum and rhenium.
1. A method for using an orthopedic medical device having increased surface hardness and wear resistance comprising:
providing said orthopedic medical device selected from a joint implant, said joint implant is a knee implant, hip implant, shoulder implant, ankle implant, wrist implant, or elbow implant, said orthopedic medical device having a body that includes a molybdenum-rhenium alloy and a nitride surface layer on an outer surface layer of said molybdenum-rhenium alloy, said nitride surface layer includes nitrogen, molybdenum, and rhenium;
providing a liner of said joint implant; and,
mating said joint implant with said liner, said nitride surface layer of said orthopedic medical device engages said liner,
wherein said nitride surface layer is formed by exposing said body that includes a molybdenum-rhenium alloy to a nitriding process in the presence of nitrogen gas or a nitrogen gas mixture for at least about one minute at a temperature of at least about 400° Celsius,
wherein said nitride surface layer comprises 40-99 wt. % molybdenum, 1-40 wt. % rhenium, and 0.0001-5 wt. % nitrogen, and
wherein said nitride surface layer a) results in enhanced wear-resistance properties to said orthopedic medical device as compared to a similar molybdenum-rhenium alloy that is absent said nitride surface layer, b) extends a life of said orthopedic medical device, c) increases a wear life of mating surfaces on the orthopedic medical device, and d) reduces particulate generation from use of said orthopedic medical device.
2. The method as defined in claim 1 , wherein a thickness of said nitride surface layer is less than 1 mm.
3. The method as defined in claim 2 , wherein a thickness of said nitride surface layer is 50 nm to 0.1 mm.